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Hydroxy-Thioxanthones as Suitable Neutral Ionophores for the Preparation of PVC-Membrane Potentiometric Sensors for Al(III) Ion

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Abstract

The complexation of five recently synthesized hydroxy-thioxanthone derivatives with Al3+ ion was studied in a methanol solution spectrophotometrically, and the stepwise formation constants of the resulting 1:1 and 2:1 (ligand-to-metal) complexes were evaluated. The suitability of the thioxanthone derivatives as neutral ionophores for the preparation of a new Al3+ ion-selective PVC-membrane electrode was investigated, and 1-hydroxy-3-methyl-thiocanthone was selected as the best compound for this purpose. The prepared electrode exhibits a Nernstian response for Al3+ ions over a wide concentration range (2.0 × 10–2 to 2.0 × 10–6 M), with a limit of detection of 1.0 × 10–6 M. It has a very fast response time of about 5 s and can be used for at least 3 months without any considerable divergence in the potentials. The proposed membrane sensor revealed very good selectivities for Al3+ over a wide variety of other metal ions, and could be used at a working pH range of 3.4–5.0. It was used as an indicator electrode in potentiometric titration of aluminum ions with EDTA, and in the determination of Al3+ in different real samples.

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Authors and Affiliations

  1. Department of Chemistry, Razi University, Kermanshah, Iran

    Mojtaba Shamsipur, Sohrab Ershad & Absollah Yari

  2. Department of Chemistry, Shiraz University, Shiraz, Iran

    Hashem Sharghi & Ali Reza Salimi

Authors
  1. Mojtaba Shamsipur
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  2. Sohrab Ershad
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  3. Absollah Yari
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  4. Hashem Sharghi
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  5. Ali Reza Salimi
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Correspondence to Mojtaba Shamsipur.

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Shamsipur, M., Ershad, S., Yari, A. et al. Hydroxy-Thioxanthones as Suitable Neutral Ionophores for the Preparation of PVC-Membrane Potentiometric Sensors for Al(III) Ion. ANAL. SCI. 20, 301–306 (2004). https://doi.org/10.2116/analsci.20.301

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