Skip to main content
SpringerLink
Log in

Adsorption-Desorption Studies of Ketones at a Hanging Mercury Drop Electrode by a Flow Injection Method

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The adsorption-desorption phenomena of ketones were studied by measuring differential capacity-time curves in a flowing solution. The ketones investigated were acetone, 2-butanone, 3-pentanone and 4-heptanone. The differential capacity-time curves for these ketones showed different shapes with and without peaks. The curves were used to study the adsorption reversibility of the ketones at a mercury electrode. The adsorption of acetone was irreversible and that of 3-pentanone and 4-heptanone was reversible. The adsorption of 2-butanone was rather complicated. It seems that two types of adsorption exist for 2-butanone.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. J. Motheo and E. R. Gonzales, Electrochim. Acta, 41, 2631 (1996).

    Article  CAS  Google Scholar 

  2. A. S. Baranski and A. Szulborska, Electrochim. Acta, 41, 985 (1996).

    Article  CAS  Google Scholar 

  3. V. Vacheva, M. Kaisheva and B. Damaskin, Electrochim. Acta, 42, 2327 (1997).

    Article  CAS  Google Scholar 

  4. A. N. Frumkin and B. B. Damaskin, “Modern Aspects of Electrochemistry”, ed. J. O’M. Bockris, Vol. 3, p. 214, Butterworths, London, 1964.

    Google Scholar 

  5. Y. M. Temerk and P. Valenta, J. Electroanal. Chem., 214, 391 (1986).

    Article  CAS  Google Scholar 

  6. T. Wandlowski, E. Kretschmer and U. Retter, J. Electroanal. Chem, 224, 261 (1987).

    Article  CAS  Google Scholar 

  7. I. Ruzic, H. J. Ulrich and B. Cosovic, J. Colloid Interface Sci., 126, 525 (1988).

    Article  CAS  Google Scholar 

  8. C. Muller, E. Valles, O. Vellve and E. Gomez, J. Electroanal. Chem, 224, 237 (1987).

    Article  Google Scholar 

  9. T. Wandlowski, J. Electroanal. Chem., 333, 77 (1992).

    Article  CAS  Google Scholar 

  10. Z. Adsmczyk and G. Para, Colloids Surfaces, 66, 249 (1992).

    Article  Google Scholar 

  11. T. Wandlowski and R. de Levie, J. Electroanal. Chem., 329, 103 (1992).

    Article  CAS  Google Scholar 

  12. T. Wandlowski and R. de Levie, J. Electroanal. Chem., 345, 413 (1993).

    Article  CAS  Google Scholar 

  13. T. Wandlowski and R. de Levie, J. Electroanal. Chem., 352, 279 (1993).

    Article  CAS  Google Scholar 

  14. L. Pospisil and M. Svestka, J. Electroanal. Chem., 426, 47 (1997).

    Article  CAS  Google Scholar 

  15. H. Sawamoto and K. Gamoh, J. Electroanal. Chem., 28, 421 (1990).

    Article  Google Scholar 

  16. H. Sawamoto, J. Electroanal. Chem., 361, 215 (1993).

    Article  CAS  Google Scholar 

  17. H. Sawamoto, J. Electroanal. Chem., 375, 391 (1994).

    Article  CAS  Google Scholar 

  18. H. Sawamoto, Nippon Kagaku Kaishi, 1996, 958.

    Google Scholar 

  19. H. Sawamoto, Nippon Kagaku Kaishi, 1997, 294.

    Google Scholar 

  20. H. Sawamoto, J. Electroanal. Chem., 432, 153 (1997).

    Article  CAS  Google Scholar 

  21. S. Trasatti, Electrochim. Acta, 37, 2137 (1992).

    Article  CAS  Google Scholar 

  22. G. M. Torrie and G. N. Patey, Electrochim. Acta, 36, 1677 (1991).

    Article  CAS  Google Scholar 

  23. Z. Q. Tian, S. K. Sigalaev, S. Z. Zou, B. W. Mao, A. M. Funtikov and V. E. Kazarinov, Electrochim. Acta, 39, 2195 (1994).

    Article  CAS  Google Scholar 

  24. J. G. Gordon, O. R. Melroy and M. F. Toney, Electrochim. Acta, 40, 3 (1995).

    Article  CAS  Google Scholar 

  25. T. Matsui, Denki Kagaku, 63, 275 (1995).

    Article  CAS  Google Scholar 

  26. E. Spohr, G. Toth and K. Heinzinger, Electrochim. Acta, 41, 2131 (1996).

    Article  CAS  Google Scholar 

  27. F. Kitamura, T. Ohsaka and K. Tokuda, Electrochim. Acta, 42, 1235 (1997).

    Article  CAS  Google Scholar 

  28. Z. Borkowska, J. Electroanal. Chem., 63, 379 (1975).

    Article  CAS  Google Scholar 

  29. O. Fischer, S. Standara and J. Totusek, Collect. Czech. Chem. Commun, 39, 924 (1994).

    Article  Google Scholar 

  30. W. Lorenz and F. Mockel, Z. Elektrochem., 60, 507 (1956).

    CAS  Google Scholar 

  31. W. Lorenz and F. Mockel, Z. Elektrochem., 60, 939 (1956).

    CAS  Google Scholar 

  32. L. K. Partridge, A. C. Tansley and A. S. Porter, Electrochim. Acta, 13, 2029 (1968).

    Article  CAS  Google Scholar 

  33. R. S. Hansen, R. E. Minturn and D. A. Hickson, J. Phys. Chem, 61, 953 (1957).

    Article  CAS  Google Scholar 

  34. V. K. Venkatesan, B. B. Damaskin and N. V. Nikolaeva-Fedorovich, J. Electroanal. Chem., 25, 85 (1970).

    Article  CAS  Google Scholar 

  35. J. Lipkowski and Z. Galus, J. Electroanal. Chem., 61, 11 (1975).

    Article  CAS  Google Scholar 

  36. H. A. Laitinen and B. Mosier, J. Am. Chem. Soc., 80, 2363 (1958).

    Article  CAS  Google Scholar 

  37. B. B. Damaskin and V. E. Kazarinov, “The Double Layer”, in “Comprehensive Treatise of Electrochemistry”, ed. J. O’M. Bockris, B. E. Conway, E. Yeager, Vol. 1, p. 353, Plenum, New York, 1980.

    Article  CAS  Google Scholar 

  38. J. Goodisman, “Electrochemistry: TheoreticalFundations”, p. 71, John Wiley & Sons, New York, 1987.

    Google Scholar 

  39. J. O’M. Bockris, M. A. V. Devanathan and K. Muller, Proc. Roy. Soc. London, A274, 55 (1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Education, Kochi University, Akebono-cho, Kochi, 780-8520, Japan

    Hiromiti Sawamoto

Authors
  1. Hiromiti Sawamoto
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sawamoto, H. Adsorption-Desorption Studies of Ketones at a Hanging Mercury Drop Electrode by a Flow Injection Method. ANAL. SCI. 15, 73–78 (1999). https://doi.org/10.2116/analsci.15.73

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.15.73

Keywords

Search

Navigation