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The abundant oxygen vacancy on CuInS2/BiOBr composite catalyst cooperated with the double Fenton system to perform efficient heterogeneous Fenton degradation of levofloxacin

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Abstract

In this study, we prepared a series of heterogeneous Fenton catalytic materials x-CuInS2/BiOBr(x = 10–60 wt%, x-CIS/BiOBr) for the degradation of levofloxacin (LVF) by in- situ hydrothermal synthesis. X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) show that the x-CIS/BiOBr heterogeneous Fenton catalyst has abundant oxygen vacancy (OVs). The experimental results showed that the degradation rate of LVF by 40%-CIS/BiOBr reached 94.1% within 60 min, and the apparent rate constant was 0.0439 min−1, 8.92 times that of CuInS2 and 10.4 times that of BiOBr, respectively. The BET-specific surface area and pore volume were approximately 10 times and 7 times that of pure CuInS2 and BiOBr. Based on the characterization and quenching experiments results, the catalytic mechanism of synergistic interaction between the dual Fenton system (In3+/In+ and Cu+/Cu2+) and OVs was proposed, the possible degradation pathways of LVF were analyzed, and the toxicity of its intermediates was evaluated.

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Acknowledgments

The authors would like to acknowledge the Analysis and Testing Center of SEU for its instrumental and technical support.

Funding

This work was supported by the innovation platform project of Jiangsu Province (No. 6907041203) for its financial support.

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  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Fukang Teng, Min Wu, Min Zhao, Lin He, Chaohua Dai, Jiaxuan Li, Yongliang Sang & Yu Li

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Contributions

Fukang Teng: conceptualization, investigation, writing—original draft. Min Zhao: methodology, writing—review & editing. Lin He: software. Chaohua Dai: visualization. Jiaxuan Li: validation. Yongliang Sang: validation. Yu Li: formal analysis. Min Wu: resources, supervision, writing—review & editing, funding acquisition.

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Teng, F., Wu, M., Zhao, M. et al. The abundant oxygen vacancy on CuInS2/BiOBr composite catalyst cooperated with the double Fenton system to perform efficient heterogeneous Fenton degradation of levofloxacin. Journal of Materials Research 39, 412–426 (2024). https://doi.org/10.1557/s43578-023-01234-z

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