Abstract
Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.
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Original Russian Text © M.G. Abdullaev, Z.G. Gebekova, 2016, published in Neftekhimiya, 2016, Vol. 56, No. 2, pp. 166–170.
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Abdullaev, M.G., Gebekova, Z.G. Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins. Pet. Chem. 56, 146–150 (2016). https://doi.org/10.1134/S096554411602002X
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DOI: https://doi.org/10.1134/S096554411602002X