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Synthesis of 2-alkyl(aryl)thietanes

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Abstract

Thietane and its 2-substituted derivatives were synthesized. A general preparation procedure for the synthesis of thietanes bearing alkyl and aryl substituents in the α-position was developed. Using this procedure, 2-substituted thietanes can be obtained from cheap and easily accessible raw materials in three steps. 2-R-Thietanes (where R = H, CH3, C4H9, C5H11, C6H13, C6H5) and the corresponding sulfoxides and sulfones were synthesized and examined. Intermediate and by-products of the synthesis were studied.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    N. P. Volynskii & S. E. Shevchenko

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  1. N. P. Volynskii
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  2. S. E. Shevchenko
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Original Russian Text © N.P. Volynskii, S.E. Shevchenko, 2007, published in Neftekhimiya, 2007, Vol. 47, No. 2, pp. 125–133.

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Volynskii, N.P., Shevchenko, S.E. Synthesis of 2-alkyl(aryl)thietanes. Pet. Chem. 47, 109–117 (2007). https://doi.org/10.1134/S0965544107020089

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