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Sodium Sulfide in the Synthesis of N-Alkyl-1,3,5-dithiazinanes and 1,3,5-Thiadiazinanes

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Abstract

An approach to the synthesis of 1,3,5-dithiazinanes and 1,3,5-thiadiazinanes was developed based on the cyclothiomethylation of aliphatic amines with 9-aqueous Na2S and CH2O. Linear aliphatic primary amines form predominantly 1,3,5-thiadiazinanes, while branched ones lead to the formation of 1,3,5-dithiazinanes.

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Funding

The work was carried out within the framework of the project part of the state assignment (AAAA-A19-119022290010-9) using the equipment of the Center for collective use “Agidel” at the Institute of Catalysis and Petrochemicals Ufa Federal Research Center of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia

    G. R. Khabibullina, D. K. Yapparova, A. G. Ibragimov & V. R. Akhmetova

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  1. G. R. Khabibullina
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  2. D. K. Yapparova
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  3. A. G. Ibragimov
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  4. V. R. Akhmetova
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Correspondence to V. R. Akhmetova.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 8, pp. 1177–1183 https://doi.org/10.31857/S0044460X21080059.

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Khabibullina, G.R., Yapparova, D.K., Ibragimov, A.G. et al. Sodium Sulfide in the Synthesis of N-Alkyl-1,3,5-dithiazinanes and 1,3,5-Thiadiazinanes. Russ J Gen Chem 91, 1453–1458 (2021). https://doi.org/10.1134/S1070363221080053

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  • DOI: https://doi.org/10.1134/S1070363221080053

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