Abstract
In this work, the photo-physical properties of seven different phthalocyanine derivatives are studied, with a focus on their transparency spectral range. Two compounds among them are recently synthesized. The investigations include synthesis, photoluminescence, absorptive and refractive nonlinear properties, and optical limiting performances. The compounds are found to be emitting interesting broad fluorescence bands in the visible range. The nonlinear optical properties are investigated with the help of Z-scan technique, with both a continuous laser at 488, 514.5, and 632.8 nm, and with a pulsed laser at 532 nm. The sign and the magnitude of the nonlinear refractive index, third-order susceptibility, and nonlinear absorption coefficient have been evaluated in the seven compounds. The optical limiting performance of each compound was also evaluated in the continuous and pulsed laser excitation regimes.
Similar content being viewed by others
REFERENCES
G. de la Torre, P. Vazquez, F. Agullo-Lopez, and T. Torres, Chem. Rev. 104, 3723 (2004).
A. G. Gürek and Ö. Bekaroğlu, Dalton Trans., 1419 (1994). https://doi.org/10.1039/DT9940001419
E. Ule, Measurement of the Nonlinear Refractive Index by Z-scan Technique (Univ. Ljubljana, Slovenia, 2015), p. 4.
A. Erdoğmuş and T. Nyokong, Polyhedron 28, 2855 (2009).
C. G. Claessens, W. J. Blau, M. Cook, M. Hanack, R. J. Nolte, T. Torres, and D. Wöhrle, Monatsh. Chem. 132, 3 (2001).
Z. Li, X. Huang, S. Xu, Z. Chen, Z. Zhang, F. Zhang, and K. Kasatani, J. Photochem. Photobiol., A 188, 311 (2007).
M. H. Garcia, M. P. Robalo, A. R. Dias, M. T. Duarte, W. Wenseleers, G. Aerts, D. Goovaerts, M. P. Cifuentes, S. Hurst, M. G. Humphrey, et al., Organometallics 21, 2107 (2002).
K. Sakamoto and E. Ohno-Okumura, Materials 2, 1127 (2009).
T. Nyokong and E. Antunes, in Handbook of Porphyrin Science, With Applications to Chemistry, Physics, Materials Science, Engineering, Biology, and Medicine (World Scientific, Singapore, 2010), Vol. 7, p. 247.
R. S. S. Kumar, S. V. Rao, L. Giribabu, and D. N. Rao, in Nonlinear Frequency Generation and Conversion: Materials, Devices, and Applications VII, Proc. SPIE 6875, 68751D (2008).
A. Tuhl, W. Chidawanayika, H. Mohamed Ibrahim, N. Al-Awadi, Ch. Litwinski, T. Nyokong, H. Behbehani, H. Manaa, and S. Makhseed, J. Porphyr. Phthalocyan. 16, 163 (2012).
S. Mathews, S. C. Kumar, L. Giribabu, and S. V. Rao, Opt. Commun. 280, 206 (2007).
E. Ule, Measurement of The Nonlinear Refractive Index by Z-scan Technique (Univ. Ljubljana, Slovenia, 2015), p. 4.
T. V. Basova, R. G. Parkhomenko, M. Polyakov, A. G. Gürek, D. Atilla, F. Yuksel, E. I. Ryabchikova, B. Y. Kadem, and A. K. Hassan, Dyes Pigments 125, 266 (2016).
P. M. Burnham, M. J. Cook, L. A. Gerrard, M. J. Heeney, and D. L. Hughes, Chem. Commun., 2064 (2003). https://doi.org/10.1039/B304173P
S. Z. Topal, K. Ertekin, A. G. Gürek, B. Yenigül, and V. Ahsen, Sens. Actuators B 156, 236 (2011).
S. V. Rao, D. N. Rao, J. Akkara, B. de Cristofano, and D. Rao, Chem. Phys. Lett. 297, 491 (1998).
M. Sheik-Bahae, M. Sheik-Bahae, A. A Said, T. H. Wei, and D. J. Hagan, and E. W. van Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
P.-C. Lo, X. Leng, and D. K. Ng, Coord. Chem. Rev. 251, 2334 (2007).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Manaa, H., Attila, D., Gürek, A.G. et al. Synthesis, Fluorescence and Nonlinear Optical Properties of Phthalocyanine Derivatives in the Continuous-Wave and Pulsed Excitation Regimes. Opt. Spectrosc. 129, 628–640 (2021). https://doi.org/10.1134/S0030400X21050064
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X21050064