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SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL

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Abstract

A Co(II) complex with 1-{1-[2-(o-tolyloxy)ethyl]-1H-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)3]2+·2(NO3)–·2H2O·2CH3OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group P21/c. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN3O3 corresponds to a distorted octahedron.

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation (State Assignment in the Field of Scientific Activity for the Southern Federal University, project 0852-2020-0031).

The XRD studies were performed using the equipment of the Shared Facility Center at the Kurnakov Institute of General and Inorganic Chemistry.

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Authors and Affiliations

  1. Southern Federal University, Institute of Physical and Organic Chemistry, Rostov-on-Don, Russia

    A. S. Burlov, L. N. Divaeva, Yu. V. V. Koshchienko, B. V. Chaltsev & S. A. Mashchenko

  2. Southern Federal University, Research Institute of Physics, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Kiskin

Authors
  1. A. S. Burlov
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  2. L. N. Divaeva
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  3. V. G. Vlasenko
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  4. Yu. V. V. Koshchienko
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  5. B. V. Chaltsev
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  6. S. A. Mashchenko
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  7. M. A. Kiskin
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Correspondence to V. G. Vlasenko.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 8, 96118.https://doi.org/10.26902/JSC_id96118

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Burlov, A.S., Divaeva, L.N., Vlasenko, V.G. et al. SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL. J Struct Chem 63, 1284–1290 (2022). https://doi.org/10.1134/S0022476622080091

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