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SYNTHESIS AND CRYSTAL STRUCTURE OF COBALT(III) COMPLEXES WITH SUBSTITUTED 2-[(BENZIMIDAZOLE-1-YL) IMINOMETHYL]PHENOLS

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Abstract

Two Co(III) complexes are synthesized based on 2-{(E)-[2-(hydroxy(alkyl)amino)benzimidazole-1-yl]iminomethyl}phenol (H3L1 and H3L2, alkyl is ethyl or propyl). By the elemental analysis and IR spectroscopy it is established that the obtained complexes have the compositions [Co(H2L1)(HL1)]·2C2H5OH and [Co(H2L2)(HL2)]CH3OH·1/2H2O. Their crystal and molecular structures are determined by single crystal X-ray diffraction (XRD). From the XRD data it is found that the complexes crystallize in the triclinic space group \(P\bar{1}\) as solvates with alcohol and water molecules. In mononuclear molecules of both complexes, two trischelate ligands in mono- and dianionic forms are coordinated to the Co(III) cation. The coordination environment of the cobalt atom CoN4O2 corresponds to a distorted octahedron in both compounds.

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Funding

The work was supported by the Ministry of Science and Higher Education of The Russian Federation (State Assignment in the Scientific Activity Area at the Southern Federal University, Project 0852-2020-0031).

The single crystal XRD study was performed using the facilities of the Research Equipment Sharing Center of Physical Methods for Studying Substances and Materials of the Institute of General and Inorganic Chemistry of the Russian Academy of Science.

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Authors and Affiliations

  1. Southern Federal University, Research Institute of Physical and Organic Chemistry, Rostov-on-Don, Russia

    A. S. Burlov, T. A. Kuzmenko, Yu. V. Koshchienko, S. A. Mashchenko, B. V. Chaltsev & A. A. Kolodina

  2. Southern Federal University, Research Institute of Physics, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Kiskin

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  1. A. S. Burlov
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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 2068-2076.https://doi.org/10.26902/JSC_id84803

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Burlov, A.S., Kuzmenko, T.A., Vlasenko, V.G. et al. SYNTHESIS AND CRYSTAL STRUCTURE OF COBALT(III) COMPLEXES WITH SUBSTITUTED 2-[(BENZIMIDAZOLE-1-YL) IMINOMETHYL]PHENOLS. J Struct Chem 62, 1946–1954 (2021). https://doi.org/10.1134/S0022476621120131

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