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Zirconium (Hafnium)-Containing Yttriumoxane Alumoxanes and Multicomponent Ceramics Based on Them

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Ceramic-forming zirconium (hafnium)-containing yttriumoxane alumoxanes, precursors of multicomponent ceramics based on alumina, yttria and zirconia/hafnia, were synthesized by co-condensation of chelated alkoxyalumoxanes, yttrium acetylacetonate hydrate (or organic yttriumoxane alumoxanes) and zirconium or hafnium acetylacetonate. The physicochemical properties of zirconium (hafnium)-containing yttriumoxane alumoxanes were studied. Computational models of the group and elemental composition of oligomeric Zr(Hf)-containing yttriumoxane alumoxane molecules were proposed. According to X-ray diffraction and scanning electron microscopy data, pyrolysis of the oligomers at 1500–1600°C results in multicomponent nano- or fine-crystalline ceramic powders, depending on the Al/Y and Al/Zr(Hf) molar ratios.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. State Research Institute for Chemistry and Technology of Organoelement Compounds, 105118, Moscow, Russia

    G. I. Shcherbakova, A. S. Pokhorenko, N. S. Krivtsova, M. S. Varfolomeev, A. I. Drachev, J. B. Lebed, T. L. Apuhtina, A. E. Chernyshev & P. A. Storozhenko

  2. Moscow Aviation Institute (National Research University), 125080, Moscow, Russia

    M. S. Varfolomeev

  3. Institute for Nuclear Research, Russian Academy of Sciences, 117312, Moscow, Russia

    J. B. Lebed

  4. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    A. A. Ashmarin

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  1. G. I. Shcherbakova
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  2. A. S. Pokhorenko
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  3. N. S. Krivtsova
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  4. M. S. Varfolomeev
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  8. T. L. Apuhtina
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  9. A. E. Chernyshev
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  10. P. A. Storozhenko
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Correspondence to G. I. Shcherbakova.

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Translated by Z. Svitanko

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Shcherbakova, G.I., Pokhorenko, A.S., Krivtsova, N.S. et al. Zirconium (Hafnium)-Containing Yttriumoxane Alumoxanes and Multicomponent Ceramics Based on Them. Russ. J. Inorg. Chem. 68, 1657–1673 (2023). https://doi.org/10.1134/S0036023623602155

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