Abstract
An original method for producing a ceramic material based on silicon carbide (SiC) and its composite with the addition of hafnium diboride (SiC–HfB2) from organic raw materials of natural origin is presented. The originality of the method is in the use of the spark plasma sintering-reactive synthesis of a powder mixture based on the product of thermal oxidative treatment of rice husk (RH). The formation of a ceramic product based on SiC occurs through an in situ reaction in the SiO2–C system constituting the basis of RH, which is initiated by spark plasma heating. The phase formation and structure formation of ceramics have been studied by X-ray diffraction analysis, Raman spectroscopy, and scanning electron microscopy; in addition, the physical and mechanical properties of ceramic materials have been reported. The influence of the SiC : HfB2 ratio on the density, hardness, and homogeneity in the microstructural organization of the ceramic composite SiC–HfB2 has been demonstrated. The unconventional method represents an obvious prospect for an efficient and cost-effective approach to obtaining high-quality SiC ceramics and its high-temperature SiC–HfB2 composites for a wide range of practical applications.
Similar content being viewed by others
REFERENCES
J.-H. Eom, Y.-W. Kim, and S. Raju, Integr. Med. Res. 1, 220 (2013). https://doi.org/10.1016/j.jascer.2013.07.003
E. P. Simonenko, A. V. Derbenev, N. P. Simonenko, et al., Russ. J. Inorg. Chem. 62, (2017). https://doi.org/10.1134/S0036023617070221
E. P. Simonenko, N. P. Simonenko, M. A. Zharkov, et al., J. Mater. Sci. 50, 733 (2014). https://doi.org/10.1007/s10853-014-8633-1
D. Das, K. Nijhuma, A. M. Gabriel, et al., J. Eur. Ceram. Soc. 40, 2163 (2020). https://doi.org/10.1016/j.jeurceramsoc.2020.01.034
N. D. Shcherban, J. Ind. Eng. Chem. 50 (2016), 15 (2017). https://doi.org/10.1016/j.jiec.2017.02.002
E. P. Simonenko, N. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 63, 1772 (2018). https://doi.org/10.1134/S003602361814005X
E. P. Simonenko, N. P. Simonenko, V. G. Sevastyanov, et al., Russ. J. Inorg. Chem. 64, 1697 (2019). https://doi.org/10.1134/S0036023619140079
E. P. Simonenko, N. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 64, 1681 (2019). https://doi.org/10.1134/S0036023619130084
E. P. Simonenko, N. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 65, 606 (2020). https://doi.org/10.1134/S0036023620040191
T. Koyanagi, Y. Katoh, T. Nozawa, et al., J. Nucl. Mater. 511, 544 (2018). https://doi.org/10.1016/j.jnucmat.2018.06.017
Y. Katoh, L. L. Snead, I. Szlufarska, et al., Curr. Opin. Solid State Mater. Sci. 16, 143 (2012). https://doi.org/10.1016/j.cossms.2012.03.005
Y. Katoh and L. L. Snead, J. Nucl. Mater. 526, 151849 (2019). https://doi.org/10.1016/j.jnucmat.2019.151849
M. Tokita, in Handbook of Advanced Ceramic Materials, Applied Processes and Properties, Ed. by S. Somiya, 2nd ed. (Elsevier, 2013). https://doi.org/10.1016/B978-012654640-8/50007-9
E. K. Papynov, O. O. Shichalin, V. Y. Mayorov, et al., Nanotechnol. Russ. 12, 49 (2017). https://doi.org/10.1134/S1995078017010086
Z.-Y. Hu, Z.-H. Zhang, X.-W. Cheng, et al., Mater. Des. 191, 108662 (2020). https://doi.org/10.1016/j.matdes.2020.108662
T. L. Simonenko, M. V. Kalinina, N. P. Simonenko, et al., Int. J. Hydrogen Energy 44, 20345 (2019). https://doi.org/10.1016/j.ijhydene.2019.05.231
A. P. Kreshkov, Foundations of Analytical Chemistry, Physicochemical (Instrumental) Methods of Analysis (Khimiya, Moscow, 1970) [in Russian].
T. L. Simonenko, M. V. Kalinina, N. P. Simonenko, et al., Ceram. Int. 44, 19879 (2018). https://doi.org/10.1016/j.ceramint.2018.07.249
E. K. Papynov, O. O. Shichalin, M. A. Medkov, et al., Glas. Phys. Chem. 44, 632 (2018). https://doi.org/10.1134/S1087659618060159
V. G. Sevast’yanov, E. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 58, 1269 (2013). https://doi.org/10.1134/S003602361311017X
V. G. Sevastyanov, E. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 59, 1361 (2014).
V. G. Sevastyanov, E. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 59, 1298 (2014). https://doi.org/10.1134/S0036023614110217
E. P. Simonenko, A. N. Gordeev, N. P. Simonenko, et al., Russ. J. Inorg. Chem. 61, 1203 (2016). https://doi.org/10.1134/S003602361610017X
E. P. Simonenko, N. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 63, 421 (2018). https://doi.org/10.1134/S0036023618040186
D. V. Dudina and A. K. Mukherjee, J. Nanomater. 2013, 625218 (2013). https://doi.org/10.1155/2013/625218
E. K. Papynov, O. O. Shichalin, I. Y. Buravlev, et al., Russ. J. Inorg. Chem. 65, 263 (2020). https://doi.org/10.1134/S0036023620020138
G. Shao, X. Zhao, H. Wang, et al., Int. J. Refract. Met. Hard Mater. 60, 104 (2016). https://doi.org/10.1016/j.ijrmhm.2016.07.011
Q. Guo, J. Li, Q. Shen, et al., Mater. Sci. Eng., A 558, 186 (2012). https://doi.org/10.1016/j.msea.2012.07.109
E. K. Papynov, O. O. Shichalin, I. Y. Buravlev, et al., Vacuum 180, 109628 (2020). https://doi.org/10.1016/j.vacuum.2020.109628
L. Wang, J. Zhang, and W. Jiang, Int. J. Refract. Met. Hard Mater. 39, 103 (2013). https://doi.org/10.1016/j.ijrmhm.2013.01.017
E. K. Papynov, O. O. Shichalin, Y. E. Skurikhina, et al., Ceram. Int. 45, 13838 (2019). https://doi.org/10.1016/j.ceramint.2019.04.081
R. Licheri, C. Musa, R. Orru, et al., J. Alloys Compd. 663, 351 (2016). https://doi.org/10.1016/j.jallcom.2015.12.096
E. P. Simonenko, N. P. Simonenko, E. K. Papynov, et al., J. Sol-Gel Sci. Technol. 82, 748 (2017). https://doi.org/10.1007/s10971-017-4367-2
V. Rodriguez-Lugo, E. Rubio, I. Gomez, et al., Int. J. Environ. Pollut. 18, 378 (2002). https://doi.org/10.1504/IJEP.2002.003734
L. Sun and K. Gong, Ind. Eng. Chem. Res. 40, 5861 (2001). https://doi.org/10.1021/ie010284b
S. K. S. Hossain, L. Mathur, and P. K. Roy, J. Asian Ceram. Soc. 6, 299 (2018). https://doi.org/10.1080/21870764.2018.1539210
T. Ya. Kosolapova, T. V. Andreeva, T. B. Bartintskaya, et al., Refractory Nonmetal Compounds (Metallurgiya, Moscow, 1985) [in Russian].
ACKNOWLEDGMENTS
This research has been performed with the use of facilities of the interdisciplinary center for collective use in the field of nanotechnology and new functional materials (FEFU, Vladivostok).
Funding
The study was carried out as part of the State assignment of the Ministry of Science and Higher Education of the Russian Federation (topic no. 00657-2020-0006).
X-ray diffraction analysis of the samples was carried out within the framework of the State assignment of the Institute of Chemistry, Far Eastern Branch, RAS (topic no. 0205-2021-0001).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflict of interest.
Additional information
Translated by G. Kirakosyan
Rights and permissions
About this article
Cite this article
Shapkin, N.P., Papynov, E.K., Shichalin, O.O. et al. Spark Plasma Sintering-Reactive Synthesis of SiC and SiC–HfB2 Ceramics Based on Natural Renewable Raw Materials. Russ. J. Inorg. Chem. 66, 629–637 (2021). https://doi.org/10.1134/S0036023621050168
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023621050168