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Identification of the Reaction Mechanism of Linear Irreversible Sequential Reactions

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Abstract

The article shows how the analysis of limited kinetic data (separate kinetic curves or even parts of them) for the set of sequential reactions with close values of the rate constants of separate stages allows one to get insight into the reaction mechanism, in particular, to find the stage number in which the substance with the constructed kinetic curve is present. The proposed method gives the plausible results when analyzing well-known kinetic curves of hydrocarbon oxidation.

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REFERENCES

  1. Eigen, M., Selforganization of Matter and the Evolution of Biological Macromolecules, Berlin: Springer, 1971.

    Book  Google Scholar 

  2. Eigen, M. and Schuster, P., The Hypercycle. A Principle of Natural Self-Organization, Berlin: Springer, 1979.

    Google Scholar 

  3. Varfolomeev, S.D., Kots, E.D., Lushchekina, S.V., Nemukhin, A.V., and Khrenova, M.G., Dokl. Phys. Chem., 2017, vol. 474, no. 2, p. 89.

    Article  CAS  Google Scholar 

  4. Khrenova, M.G., Kots, E.D., Varfolomeev, S.D., Lushchekina, S.V., and Nemukhin, A.V., J. Phys. Chem., 2017, vol. 121, p. 9389.

    Article  CAS  Google Scholar 

  5. Semenova, N.A., Akhadov, T.A., Petryaikin, A.V., Sidorin, S.S., Lukovenkov, A.V., and Varfolomeev, S.D., Biochem. (Moscow), 2012, vol. 77, p. 388.

    Article  CAS  Google Scholar 

  6. Ublinskii, M.V., Semenova, N.A., Akhadov, T.A., Mel’nikov, I.A., and Varfolomeev, S.D., Russ. Chem. Bull., 2015, vol. 64, p. 451.

    Article  CAS  Google Scholar 

  7. Bykov, V.I., Lukovenkov, A.V., and Varfolomeev, S.D., Dokl. Biochem. Biophys. 2017, vol. 474, no. 3, p. 189.

    Article  CAS  Google Scholar 

  8. Pryamye i obratnye zadachi v khimicheskoi kinetike (Direct and Inverse Problems in Chemical Kinetics) Bykov, V.I., Eds., Novosibirsk: Nauka. Sibirskoe otdelenie, 1993.

  9. Yablonsky, G.S., Branco, P.D., Marin, G.B., and Constales, D., Chem. Eng. Sci., 2019, no. 196, p. 384.

  10. Xi, Y., Liu, X., Constales, D., and Yablonsky, G.S., Entropy, 2020, no. 22, p. 1160.

  11. Gevertz, J.L., Dunn, S.M., and Roth, Ch.M., Biotechnol. Bioeng., 2005, vol. 92, no. 3, p. 346.

    Article  CAS  Google Scholar 

  12. Rodigin, N.M. and Rodigina, E.N., Posledovatel’nye khimicheskie reaktsii. Matematicheskii analiz i raschet (Serial Chemical Reactions. Mathematical Analysis and Calculation), Moscow: AS USSR, 1960.

    Google Scholar 

  13. Malyshev, V.P., Turdukodzhaeva, A.M., and Kaikenov, D.A., Dokl. Nats. Akad. Nauk Resp. Kazakhstan, Ser. Matematika, 2012, no. 4, p. 5.

  14. Berezin, I.V., Denisov, E.T., and Emanuel’, N.M., Okislenie tsiklogeksana (Oxidation of Cyclohexane), Moscow: Moscow State University, 1962.

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Funding

This work was partially supported by grant no. 16-03-00123A (2016–2018) from the Russian Foundation for Basic Research and by grant no. 18-13-00030 (2018–2020) from the Russian Science Foundation.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    A. V. Lukovenkov, V. I. Bykov & S. D. Varfolomeev

  2. Institute of Physicochemical Foundations of the Functioning of Neural Network and Artificial Intellegence, Moscow State University, 119192, Moscow, Russia

    V. I. Bykov & S. D. Varfolomeev

  3. Department of Chemical Enzymology, Faculty of Chemistry, Moscow State University, 119192, Moscow, Russia

    S. D. Varfolomeev

Authors
  1. A. V. Lukovenkov
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  2. V. I. Bykov
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  3. S. D. Varfolomeev
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Corresponding author

Correspondence to A. V. Lukovenkov.

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The authors declare that they have no conflicts of interest.

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Translated by O. Kadkin

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Lukovenkov, A.V., Bykov, V.I. & Varfolomeev, S.D. Identification of the Reaction Mechanism of Linear Irreversible Sequential Reactions. Kinet Catal 62, 557–564 (2021). https://doi.org/10.1134/S0023158421050037

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  • DOI: https://doi.org/10.1134/S0023158421050037

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