Abstract
The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 6, pp. 1214–1220, July–August, 2017.
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Fedorenko, A.D., Mazalov, L.N., Fursova, E.Y. et al. X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes. J Struct Chem 58, 1166–1172 (2017). https://doi.org/10.1134/S0022476617060142
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DOI: https://doi.org/10.1134/S0022476617060142