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Solid Products of NO3 Uptake on Methane Soot

  • Chemical Physics of Atmospheric Phenomena
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Abstract

A soot coating was treated with NO3 radicals using a flow reactor having a movable insert and coupled to a mass spectrometer for kinetic studies; the treatment was performed until the surface completely stopped to trap the radicals. The chromatographic and mass spectrometry analyses of the composition of the original methane soot and the solid products of its reaction with the gas-phase NO3 oxidant showed that the main products of this heterogeneous reaction were phthalic acid derivatives, paraffins, and acetophenones. The untreated soot contained arenes (up to four-membered aromatic molecules). The nitro compounds were not detected in the original soot and the products of its treatment with NO3 radicals.

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References

  1. W. S. Goliff, M. Luria, D. R. Blake, et al., Atmos. Environ. 114, 102 (2015).

    Article  CAS  Google Scholar 

  2. N. Sobanski, M. J. Tang, J. Thieser, et al., Atmos. Chem. Phys. 16, 4867 (2016).

    Article  CAS  Google Scholar 

  3. S. S. Brown, W. P. Dubé, J. Peischl, et al., J. Geophys. Res. 116D, 24305 (2011).

    Google Scholar 

  4. M. Martinez, D. Perner, E.-M. Hackenthal, et al., J. Geophys. Res. 105D, 22685 (2000).

    Article  Google Scholar 

  5. D. Stadler and M. J. Rossi, Phys. Chem. Chem. Phys. 2, 5420 (2000).

    Article  CAS  Google Scholar 

  6. J. B. Cohen and C. Wang, J. Geophys. Res. Atmos. 119, 307 (2014).

    Article  CAS  Google Scholar 

  7. R. Mahmood, K. von Salzen, M. Flanner, et al., J. Geophys. Res. Atmos. 121, 7100 (2016).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. U. Kirchner, V. Scheer, and R. Vogt, J. Phys. Chem. A 104, 8908 (2000).

    Article  CAS  Google Scholar 

  9. F. Arens, L. Gutzwiller, U. Baltensperger, et al., Environ. Sci. Technol. 35, 2191 (2001).

    Article  CAS  PubMed  Google Scholar 

  10. M. S. Akhter, A. R. Chughtai, and D. M. Smith, Appl. Spectrosc. 39, 143 (1985).

    Article  CAS  Google Scholar 

  11. J. Ringuet, A. Albinet, E. Leoz-Garziandia, et al., Atmos. Environ. 61, 15 (2012).

    Article  CAS  Google Scholar 

  12. M. S. Salgado and M. J. Rossi, Int. J. Chem. Kinet. 34, 620 (2002).

    Article  CAS  Google Scholar 

  13. A. A. Onischuk, S. di Stasio, V. V. Karasev, et al., J. Aerosol Sci. 34, 383 (2003).

    Article  CAS  Google Scholar 

  14. R. A. Dobbings, Aerosol Sci. Technol. 41, 485 (2007).

    Article  CAS  Google Scholar 

  15. S. O. Baek, R. A. Field, M. E. Goldstone, et al., Water, Air, Soil Pollut. 60, 279 (1991).

    Article  CAS  Google Scholar 

  16. W.-J. Hong, H. Jia, W.-L. Ma, et al., Environ. Sci. Technol. 50, 7163 (2016).

    Article  CAS  PubMed  Google Scholar 

  17. J. N. Pitts, Jr., B. Zielinska, J. A. Sweetman, et al., Atmos. Environ. 19, 911 (1985).

    Article  CAS  Google Scholar 

  18. J. L. Durant, A. L. Lafleur, E. F. Plummer, et al., Environ. Sci. Technol. 32, 1894 (1998).

    Article  CAS  Google Scholar 

  19. F. Karagulian and M. J. Rossi, J. Phys. Chem. A 111, 1914 (2007).

    Article  CAS  PubMed  Google Scholar 

  20. H. Saathoff, K.-H. Naumann, N. Riemer, et al., Geophys. Res. Lett. 28, 1957 (2001).

    Article  CAS  Google Scholar 

  21. J. Mak, S. Gross, and A. K. Bertram, Geophys. Res. Lett. 34, L10804 (2007).

    Article  CAS  Google Scholar 

  22. V. V. Zelenov, E. V. Aparina, S. A. Kashtanov, and E. V. Shardakova, Russ. J. Phys. Chem. B 11, 180 (2017).

    Article  CAS  Google Scholar 

  23. V. V. Zelenov, E. V. Aparina, A. V. Chudinov, and S. A. Kashtanov, Russ. J. Phys. Chem. B 4, 399 (2010).

    Article  Google Scholar 

  24. V. V. Zelenov, E. V. Aparina, S. A. Kashtanov, and E. V. Shardakova, Russ. J. Phys. Chem. B 10, 172 (2016).

    Article  CAS  Google Scholar 

  25. www.sisweb.com/software/ms/nist.htm.

  26. U. Poschl, Y. Rudich, and M. Ammann, Atmos. Chem. Phys. 7, 5989 (2007).

    Article  Google Scholar 

  27. M. Shiraiwa, R. M. Garland, and U. Poschl, Atmos. Chem. Phys. 9, 9571 (2009).

    Article  CAS  Google Scholar 

  28. C. Kaiser, N. Riemer, and D. A. Knopf, Atmos. Chem. Phys. Discuss. 11, 5127 (2011).

    Article  Google Scholar 

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Authors and Affiliations

  1. Talrose Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Zelenov, E. V. Aparina, V. I. Kozlovskiy & I. V. Sulimenkov

  2. Sechenov First Moscow State Medical University, Moscow, 119146, Russia

    D. A. Kardonsky & A. E. Nosyrev

Authors
  1. V. V. Zelenov
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  2. E. V. Aparina
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  3. V. I. Kozlovskiy
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  4. I. V. Sulimenkov
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  5. D. A. Kardonsky
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  6. A. E. Nosyrev
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Correspondence to V. V. Zelenov.

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Zelenov, V.V., Aparina, E.V., Kozlovskiy, V.I. et al. Solid Products of NO3 Uptake on Methane Soot. Russ. J. Phys. Chem. B 13, 219–224 (2019). https://doi.org/10.1134/S1990793119010160

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  • DOI: https://doi.org/10.1134/S1990793119010160

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