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Reaction of polyvinyl chloride with calcium and magnesium oxides

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

Reaction of polyvinyl chloride with calcium and magnesium oxides was studied. The dependence of binding with metal oxides of hydrogen chloride formed by polyvinyl chloride dehydrochlorination on the oxide to polymer weight ratio and on temperature was examined. The activation energies and specific rates of formation of the corresponding metal chlorides were calculated. Conditions of complete chloride binding into environmentally safe products were found.

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References

  1. RF Patent 2 100 702.

  2. Yanborisov, V.M. and Minsker, K.S., Vysokomol. Soedin., Ser. A, 2002, vol. 44, no. 5, pp. 857–862.

    CAS  Google Scholar 

  3. Jordan, K.J., Suib, S.L., and Koberstein, J.T., J. Phys. Chem. B, 2001, vol. 105, no. 16, pp. 3174–3181.

    Article  CAS  Google Scholar 

  4. Wang Pong-Li, Xu Xiao-Bai, Zheng Ming-Hui, and Chung, H., Acta Chim. Sin., 2000, vol. 58, no. 12, pp. 1681–1684.

    CAS  Google Scholar 

  5. Cheng Wu Hsun and Liang, Y.C., J. Appl. Polym. Sci., 2000, vol. 77, no. 11, pp. 2464–2471.

    Article  CAS  Google Scholar 

  6. Li Shuiquing, Chi Yong, Li Weiwu, et al., J. Environ. Sci., 2001, vol. 22, no. 2, pp. 95–100.

    Google Scholar 

  7. Minsker, K.S., Kolesov, S.V., and Zaikov, G.E., Starenie i stabilizatsiya polimerov na osnove vinilkhlorida (Aging and Stabilization of Polymers Based on Vinyl Chloride) Moscow: Nauka, 1982.

    Google Scholar 

  8. Vrandecic, N.S., Klaric, I., and Kovacic, T., Polym. Degrad. Stab., 2004, vol. 84, no. 1, pp. 31–39.

    Article  CAS  Google Scholar 

  9. Berg, L.G., Vvedenie v termografiyu (Introduction to Thermography), Moscow: Akad. Nauk SSSR, 1961.

    Google Scholar 

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Original Russian Text © O.V. Rudometova, Zh.A. Vnutskikh, A.A. Fedorov, Yu.S. Chekryshkin, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 1, pp. 108–111.

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Rudometova, O.V., Vnutskikh, Z.A., Fedorov, A.A. et al. Reaction of polyvinyl chloride with calcium and magnesium oxides. Russ J Appl Chem 81, 104–107 (2008). https://doi.org/10.1134/S1070427208010242

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  • DOI: https://doi.org/10.1134/S1070427208010242

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