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Use of redox reagents for stabilization of Pu and Np valence forms in aqueous reprocessing of spent nuclear fuel: Chemical and technological aspects

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Radiochemistry Aims and scope

Abstract

Published data on properties of reagents used in aqueous reprocessing of spent nuclear fuel for controlling the Pu and Np valence are summarized. The chemical principles of the reactions of U(IV), NH2OH, HNO2 (nitrogen oxides), and H2O2 with Pu and Np ions in nitric acid solutions and specific features of the behavior of these elements in the course of fuel reprocessing are considered. The properties of new promising organic redox reagents for stabilization of Pu and Np valence forms in the PUREX process are briefly described.

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References

  1. Nash, K.L., in Proc. GLOBAL’2001, Paris (France), September 9–13, 2001, paper no. 249.

  2. Shibata, A., Nomura, K., Koizumi, T., and Koyama, T., in Proc. GLOBAL’2003, New Orleans (USA), November 16–20, 2003, pp. 2251–2254.

  3. Yano, K., Shibata, A., Nomura, K., et al., in Proc. GLOBAL’2005, Tsukuba (Japan), October 9–13, 2005, paper no. 118.

  4. Ohyama, K., Nomura, K., Washiya, T., et al., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 1461–1466.

  5. Wei, Y., Arai, T., Kumagai, M., and Bruggeman, A., in Proc. GLOBAL’2003, New Orleans (USA), November 16–20, 2003, pp. 479–484.

  6. Wei, Y., Arai, T., Hoshi, H., and Kumagai, M., in Proc. GLOBAL’2005, Tsukuba (Japan), October 9–13, 2005, paper no. 032.

  7. Blinova, I.V., Sokolova, I.D., and Shul’ga, N.A., Yadernyi toplivnyi tsikl za rubezhom v 2005–2006 g.g. (Sostoyanie promyshlennosti i osnovnye napravleniya NIOKR): Obzor (Nuclear Fuel Cycle Abroad in 2005–2006 (State of Industry and Main Lines of Research and Development): Review), Moscow: TsNIIAtominform, 2006.

    Google Scholar 

  8. Zilberman, B.Ya., Radiokhimiya, 2000, vol. 42, no. 1, pp. 3–15.

    Google Scholar 

  9. Uchiyama, G., Asakura, H., Hotoku, S., and Fujine, S., in Proc. RECOD’98, Nice (France), October 25–28, 1998, vol. 1, pp. 393–400.

  10. Mineo, H., Asakura, H., Hotoku, S., et al., in Proc. GLOBAL’2003, New Orleans (USA), November 16–20, 2003, pp. 1250–1255.

  11. Marchenko, V.I., Atom. Tekh. Rubezhom, 1987, no. 2, pp. 3–11.

  12. Schmieder, H. and Galla, U., J. Appl. Electrochem., 2000, vol. 30, pp. 201–207.

    Article  CAS  Google Scholar 

  13. Kosyakov, V.N. and Marchenko, V.I., Radiokhimiya, 2008, vol. 50, no. 4, pp. 289–300.

    Google Scholar 

  14. Denniss, I. and Jeaps, A., in Proc. RECOD’94, London (UK), 1994. vol. 1, Session 4B.

  15. Rovnyi, S.I. and Shevtsev, P.P., Vopr. Radiats. Bezopasn., 2007, no. 2, pp. 5–13.

  16. Marchenko, V.I. and Koltunov, V.S., Radiokhimiya, 1974, vol. 16, no. 4, pp. 486–502.

    CAS  Google Scholar 

  17. Ochsenfeld, W., and Schmieder, H., US Patent 3949049, 1976; Jenkins, I.L., Hydrometallurgy, 1979, vol. 4, no. 1, pp. 1–20.

    Article  Google Scholar 

  18. Koltunov, V.S., Taylor, R.J., Marchenko, V.I., et al., Radiochim. Acta, 2004, vol. 92, no. 7, pp. 387–394.

    Article  CAS  Google Scholar 

  19. Koltunov, V.S., Zhuravleva, G.I., Marchenko, V.I., et al., Radiochim. Acta, 2007, vol. 95, no. 10, pp. 559–567.

    Article  CAS  Google Scholar 

  20. Koltunov, V.S., Marchenko, V.I., Nikiforov, A.S., et al., At. Energ., 1986, vol. 60, no. 1, pp. 35–41.

    Article  CAS  Google Scholar 

  21. Popova, N.N., Tananaev, I.G., Rovnyi, S.I., and Myasoedov, B.F., Usp. Khim., 2003, vol. 72, no. 2, pp. 115–136.

    Google Scholar 

  22. Anan’ev, A.V. and Shilov, V.P., Radiokhimiya, 2006, vol. 48, no. 2, pp. 97–107.

    Google Scholar 

  23. Suslov, Yu.P., Ramazanov, L.M., and Borovinskii, V.A., Radiokhimiya, 1986, vol. 28, no. 2, pp. 177–185.

    CAS  Google Scholar 

  24. Koltunov, V.S. and Gomonova, T.V., Radiokhimiya, 1991, vol. 33, no. 5, pp. 107–117.

    CAS  Google Scholar 

  25. Koltunov, V.S., Taylor, R., Marchenko, V.I., et al., Radiokhimiya, 2007, vol. 49, no. 4, pp. 327–330.

    Google Scholar 

  26. Koltunov, V.S., Taylor, R.J., Marchenko, V.I., et al., Radiochim. Acta, 1999, vol. 86, no. 1, pp. 41–46.

    CAS  Google Scholar 

  27. Belyaev, E.M. and Mashkin, A.N., Abstracts of Papers, Vtoraya Rossiiskaya shkola po radiokhimii i yadernym tekhnologiyam (Second Russian School on Radiochemistry and Nuclear Technologies), Ozersk: Mayak, September 4–8, 2006, pp. 19–22.

    Google Scholar 

  28. Marchenko, V.I., Polunin, A.K., Zakharkin, B.S., et al., At. Energ., 1987, vol. 82, no. 2, pp. 155–157.

    Google Scholar 

  29. Mashkin, A.N. and Belyaev, E.M., Abstracts of Papers, Pyataya Rossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2006” (Fifth Russian Conf. on Radiochemistry “Radiochemistry-2006”), Dubna, October 23–27, 2006, Ozersk: Mayak, 2006, p. 198.

    Google Scholar 

  30. Marchenko, V.I., Rubisov, V.N., Revyakin, V.V., and Shmidt, V.S., At. Energ., 1987, vol. 62, no. 2, pp. 88–90.

    Article  CAS  Google Scholar 

  31. Revyakin, V.V., Marchenko, V.I., Gitkovich, E.S., et al., Radiokhimiya, 1983, vol. 25, no. 5, pp. 617–621.

    CAS  Google Scholar 

  32. Taylor, R.J., Hudson, P.I., and Phillips, C., in Proc. Int. Symp. “Back End of the Nuclear Fuel Cycle,” Vienna: IAEA, May 11–15, 1987, pp. 399–407.

    Google Scholar 

  33. Birkett, J., Carrot, M., Fox, O., et al., Chimia, 2005, vol. 59, no. 12, pp. 898–904.

    Article  CAS  Google Scholar 

  34. Rance, P., Chesnay, B., Killeen, T., et al., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 346–352.

  35. Mashkin, A.N., Korchenkin, K.K., and Svetlakova, N.A., Radiokhimiya, 2002, vol. 44, no. 1, pp. 34–40.

    Google Scholar 

  36. Koltunov, V.S., Taylor, R.J., Marchenko, V.I., et al., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 351–354.

  37. Taylor, R.J., Koltunov, V.S., Marchenko, V.I., et al., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 355–358.

  38. Koltunov, V.S., Taylor, R.J., Marchenko, V.I., et al., Radiochim. Acta, 2002, vol. 90, no. 5, pp. 259–265.

    Article  CAS  Google Scholar 

  39. Koltunov, V.S., Marchenko, V.I., Frolov, K.M., et al., Abstracts of Papers, Int. Conf. “Actinides’89,” Tashkent (USSR), September 24–29, 1989, Moscow: Nauka, 1989, pp. 353–354.

    Google Scholar 

  40. Rovnyi, S.I., Nedelina, L.V., Tarakanov, V.M., et al., Radiokhimiya, 1998, vol. 40, no. 4, pp. 331–335.

    Google Scholar 

  41. Zilberman, B.Ya., Borovinskii, V.A., Ramazanov, L.M., et al., RF Patent 2066489, 1996, Byull. Izobret., 1996, no. 25.

  42. Marchenko, V.I., Savilova, O.A., and Dvoeglazov, K.N., Abstracts of Papers, Pyataya Rossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2006” (Fifth Russian Conf. on Radiochemistry “Radiochemistry-2006”), Dubna, October 23–27, 2006, Ozersk: Mayak, 2006, pp. 83–84.

    Google Scholar 

  43. Marchenko, V.I., Zhuravleva, G.I., Dvoeglazov, K.N., and Savilova, O.A., Khim. Tekhnol., 2008, vol. 9, no. 2, pp. 61–67.

    Google Scholar 

  44. Taylor, R.J., Denniss, I., and Wallwork, A., Nucl. Energy, 1997, vol. 36, no. 1, pp. 39–46.

    CAS  Google Scholar 

  45. Birkett, J., Carrott, M., Fox, O., et al., in Proc. GLOBAL’2005, Tsukuba (Japan), October 9–13, 2005, paper no. 161.

  46. Detilleux, E., Hild, W., and Geens, L., Nucl. Technol., 1983, vol. 61, June, pp. 398–402.

    CAS  Google Scholar 

  47. Schmieder, H., Goldaker, H., Heilgeist, M., and Petrich, G., in Proc. Int. Conf. “Fast Reactor Fuel Cycle,” London, 1982, p. 361.

  48. Koltunov, V.S. and Marchenko, V.I., in Proc. RECOD’ 98, Nice (France), October 25–28, 1998, vol. 1, pp. 425–431.

  49. Polunin, A.K., Mitroshin, I.E., Starikov, V.M., et al., Abstracts of Papers, Tret’ya Rossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2000” (Third Russian Conf. on Radiochemistry “Radiochemistry-2000”, St. Petersburg, November 28–December 1, 2000, p. 126.

  50. Renard, E.V., Pavlovich, V.B., Scklyar, L.I., et al., in Solvent Extraction 1990: Proc. Int. Solvent Extraction Conf. “ISEC’90,” Kyoto (Japan), July 16–21, 1990, Amsterdam: Elsevier, 1992, part A, pp. 573–578.

    Google Scholar 

  51. Talmon, K., in Khimiya ekstraktsii metallov organicheskimi vosstanovitelyami (Chemistry of Metal Extraction with Organic Reductants), Moscow: Atomizdat, 1965, pp. 81–89.

    Google Scholar 

  52. Van Geel, J., Joseph, C., Detilleaux, E., et al., in Proc. Int. Solvent Extraction Conf. “ISEC’71,” Hague, April 19–23, 1971, London: Soc. Chem. Ind., 1971, paper no. 200.

    Google Scholar 

  53. Baron, P., Dinh, B., and Mauborge, B., in Proc. ATALANTE’ 2000, Avignon (France), October 9–13, 2000, paper no. 01.04.

  54. Drain, F., Miquel, P., Moulin, J.-P., et al., Proc. GLOBAL’97, Yokohama (Japan), October 1997, vol. 1, pp. 250–254.

  55. Koltunov, V.S. and Marchenko, V.I., Kinet. Katal., 1966, vol. 7, no. 2, pp. 224–229.

    CAS  Google Scholar 

  56. Melent’ev, A.B., Belyaev, E.M., and Mashkin, A.N., Abstracts of Papers, Chetvertaya molodezhnaya nauchno-prakticheskaya konferentsiya “Yadernopromyshlennyi kompleks Urala: problemy and perspektivy” (Fourth Scientific and Practical Youth Conf. “Nuclear Industrial Complex of Urals: Problems and Prospects”), Ozersk: Mayak, April 18–20, 2007, pp. 68–70.

    Google Scholar 

  57. Dzekun, E.G., Mashkin, A.N., Potapov, V.P., and Zilberman, B.Ya., Abstracts of Papers, Tret’ya Rossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2000” (Third Russian Conf. on Radiochemistry “Radiochemistry-2003”), St. Petersburg, November 28–December 1, 2000, p. 172.

  58. Garraway, J. and Wilson, P., J. Less-Common Met., 1984, vol. 97, no. 2, pp. 191–203.

    Article  CAS  Google Scholar 

  59. Zilberman, B.Ya., Lelyuk, G.A., Mashkin, A.N., and Yasnovitskaya, A.L., Radiokhimiya, 1988, vol. 30, no. 6, pp. 833–837.

    CAS  Google Scholar 

  60. Zilberman, B.Ya. and Mashkin, A.N., Radiokhimiya, 1992, vol. 34, no. 4, pp. 34–41.

    CAS  Google Scholar 

  61. Vialard, E. and Germain, V., in Proc. Int. Solvent Extraction Conf. “ISEC’86,” Munich (FRG), September 11–16, 1986, vol. I, pp. 137–142.

  62. Tugarina, O.V. and Mashkin, A.N., Abstracts of Papers, Vtoraya molodezhnaya nauchno-prakticheskaya konferentsiya “Yaderno-promyshlennyi kompleks Urala: problemy and perspektivy” (Second Scientific and Practical Youth Conf. “Nuclear Industrial Complex of Urals: Problems and Prospects”), Ozersk: Mayak, 2003, pp. 208–210.

    Google Scholar 

  63. Mashkin, A.N. and Tugarina, O.V., in Nauchnaya sessiya MIFI-2004: Sbornik nauchnykh trudov (Scientific Session of Moscow Inst. of Engineering Physics 2004: Coll. of Scientific Works), Moscow: Mosk. Inzh.-Fiz. Inst., 2004, vol. 9, pp. 158–159.

    Google Scholar 

  64. Blanc, E., Emin, J.-L., and Bretault, Ph., in Proc. GLOBAL’2005, Tsukuba (Japan), October 9–13, 2005, paper no. 354.

  65. Uchiyama, G., Asakura, T., Hotoku, S., et al., Radiokhimiya, 2000, vol. 42, no. 6, pp. 488–492.

    Google Scholar 

  66. Germain, M., Gillet, B., and Pasquiou, J., in Solvent Extraction 1990: Proc. Int. Solvent Extraction Conf. “ISEC’90,” Kyoto (Japan), July 16–21, 1990, Amsterdam: Elsevier, 1992, part A, pp. 597–601.

    Google Scholar 

  67. Taylor, R.J. and May, I., Sep. Sci. Technol., 2001, vol. 36, nos. 5/6, pp. 1225–1240.

    Article  CAS  Google Scholar 

  68. FRG Patent 3504743 A1, applied May 12, 1985, published September 26, 1985.

  69. Denniss, I. and Philips, C., in Solvent Extraction 1990: Proc. Int. Solvent Extraction Conf. “ISEC’90,” Kyoto (Japan), July 16–21, 1990, Amsterdam: Elsevier, 1992, part A, pp. 549–554.

    Google Scholar 

  70. Isei, T., Tsujimura, A., Nitta, T., and Matsuda, T., Proc. GLOBAL’2007, Boise (Idaho), September 9–13, 2007, pp. 234–237.

  71. Barney, G.S., J. Inorg. Nucl. Chem., 1976, vol. 38, no. 9, pp. 1677–1681.

    Article  CAS  Google Scholar 

  72. Koltunov, V.S. and Zhuravleva, G.I., Radiokhimiya, 1978, vol. 20, no. 1, pp. 94–101.

    CAS  Google Scholar 

  73. Paviet-Hartmann, P. and Senentz, G., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 1865–1869.

  74. Patigny, P., Regnier, J., Miquel, P., and Taillard, D., in Proc. Int. Solvent Extraction Conf. ISEC’74, Lyon (France), 1974, London: Soc. Chem. Ind., 1974, vol. 3, p. 2019.

    Google Scholar 

  75. Thompson, M., Abstracts of Papers, Nat. Topical Meet. “Fuel Cycles for the 80’s,” Oak Ridge, Tennessee (USA), September 1980.

  76. Germain, M., Bathellier, A., and Berard, P., in Proc. Int. Solvent Extraction Conf. “ISEC’74,” Lyon (France), September 8–14, 1974, London: Soc. Chem. Ind., 1974, vol. 3, pp. 2075–2091.

    Google Scholar 

  77. Koltunov, V.S. and Tikhonov, M.F., Radiokhimiya, 1977, vol. 19, no. 5, pp. 611–619.

    CAS  Google Scholar 

  78. Koltunov, V.S. and Tikhonov, M.F., Radiokhimiya, 1977, vol. 19, no. 5, pp. 620–625.

    CAS  Google Scholar 

  79. Taylor, R., May, I., Denniss, I., et al., in Proc. RECOD’ 98, Nice (France), October 25–28, 1998, vol. 1, pp. 417–424.

  80. Koyama, T., Koma, Y., Sano, Y., and Tanaka, Y., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, vol. 2, pp. 1495–1500.

  81. Kolarik, Z. and Schuler, R., Abstracts of Papers, Int. Conf. on Nuclear and Radiochemistry, Lindau (FRG), October 8–12, 1984, Frankfurt/Main, 1984, p. 89.

  82. Gowland, R. and Stedman, G., J. Inorg. Nucl. Chem., 1981, vol. 43, no. 11, pp. 2859–2862.

    Article  CAS  Google Scholar 

  83. Marchenko, V.I., Zhuravleva, G.I., Dvoeglazov, K.N., and Savilova, O.A., Khim. Tekhnol., 2007, vol. 8, no. 7, pp. 318–323.

    Google Scholar 

  84. Marchenko, V.I., Zhuravleva, G.I., Dvoeglazov, K.N., and Savilova, O.A., RF Patent 2270172, 2006, Byull. Izobret., 2006, no. 5.

  85. Zemlyanukhin, V.I., Il’enko, E.I., Kondrat’ev, A.N., et al., Radiokhimicheskaya pererabotka yadernogo topliva AES (Radiochemical Reprocessing of NPP Nuclear Fuel), Moscow: Energoatomizdat, 1983.

    Google Scholar 

  86. Aochima, A., Yamanouchi, T., Ichimura, T., and Shikakura, S., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, vol. 1, pp. 355–360.

  87. Anzai, K., Hishi, T., Hayashibara, H., and Koiwa, Y., in Proc. GLOBAL’2005, Tsukuba (Japan), October 9–13, 2005, paper no. 406.

  88. Bennet, B., Chem. Eng., 1985, June, pp. 35–37.

  89. Koltunov, V.S. and Marchenko, V.I., Radiokhimiya, 1973, vol. 15, no. 5, pp. 748–750.

    CAS  Google Scholar 

  90. Koltunov, V.S. and Marchenko, V.I., Radiokhimiya, 1973, vol. 15, no. 6, pp. 777–781.

    CAS  Google Scholar 

  91. Miura, S., Nakahara, M., Sano, Y., et al., in Proc. Int. Conf. “Plutonium Futures. The Science 2006,” Alsimor, Pacific Grove, California (USA), July 9–13, 2006, pp. 96–97.

  92. Koltunov, V.S., Zhuravleva, G.I., Marchenko, V.I., and Shapovalov, M.P., Radiokhimiya, 1984, vol. 26, no. 2, pp. 187–192.

    CAS  Google Scholar 

  93. Bennet, M. and Kelmers, A., Trans. Am. Nucl. Soc., 1977, vol. 27, pp. 481–482.

    Google Scholar 

  94. Rance, P.J.W. and Zilberman, B.Ya., in Proc. GLOBAL’2001, Paris (France), September 9–13, 2001, paper no. 314.

  95. Neumoev, N.V., Korotkov, I.A., Semenova, T.I., et al., Radiokhimiya, 1989, vol. 31, no. 2, pp. 40–47.

    CAS  Google Scholar 

  96. Koltunov, V.S., Kinetika reaktsii aktinoidov (Kinetics of Actinide Reactions), Moscow: Atomizdat, 1974.

    Google Scholar 

  97. Tochiyama, O., Nakamura, Y., Katayama, Y., and Inoue, Y., J. Nucl. Sci. Technol., 1995, vol. 32, no. 1, pp. 50–59.

    Article  CAS  Google Scholar 

  98. Tsuboya, T., Nemoto, S., Hoshino, T., and Tanaka, C., US Patent 3962401, 1976.

  99. Drake, A., in Proc. Int. Solvent Extraction Conf. “ISEC’88,” Moscow, July 18–24, 1988, vol. IV, pp. 183–186.

  100. Fox, O., Carrot, M., Gaubert, E., et al., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 182–187.

  101. Arm, S., Abrefah, J., Lumetta, G., and Sinkov, S., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 700–706.

  102. Baron, P., Masson, M., Rostaing, C., and Bouliss, B., in Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 537–540.

  103. Nikiforov, A.S., Zakharkin, B.S., Renard, E.V., et al., in Proc. Int. Solvent Extraction Conf. “ISEC’88,” Moscow, July 18–24, 1988, vol. IV, pp. 168–174.

  104. Birkett, J., Carrot, M., Fox, O., et al., J. Nucl. Sci. Technol., 2007, vol. 44, no. 3, pp. 337–343.

    Article  CAS  Google Scholar 

  105. Sano, Y., Kamiya, M., Shibata, A., et al., in Proc. Int. Solvent Extraction Conf. “ISEC’2005,” Beijing (China), September 19–23, 2005, pp. 689–697.

  106. Nakahara, M., Sano, Y., Koma, Y., et al., J. Nucl. Sci. Technol., 2007, vol. 44, no. 3, pp. 373–381.

    Article  CAS  Google Scholar 

  107. Koltunov, V.S., Kulikov, I.A., Kermanova, N.V., and Nikishova, L.K., Radiokhimiya, 1981, vol. 23, no. 3, pp. 462–465.

    CAS  Google Scholar 

  108. Kulikov, I.A., Koltunov, V.S., Marchenko, V.I., et al., Zh. Fiz. Khim., 1979, vol. 53, no. 3, pp. 647–651.

    CAS  Google Scholar 

  109. Koltunov, V.S. and Zhuravleva, G.I., Radiokhimiya, 1987, vol. 29, no. 3, pp. 423–426.

    CAS  Google Scholar 

  110. Maillard, Ch. and Adnet, J.-M., Radiochim. Acta, 2001, vol. 89, no. 8, pp. 485–490.

    Article  CAS  Google Scholar 

  111. Zielen, A., Sullivan, J., Cohen, D., and Hindman, J., J. Am. Chem. Soc., 1960, vol. 82, no. 2, pp. 5294–5996.

    Google Scholar 

  112. Krot, N.N. and Shuiskaya, L.G., Radiokhimiya, 1971, vol. 13, no. 1, pp. 79–82.

    CAS  Google Scholar 

  113. Koltunov, V.S., Kulikov, I.A., Marchenko, V.I., and Milovanova, A.S., Radiokhimiya, 1980, vol. 22, no. 6, pp. 833–839.

    CAS  Google Scholar 

  114. Tananaev, I.G. and Dzyubenko, V.I., Radiokhimiya, 1989, vol. 31, no. 6, pp. 842–845.

    Google Scholar 

  115. Rovnyi, S.I., Ufimtsev, V.P., Tarakanov, V.M., et al., Abstracts of Papers, Vtoraya Rossiiskaya konferentsiya po radiokhimii (Second Russian Conf. on Radiochemistry), Dimitrovgrad: Nauchno-Issled. Inst. Atomnykh Reaktorov, October 27–31, 1997, pp. 221–222.

    Google Scholar 

  116. Anisimov, V.I., Kozlov, A.G., Lanin, V.P., et al., At. Energ., 1987, vol. 42, no. 3, pp. 191–193.

    Google Scholar 

  117. Plutonium Handbook. A Guide to the Technology, Wick, O.J., Ed., New York: Gordon and Breach, 1967.

    Google Scholar 

  118. Lukin, S.A. and Korchenkin, K.K., Abstracts of Papers, Chetvertaya molodezhnaya nauchno-prakticheskaya konferentsiya “Yaderno-promyshlennyi kompleks Urala: problemy and perspektivy” (Fourth Scientific and Practical Youth Conf. “Nuclear Industrial Complex of Urals: Problems and Prospects”), Ozersk: Mayak, April 18–20, 2007, pp. 72–73.

    Google Scholar 

  119. Yu-Keung Sze and Gosselin, J., Nucl. Technol., 1983, vol. 63, no. 3, pp. 431–441.

    Google Scholar 

  120. Koltunov, V.S. and Baranov, S.M., Radiokhimiya, 1993, vol. 35, no. 6, pp. 11–21.

    CAS  Google Scholar 

  121. Koltunov, V.S. and Baranov, S.M., in Proc. GLOBAL’95, Versailles (France), September 11–14, 1995, vol. 1, pp. 577–584.

  122. Koltunov, V.S., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 347–350.

  123. Zhang, A., Hu, J., Zhang, H., and Wang, F., J. Radioanal. Nucl. Chem., 2002, vol. 252, no. 3, pp. 565–571.

    Article  CAS  Google Scholar 

  124. Zhang, A., Hu, J., Zhang, X., and Wang, F., J. Radioanal. Nucl. Chem., 1998, vol. 230, nos. 1–2, pp. 235–239.

    CAS  Google Scholar 

  125. Koltunov, V.S., Taylor, R.J., Baranov, S.M., et al., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 878–881.

  126. Taylor, R.J., May, I., Koltunov, V.S., et al., Radiochim. Acta, 1998, vol. 81, no. 3, pp. 149–156.

    CAS  Google Scholar 

  127. Koltunov, V.S., Taylor, R.J., and Baranov, S.M., Radiochim. Acta, 2000, vol. 88, no. 2, pp. 65–70.

    Article  CAS  Google Scholar 

  128. Taylor, R.J. and May, I., Sep. Sci. Technol., 2001, vol. 36, no. 5/6, pp. 1225–1240.

    Article  CAS  Google Scholar 

  129. Wang, J., Bao, B., Wu, M., et al., J. Radioanal. Nucl. Chem., 2004, vol. 262, no. 2, pp. 451–453.

    Article  CAS  Google Scholar 

  130. Koltunov, V.S., Taylor, R.J., Gomonova, T.V., et al., Radiochim. Acta, 2000, vol. 88, no. 7, pp. 425–430.

    Article  CAS  Google Scholar 

  131. Ramazanov, L.M., Rovnyi, S.I., Glagolenko, Yu.V., et al., RF Patent 2307794, 2007, Byull. Izobret., 2007, no. 28.

  132. Zhang, A., Hu, J., Zhang, X., and Wang, F., Solvent Extr. Ion Exch., 2001, vol. 19, no. 6, pp. 965–979.

    Article  CAS  Google Scholar 

  133. Uchiyama, G., Hotoku, S., Kihara, T., et al., in Solvent Extraction 1990: Proc. Int. Solvent Extraction Conf. “ISEC’90,” Kyoto (Japan), July 16–21, 1990, Amsterdam: Elsevier, 1992, paper no. 04-29.

    Google Scholar 

  134. Uchiyama, G., Asakura, H., Watanabe, M., et al., in Proc. Int. Solvent Extraction Conf. “ISEC’96,” Melbourne (Australia), 1996, vol. 2, pp. 1291–1296.

    CAS  Google Scholar 

  135. Takanashi, M., Homma, S., Koga, J., and Matsumoto, S., J. Alloys Comp., 1998, vols. 271–273, pp. 689–692.

    Article  Google Scholar 

  136. Uchiyama, G., Mineo, H., Asakura, H., and Hotoku, S., Proc. GLOBAL’2001, Paris (France), September 9–13, 2001, paper no. 012.

  137. Uchiyama, G., Hotoku, S., Fujine, S., and Maeda, M., Solvent Extr. Ion Exch., 1997, vol. 15, no. 5, pp. 863–867.

    Article  CAS  Google Scholar 

  138. Zilberman, B.Ya., Fedorov, Yu.S., Sytnik, L.V., et al., Khim. Tekhnol., 2000, no. 6, pp. 16–21.

  139. Taylor, R.J., May, I., Wallwork, A.L., et al., J. Alloys Comp., 1998, vols. 271–273, pp. 534–537.

    Article  Google Scholar 

  140. Taylor, R.J., Denniss, I.S., and May, I., in Proc. ATALANTE’ 2000, Avignon (France), October 24–26, 2000, paper no. P2–15.

  141. Alyapyshev, M., Paulenova, A., Cleveland, M., et al., in Proc. GLOBAL’2007, Boise (Idaho), September 9–13, 2007, pp. 1861–1864.

  142. Colston Belinda, J., Choppin, G., and Taylor, R.J., Radiochim. Acta, 2000, vol. 88, no. 6, pp. 329–334.

    Article  Google Scholar 

  143. Chung, D.Y. and Lee, E.H., in Proc. Actinides’2005: Final Programme and Abstracts, Manchester (UK), July 4–8, 2005, paper no. 5P26.

  144. Butler, R., Sinkov, S., Renshaw, J., et al., Proc. ATALANTE’ 2000, Avignon (France), October 24–26, 2000, paper no. P2-09.

  145. Taylor, R.J., Mason, C., Cooke, R., and Boxall, C., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 278–281.

  146. Taylor, R.J., J. Nucl. Sci. Technol., 2002, suppl. 3, November, pp. 886–889.

  147. Carrot, M.J., Fox, O.D., Le Gurun, G., et al., Radiochim. Acta, 2008, vol. 96, no. 6, pp. 333–343.

    Article  CAS  Google Scholar 

  148. Paulenova, A. and Tkac, P., Proc. GLOBAL’2007, Boise, Idaho (USA), September 9–13, 2007, pp. 723–727.

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  1. Bochvar High-Tech Research Institute of Inorganic Materials, Joint-Stock Company, Moscow, Russia

    V. I. Marchenko, K. N. Dvoeglazov & V. I. Volk

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  1. V. I. Marchenko
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  2. K. N. Dvoeglazov
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Original Russian Text © V.I. Marchenko, K.N. Dvoeglazov, V.I. Volk, 2009, published in Radiokhimiya, 2009, Vol. 51, No. 4, pp. 289–302.

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Marchenko, V.I., Dvoeglazov, K.N. & Volk, V.I. Use of redox reagents for stabilization of Pu and Np valence forms in aqueous reprocessing of spent nuclear fuel: Chemical and technological aspects. Radiochemistry 51, 329–344 (2009). https://doi.org/10.1134/S1066362209040018

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