Abstract
A new coordination polymer formulated as [Zn(L)(1,3-BDC)] (L = 1,3-bis-(benzimidazole-1-ylmethylene)-benzene, 1,3-H2BDC = isophthalic acid) is hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group P21/n, a = 10.179(3) Å, b = 10.510(3) Å, c = 23.217(6) Å, α = 90, β = 91.983(3), γ = 90°, V = 2482.4(11) Å3, Z = 4, C30H22N4O4Zn, Mr = 567.91, Dc = 1.520 g/cm3, μ = 1.036 mm–1. The complex exhibits a 2D (4,4) network with the point symbol {44,62} and further extended into a 3D supramolecular framework through π⋯π stacking interactions between two well-overlapping benzimidazolyl rings of the neighboring L ligands. Furthermore, the thermal stability and fluorescence properties of the complex are investigated.
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Original Russian Text © 2018 S. Y. Hao, Z. C. Hao, Y. G. Liu, G. Y. Dong.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 742–746, March-April, 2018.
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Hao, S.Y., Hao, Z.C., Liu, Y.G. et al. Structure and Fluorescence Properties of a Two-Dimensional Zinc(II) Coordination Polymer Containing Isophthalate. J Struct Chem 59, 720–724 (2018). https://doi.org/10.1134/S0022476618030332
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DOI: https://doi.org/10.1134/S0022476618030332