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Structure and fluorescence property of a two-fold interpenetrated three-dimensional Zn(II) complex constructed by terephthalate and 1,3-dipyridyl benzene

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Abstract

A new coordination polymer {[Zn2(dpb)2(bdc)2]·1.03H2O} n (1) was prepared under solvothermal condition using terephthalate(1,4-H2bdc) as well as 1,3-dipyridyl benzene(1,3-dpb) as initiators. The complex was characterized by means of infrared spectroscopy(IR), thermogravimetric analysis(TGA), powder X-ray diffraction(XRD) and X-ray single-crystal diffraction. The results indicate that complex 1 crystallizes in the monoclinic system with space group of P21/c. The neighboring Zn(II) ions are linked by ligand dpb to form infinitely meso-helical or zigzag chains, which are further connected to form a two-fold interpenetrated 3D framework, in which there exists strong hydrogen bonds(O—H···O) between the interpenetrated frameworks. In addition, the solid-state fluorescence behavior of complex 1 was also discussed.

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Authors and Affiliations

  1. Laboratory of Multiscale Materials and Molecular Catalysis, School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan, 232001, P. R. China

    Jingyao Xu, Lei Zhang, Xueman Shao & Chengling Pan

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Chengling Pan & Jiqing Xu

Authors
  1. Jingyao Xu
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  2. Lei Zhang
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  3. Xueman Shao
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  4. Chengling Pan
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  5. Jiqing Xu
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Corresponding author

Correspondence to Chengling Pan.

Additional information

Supported by the National Natural Science Foundation of China(No.21201006), the Natural Science Foundation of Anhui Province, China(No.1308085QB34) and the Special Research Fund for the Doctoral Program of Higher Education, China (No.26920123415120002).

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Xu, J., Zhang, L., Shao, X. et al. Structure and fluorescence property of a two-fold interpenetrated three-dimensional Zn(II) complex constructed by terephthalate and 1,3-dipyridyl benzene. Chem. Res. Chin. Univ. 31, 328–331 (2015). https://doi.org/10.1007/s40242-015-4433-7

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  • DOI: https://doi.org/10.1007/s40242-015-4433-7

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