Abstract
A variety of high-performance strain sensors for monitoring changes in physical quantities have attracted considerable interest from academia and industry. In this work, a high sensitive flexible strain sensor is fabricated through electrospun thermoplastic polyurethane (TPU) fibrous film with dip-coating ultrasonication treated carbon nanotubes (CNTs). TPU/CNTs strain sensor exhibits an excellent comprehensive performance of high sensitivity (maximum gauge factor of 1571), outstanding tensile strength and toughness (stress > 24 MPa, strain > 400%), brilliant durability (10,000 cycles at 10% strain) and a widely workable stretching range (0–400%). Based on the properties of high sensitivity, wearable and wide workable, TPU/CNTs strain sensor has been prepared as a simple application for intelligent terminals, e-skins and body activity monitoring. More importantly, this work introduces a novel optimization empirical equation to describe and predict the conductive response on the stretching of the sensor. Compared with the general optimization model, the novel optimization empirical model presents a better fitting degree and more similar to the benchmark mathematic model from tunnelling theory. Furthermore, this model provides a good description of the changes in the conductive pathways during the operation of different sensors as well.
Graphical Abstract
Fabrication of high-performance electrospun TPU/CNTs strain sensor and fitting by a novel optimization empirical equation to predict the conductive response.
Similar content being viewed by others
References
Chen Q, Gao QS, Wang X, Schubert DW, Liu XH (2022) Flexible, conductive, and anisotropic thermoplastic polyurethane/polydopamine/MXene foam for piezoresistive sensors and motion monitoring. Compos A 155:106838
Liu ZZ, Li GJ, Qin Q, Mi LW, Li G, Zheng GQ, Liu CT, Li Q, Liu XH (2021) Electrospun PVDF/PAN membrane for pressure sensor and sodium-ion battery separator. Adv Compos Hybrid Mater 4(4):1215–1225
Wang X, Liu XH, Schubert DW (2021) Highly sensitive ultrathin flexible thermoplastic polyurethane/carbon black fibrous film strain sensor with adjustable scaffold networks. Nano-Micro Lett 13(1):1–19
Sun HL, Dai K, Zhai W, Zhou YJ, Li J, Zheng GQ, Li B, Liu CT, Shen CY (2019) A highly sensitive and stretchable yarn strain sensor for human motion tracking utilizing a wrinkle-assisted crack structure. ACS Appl Mater Interfaces 11:36052–36062
Qin YJ, Qu MC, Pan YM, Zhang CH, Schubert DW (2020) Fabrication, characterization and modelling of triple hierarchic PET/CB/TPU composite fibres for strain sensing. Compos Part A-Appl S 129:105724
Jia YP, Pan YM, Wang CF, Liu CT, Shen CY, Pan CF, Guo ZH, Liu XH (2021) Flexible Ag microparticle/MXene-based film for energy harvesting. Nano-Micro Lett 13(1):1–12
Zhou KK, Xu W, Yu YF, Zhai W, Yuan Z, Dai K, Zheng GQ, Mi LW, Pan CF, Liu CT, Shen CY (2021) Tunable and nacre-mimetic multifunctional electronic skins for highly stretchable contact-noncontact sensing. Small 17:2100542
Li SM, Li RQ, González OG, Chen TJ, Xiao XL (2021) Highly sensitive and flexible piezoresistive sensor based on c-MWCNTs decorated TPU electrospun fibrous network for human motion detection. Compos Sci Technol 203:108617
Jia YP, Sun RZ, Pan YM, Wang X, Zhai Z, Min Z, Zheng GQ, Liu CT, Shen CY, Liu XH (2021) Flexible and thin multifunctional waterborne polyurethane/Ag film for high-efficiency electromagnetic interference shielding, electro-thermal and strain sensing performances. Compos B 210:1359–8368
Kuang TR, Zhang ML, Chen F, Fei YP, Yang JT, Zhong MQ, Wu BZ, Liu T (2023) Creating poly (lactic acid)/carbon nanotubes/carbon black nanocomposites with high electrical conductivity and good mechanical properties by constructing a segregated double network with a low content of hybrid nanofiller. Adv Compos Hybrid Mater 6(1):48
Kuang TR, Ju JJ, Chen F, Liu XH, Zhang SD, Liu T, Peng XF (2022) Coupled effect of self-assembled nucleating agent, Ni-CNTs and pressure-driven flow on the electrical, electromagnetic interference shielding and thermal conductive properties of poly (lactic acid) composite foams. Compos Sci Technol 230:109736
Fei YP, Jiang RT, Fang W, Liu T, Saeb MR, Hejna A, Ehsani M, Barczewski M, Sajadi SM, Chen F, Kuang TR (2022) Highly sensitive large strain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite foams: from design to performance evaluation. J Supercrit Fluids 188:105653
Yanpei Fei YP, Chen F, Fang W, Hejna A, Xu LX, Liu T, Zhong MQ, Yang JT, Kuang TR (2021) Conductive thermoplastic polyurethane nanocomposite foams derived from a cellulose/MWCNTs aerogel framework: simultaneous enhancement of piezoresistance, strength, and endurance. J Mater Chem C 9(38):13103–13114
Dong H, Sun JC, Liu XM, Jiang XD, Lu SW (2022) Highly sensitive and stretchable MXene/CNTs/TPU composite strain sensor with bilayer conductive structure for human motion detection. ACS Appl Mater Interfaces 14(13):15504–15516
Ajeev A, Javaregowda BH, Ali A, Modak M, Patil S, Khatua S, Ramadoss M, Kothavade PA, Arulraj AK (2020) Ultrahigh sensitive carbon-based conducting rubbers for flexible and wearable human–machine intelligence sensing. Adv Mater Technol 5(12):2000690
Zhang YJ, Li CC, Zhou BZ, He HT, Zhou YF, Jiang L, Zhou FL, Chen SJ (2022) A flexible strain sensor based on conductive TPU/CNTs-Gr composites. J Appl Polym Sci 139(27):e52475
Huang K, Wu YF, Liu JC, Chang G, Pan XC, Weng XD, Wang YG, Lei M (2022) A double-layer carbon nanotubes/polyvinyl alcohol hydrogel with high stretchability and compressibility for human motion detection. Engineered Science 17:319–327
Wu YF, Chen EF, Weng XD, He ZF, Chang G, Pan XC, Liu JC, Huang K, Huang K, Lei M (2022) Conductive polyvinyl alcohol/silver nanoparticles hydrogel sensor with large draw ratio, high sensitivity and high stability for human behavior monitoring. Engineered Science 18:113–120
Wu YF, Liu JC, Lin S, Huang K, Chen EF, Huang K, Lei M (2022) New pressure matrix array sensor composed of flexible mechanical sensor elements. Engineered Science 18:105–112
Chen Z, Ren W, Gao L, Liu B, Pei S, Cheng HM (2011) Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nat Mater 10:424–428
Yu Y, Luo YF, Guo A, Yan LJ, Wu Y, Jiang KL, Li QQ, Fan SS, Wang JP (2017) Flexible and transparent strain sensors based on super-aligned carbon nanotube films. Nanoscale 9(20):6716–6723
Zhang BC, Wang H, Zhao Y, Li F, Ou XM, Sun BQ, Zhang XH (2016) Large-scale assembly of highly sensitive Si-based flexible strain sensors for human motion monitoring. Nanoscale 8(4):2123–2128
Xu MX, Qi JJ, Feng Li F, Zhang Y (2018) Highly stretchable strain sensors with reduced graphene oxide sensing liquids for wearable electronics. Nanoscale 10(11):5264–5271
Qu MC, Qin YJ, Sun Y, Xu HG, Schubert DW, Zheng K, Xu W, Nilsson F (2020) Biocompatible, flexible strain sensor fabricated with polydopamine-coated nanocomposites of nitrile rubber and carbon black. ACS Appl Mater Interfaces 12(37):42140–42152
Jia YY, Yue XY, Wang Y, Yan C, Zheng GQ, Dai K, Liu CT, Shen CY (2020) Multifunctional stretchable strain sensor based on polydopamine/ reduced graphene oxide/ electrospun thermoplastic polyurethane fibrous mats for human motion detection and environment monitoring. Compos B 183:107696
Zhou X, Zhu L, Fan L, Deng H, Fu Q (2018) Fabrication of highly stretchable, washable, wearable, water-repellent strain sensors with multi-stimuli sensing ability. ACS Appl Mater Interfaces 10(37):31655–31663
Chen J, Zhu Y, Jiang W (2020) A stretchable and transparent strain sensor based on sandwich-like PDMS/CNTs/PDMS composite containing an ultrathin conductive CNT layer. Compos Sci Technol 186:107938
Wang XZ, Sun HL, Yue X, Yu Y, Zheng GQ, Dai K, Liu CT, Shen CY (2018) A highly stretchable carbon nanotubes/thermoplastic polyurethane fiber-shaped strain sensor with porous structure for human motion monitoring. Compos Sci Technol 168:126–132
Schubert DW (2019) Revealing novel power laws and quantization in electrospinning considering jet splitting-toward predicting fiber diameter and its distribution. Macromol Theor Simul 28:1900006
Ding YP, Li W, Correia A, Yang Y, Zheng K, Liu DF, Schubert DW, Boccaccini AR, Santos HA, Roether JA (2018) Electrospun Polyhydroxybutyrate/Poly(Ε-Caprolactone)/Sol−Gel-derived silica hybrid scaffolds with drug releasing function for bone tissue engineering applications. ACS Appl Mater Interfaces 10:14540–14548
Liu H, Li QM, Zhang SD, Yin R, Liu XH, He YX, Dai K, Shan CX, Guo J, Liu CT, Shen CY, Wang XJ, Wang N, Wang ZC, Wei RB, Guo ZH (2018) Electrically conductive polymer composites for smart flexible strain sensors: a critical review. J Mater Chem C 6:12121–12141
Lozano-Pérez C, Cauich-Rodríguez JV, Avilés F (2016) Influence of rigid segment and carbon nanotube concentration on the cyclic piezoresistive and hysteretic behavior of multiwall carbon nanotube/segmented polyurethane composites. Compos Sci Technol 128:25–32
Zhou J, Xu XZ, Xin Y, Lubineau G (2018) Coaxial thermoplastic elastomer-wrapped carbon nanotube fibers for deformable and wearable strain sensors. Adv Funct Mater 28:1705591
Chen HT, Su ZM, Song Y, Cheng XL, Chen XX, Meng B, Song ZJ, Chen DM, Zhang HX (2017) Omnidirectional bending and pressure sensor based on stretchable CNT-PU sponge. Adv Funct Mater 27:1604434
Wang YL, Jia YY, Zhou YJ, Wang Y, Zheng GQ, Dai K, Chuntai Liu CT, Shen CY (2018) Ultra-stretchable, sensitive and durable strain sensors based on polydopamine encapsulated carbon nanotubes/ elastic bands. J Mater Chem C 6:8160–8170
Gong S, Zhang J, Wang C, Ren K, Wang ZL (2019) A monocharged electret nanogenerator-based self-powered device for pressure and tactile sensor applications. Adv Funct Mater 29:1807618
Zhao K, Li SS, Huang M, Shi XY, Zheng GQ, Liu CT, Dai K, Shen CY, Yin R, Guo JZ (2019) Remarkably anisotropic conductive Mwcnts/Polypropylene nanocomposites with alternating microlayers. Chem Eng J 358:924–935
Li YH, Zhou B, Zheng GQ, Liu XH, Li TX, Yan C, Cheng CB, Dai K, Liu CT, Shen CY, Guo ZH (2018) Continuously prepared highly conductive and stretchable SWNT/MWNT synergistically composited electrospun thermoplastic polyurethane yarns for wearable sensing. J Mater Chem C 6:2258–2269
Zhang M, Wang C, Wang Q, Jian M, Zhang Y (2019) Sheath–core graphite/silk fiber made by dry-meyer-rod-coating for wearable strain sensors. ACS Appl Mater Interfaces 8:20894–20899
Li YQ, Zhu WB, Yu XG, Huang P, Fu SY, Hu N, Liao K (2016) Multifunctional wearable device based on flexible and conductive carbon Sponge/Polydimethylsiloxane composite. ACS Appl Mater Interfaces 8:33189
Lin Y, Liu S, Chen S, Wei Y, Dong X, Liu L (2016) A highly stretchable and sensitive strain sensor based on Graphene-Elastomer composites with a novel double-interconnected network. J Mater Chem C 4:6345–6352
Tang Y, Zhao Z, Hu H, Liu Y, Wang X, Zhou S, Qiu J (2015) Highly stretchable and ultrasensitive strain sensor based on reduced graphene oxide Microtubes-Elastomer composite. ACS Appl Mater Interfaces 7:27432–27439
Shi G, Zhao Z, Pai JH, Lee I, Zhang L, Stevenson C, Ishara K, Zhang RJ, Zhu HW, Ma J (2016) Highly sensitive, wearable, durable strain sensors and stretchable conductors using graphene/silicon rubber composites. Adv Funct Mater 26:7614–7625
Gong S, Lai DT, Su B, Si KJ, Ma Z, Yap LW, Guo PZ, Cheng WL (2015) Highly stretchy black gold E-skin nanopatches as highly sensitive wearable biomedical sensors. Adv Electron Mater 1:1400063
Liu H, Gao J, Huang WJ, Dai K, Zheng GQ, Liu CT, Shen CY, Yan XG, Guo J, Zhanhu Guo ZH (2016) Electrically conductive strain sensing polyurethane nanocomposites with synergistic carbon nanotubes and graphene bifillers. J Mater Chem C 4:157–166
Wu XD, Y. Han YY, Zhang XX, Lu CH, (2017) Highly sensitive, stretchable, and wash-durable strain sensor based on ultrathin conductive layer@Polyurethane yarn for tiny motion monitoring. ACS Appl Mater Interfaces 9:23007
Zhang XW, Pan YM, Zheng Q, Yi XS (2000) Time dependence of piezoresistance for the conductor-filled polymer composites. J Polym Sci Part B Polym Phys 38(21):2739–2749
Acknowledgements
The authors acknowledge the support from all staff members in the Institute of Polymer Materials and Friedrich-Alexander-University Erlangen-Nuremberg. Xin Wang acknowledges Tiecheng Wang and Qingsen Gao for the help of drawing chart. Xin Wang would like to acknowledge Carol Jiale for the inspiration, care and help in life. The authors appreciate the thoughtful input from both reviewers, which have improved the quality of this paper. The paper reflects the views and position of the authors, and not necessarily those of the funding entities.
Funding
Xin Wang gratefully acknowledges the China Scholarship Council for funding a scholarship.
Author information
Authors and Affiliations
Contributions
X. Wang and X. Liu designed this study and draft—writing. X. Wang, M. Qu and K. Wu performed the experiments and analysis. X. Wang, D. Schubert and X. Liu devoted to the writing—edit. All authors reviewed the manuscript.
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wang, X., Qu, M., Wu, K. et al. High sensitive electrospun thermoplastic polyurethane/carbon nanotubes strain sensor fitting by a novel optimization empirical model. Adv Compos Hybrid Mater 6, 63 (2023). https://doi.org/10.1007/s42114-023-00648-x
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s42114-023-00648-x