Abstract
Two-dimensional Ti3C2Tx MXene nanosheets with excellent electrical conductivity and layered structure have shown great promising in electromagnetic wave (EMW) absorption. Here, MXene nanosheets with homogeneously anchored NiFe2O4 nanoparticles (NiFe2O4/MXene) were prepared using facial electrostatic self-assembling and freeze-drying technique. Interestingly, the minimum reflection loss (RLmin) of paraffin wax-based composites with only 3% NiFe2O4/MXene reached as low as − 41.83 dB, showing much stronger EMW absorption property than that of MXene nanosheets (RLmin = − 5.03 dB) at the same loading level. This can be mainly ascribed to the existence of NiFe2O4 nanoparticle that can effectively prevent the self-stacking of MXene nanosheets, causing improved conduction loss. Besides, large amounts of heterogeneous interfaces between NiFe2O4 nanoparticle and MXene can also produce additional interface polarization loss. More importantly, magnetic loss arising from the magnetic NiFe2O4 nanoparticle is beneficial for good impedance matching, enabling more EMW to enter into the interior of composites to be dissipated. Furthermore, effective absorption bandwidth in the frequency range of 3.44–18 GHz can be achieved by adjusting the matching thickness of composites with 5% NiFe2O4/MXene. This study paves a way for preparing high-performance MXene-based EMW absorber at ultralow loading level.
Graphical abstract
Electrostatic self-assembled NiFe2O4/MXene nanocomposites exhibit excellent electromagnetic wave absorption performance based on the synergistic effect of bifillers
Similar content being viewed by others
References
Wu N, Du W, Hu Q, Vupputuri S, Jiang Q (2021) Recent development in fabrication of Co nanostructures and their carbon nanocomposites for electromagnetic wave absorption. Eng Sci 13:11–23
Zhao B, Deng JS, Zhang R, Liang LY, Fan BB, Bai ZY, Shao G, Park CB (2018) Recent advances on the electromagnetic wave absorption properties of Ni based materials. Engineered Science 3:5–40
Xu X, Ran F, Fan Z, Lai H, Cheng Z, Lv T, Shao L, Liu Y (2019) Cactus-inspired bimetallic metal-organic framework-derived 1D-2D hierarchical Co/N-decorated carbon architecture toward enhanced electromagnetic wave absorbing performance. ACS Appl Mater Interfaces 11:13,564–13,573
Xie P, Liu Y, Feng M, Niu M, Liu C, Wu N, Sui K, Patil RR, Pan D, Guo Z, Fan R (2021) Hierarchically porous Co/C nanocomposites for ultralight high-performance microwave absorption. Adv Compos Hybrid Mater 4:173–185
Zhou C, Wang X, Luo H, Deng L, Wang S, Wei S, Zheng Y, Jia Q, Liu J (2019) Interfacial design of sandwich-like CoFe@Ti3C2Tx composites as high efficient microwave absorption materials. Appl Surf Sci 494:540–550
Zhang J, Xue W, Chen XY (2020) Ti3C2Tx MXenes as thin broadband absorbers. Nanotechnology 31:275301
Wang Z, Cheng Z, Fang C, Hou X, Xie L (2020) Recent advances in MXenes composites for electromagnetic interference shielding and microwave absorption. Compos Part A Appl Sci Manuf 136:105956
Ma M, Li W, Tong Z, Yang Y, Ma Y, Cui Z, Wang R, Lyu P, Huang W (2020) 1D flower-like Fe3O4@SiO2@MnO2 nanochains inducing RGO self-assembly into aerogels for high-efficient microwave absorption. Mater Des 188:108462
Wei H, Dong J, Fang X, Zheng W, Sun Y, Qian Y, Jiang Z, Huang Y (2019) Ti3C2Tx MXene/polyaniline (PANI) sandwich intercalation structure composites constructed for microwave absorption. Compos Sci Technol 169:52–59
Li X, Yin X, Xu H, Han M, Li M, Liang S, Cheng L, Zhang L (2018) Ultralight MXene-coated, interconnected SiCnws three-dimensional lamellar foams for efficient microwave absorption in the X-band. ACS Appl Mater Interfaces 10:34,524–34,533
You W, Che R (2018) Excellent NiO-Ni nanoplate microwave absorber via pinning effect of antiferromagnetic-ferromagnetic interface. ACS Appl Mater Interfaces 10:15,104–15,111
Wei S, Wang X, Zheng Y, Chen T, Zhou C, Chen S, Liu J (2019) Facile preparation of snowflake-like MnO2 @NiCo2O4 composites for highly efficient electromagnetic wave absorption. Chemistry 25:7695–7701
Deng R, Chen B, Li H, Zhang K, Zhang T, Yu Y, Song L (2019) MXene/Co3O4 composite material: stable synthesis and its enhanced broadband microwave absorption. Appl Surf Sci 488:921–930
Wang X, Li H, Li H, Lin S, Ding W, Zhu X, Sheng Z, Wang H, Zhu X, Sun Y (2020) 2D/2D 1T-MoS2/Ti3C2 MXene heterostructure with excellent supercapacitor performance. Adv Funct Mater 30:0190302
Wang W, Jiang D, Chen X, Xie K, Jiang Y, Wang Y (2020) A sandwich-like nano-micro LDH-MXene-LDH for high-performance supercapacitors. Appl Surf Sci 515:145982
Liu YT, Zhang P, Sun N, Anasori B, Zhu QZ, Liu H, Gogotsi Y, Xu B (2018) Self-Assembly of transition metal oxide nanostructures on MXene nanosheets for fast and stable lithium storage. Adv Mater 30:1707334
Jiang L, Duan J, Zhu J, Chen S, Antonietti M (2020) Iron-cluster-directed synthesis of 2D/2D Fe-N-C/MXene superlattice-like heterostructure with enhanced oxygen reduction electrocatalysis. ACS Nano 14:2436–2444
Gan R, Yang N, Dong Q, Fu N, Wu R, Li C, Liao Q, Li J, Wei Z (2020) Enveloping ultrathin Ti3C2 nanosheets on carbon fibers: a high-density sulfur loaded lithium-sulfur battery cathode with remarkable cycling stability. J Mater Chem A 8:7253–7260
Bu Y, Shen T, Yang W, Yang S, Zhao Y, Liu H, Zheng Y, Liu C, Shen C (2021) Ultrasensitive strain sensor based on superhydrophobic microcracked conductive Ti3C2Tx MXene/paper for human-motion monitoring and E-skin. Sci Bull. https://doi.org/10.1016/j.scib.2021.04.041
Peng C, Yang X, Li Y, Yu H, Wang H, Peng F (2016) Hybrids of two-dimensional Ti3C2 and TiO2 exposing 001 facets toward enhanced photocatalytic activity. ACS Appl Mater Interfaces 8:6051–6060
Cao MS, Cai YZ, He P, Shu JC, Cao WQ, Yuan J (2019) 2D MXenes: electromagnetic property for microwave absorption and electromagnetic interference shielding. Chem Eng J 359:1265–1302
Zhang K, Gao X, Zhang Q, Li T, Chen H, Chen X (2017) Synthesis, characterization and electromagnetic wave absorption properties of asphalt carbon coated graphene/magnetic NiFe2O4 modified multi-wall carbon nanotube composites. J Alloys Compd 721:268–275
Liu P, Yao Z, Ng VMH, Zhou J, Kong LB, Yue K (2018) Facile synthesis of ultrasmall Fe3O4 nanoparticles on MXenes for high microwave absorption performance. Compos Part A Appl Sci Manuf 115:371–382
Ouyang J, He Z, Zhang Y, Yang H, Zhao Q (2019) Trimetallic FeCoNi@C nanocomposite hollow spheres derived from metal-organic frameworks with superior electromagnetic wave absorption ability. ACS Appl Mater Interfaces 11:39,304–39,314
Liu Q, Cao Q, Bi H, Liang C, Yuan K, She W, Yang Y, Che R (2016) CoNi@SiO2@TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption. Adv Mater 28:486–490
Wang S, Xu Y, Fu R, Zhu H, Jiao Q, Feng T, Feng C, Shi D, Li H, Zhao Y (2019) Rational construction of hierarchically porous Fe-Co/N-doped carbon/rGO composites for broadband microwave absorption. Nano-micro Lett 11:1–16
Liu P, Zhu C, Gao S, Guan C, Huang Y, He W (2020) N-doped porous carbon nanoplates embedded with CoS2 vertically anchored on carbon cloths for flexible and ultrahigh microwave absorption. Carbon 163:348–359
Xu H, Yin X, Li X, Li M, Liang S, Zhang L, Cheng L (2019) Lightweight Ti3C2Tx MXene/poly(vinyl alcohol) composite foams for electromagnetic wave shielding with absorption-dominated feature. ACS Appl Mater Interfaces 11:10198–10207
Li Q, Yin R, Zhang D, Liu H, Chen X, Zheng Y, Guo Z, Liu C, Shen C (2020) Flexible conductive MXene/cellulose nanocrystal coated nonwoven fabrics for tunable wearable strain/pressure sensors. J Mater Chem A 8:21,131–21,141
Xie F, Jia F, Zhuo L, Lu Z, Si L, Huang J, Zhang M, Ma Q (2019) Ultrathin MXene/aramid nanofiber composite paper with excellent mechanical properties for efficient electromagnetic interference shielding. Nanoscale 11:23,382–23,391
Zhang D, Karki AB, Rutman D, Young DP, Wang A, Cocke D, Ho TH, Guo Z (2009) Electrospun polyacrylonitrile nanocomposite fibers reinforced with Fe3O4 nanoparticles: fabrication and property analysis. Polymer 50:4189–4198
Liu H, Chen XY, Zheng YJ, Zhang DB, Zhao Y, Wang CF, Pan CF, Liu CT, Shen CY (2021) Lightweight, superelastic, and hydrophobic polyimide nanofiber/MXene composite aerogel for wearable piezoresistive sensor and oil/water separation applications. Adv Funct Mater 31:2008006
Liu J, Zhang HB, Sun R, Liu Y, Liu Z, Zhou A, Yu ZZ (2017) Hydrophobic, flexible, and lightweight MXene foams for high-performance electromagnetic-interference shielding. Adv Mater 29:1702367
Feng A, Ma M, Jia Z, Zhang M, Wu G (2019) Fabrication of NiFe2O4@carbon fiber coated with phytic acid-doped polyaniline composite and its application as an electromagnetic wave absorber. RSC Adv 9:25,932–25,941
Zhang Y, Wang X, Cao M (2018) Confinedly implanted NiFe2O4-rGO: cluster tailoring and highly tunable electromagnetic properties for selective-frequency microwave absorption. Nano Res 11:1426–1436
Yan F, Guo D, Zhang S, Li C, Zhu C, Zhang X, Chen Y (2018) An ultra-small NiFe2O4 hollow particle/graphene hybrid: fabrication and electromagnetic wave absorption property. Nanoscale 10(6):2697–2703
Liang L, Yang R, Han G, Feng Y, Zhao B, Zhang R, Wang Y, Liu C (2020) Enhanced electromagnetic wave-absorbing performance of magnetic nanoparticles-anchored 2D Ti3C2Tx MXene. ACS Appl Mater Interfaces 12:2644–2654
Liu P, Huang Y, Zhang X (2015) Cubic NiFe2O4 particles on graphene-polyaniline and their enhanced microwave absorption properties. Compos Sci Technol 107:54–60
Hosseini H, Mahdavi H (2018) Nanocomposite based on epoxy and MWCNTs modified with NiFe2O4 nanoparticles as efficient microwave absorbing material. Appl Organomet Chem 32:e4294
Zhao R, Qian Z, Liu Z, Zhao D, Hui X, Jiang G, Wang C, Yin L (2019) Molecular-level heterostructures assembled from layered black phosphorene and Ti3C2 MXene as superior anodes for high-performance sodium ion batteries. Nano Energy 65:04037
Tong Y, He M, Zhou Y, Zhong X, Fan L, Huang T, Liao Q, Wang Y (2018) Electromagnetic wave absorption properties in the centimetre-band of Ti3C2Tx MXenes with diverse etching time. J Mater Sci Mater Electron 29:8078–8088
Yadav RS, Kuřitka I, Vilcakova J, Skoda D, Urbánek P, Machovsky M, Masař M, Kalina L, Havlica J (2019) Lightweight NiFe2O4-reduced graphene oxide-elastomer nanocomposite flexible sheet for electromagnetic interference shielding application. Compos B Eng 166:95–111
Yan J, Huang Y, Chen X, Wei C (2016) Conducting polymers- NiFe2O4 coated on reduced graphene oxide sheets as electromagnetic (EM) wave absorption materials. Synth Met 221:291–298
Fan B, Li N, Dai B, Shang S, Guan L, Zhao B, Wang X, Bai Z, Zhang R (2020) Investigation of adjacent spacing dependent microwave absorption properties of lamellar structural Ti3C2Tx MXenes. Adv Powder Technol 31:808–815
Xu G, Wang X, Gong S, Wei S, Liu J, Xu Y (2018) Solvent-regulated preparation of well-intercalated Ti3C2Tx MXene nanosheets and application for highly effective electromagnetic wave absorption. Nanotechnology 29:355201
Liu T, Liu N, An Q, Xiao Z, Zhai S, Li Z (2019) Designed construction of Ti3C2Tx@PPY composites with enhanced microwave absorption performance. J Alloys Compd 802:445–457
Dai B, Zhao B, Xie X, Su T, Fan B, Zhang R, Yang R (2018) Novel two-dimensional Ti3C2Tx MXenes/nano-carbon sphere hybrids for high-performance microwave absorption. J Mater Chem C 6:5690–5697
Yu X, Chen G, Wang Y, Liu J, Pei K, Zhao Y, You W, Wang L, Zhang J, Xing L, Ding J, Ding G, Wang M, Che R (2020) Hierarchical coupling effect in hollow Ni/NiFe2O4-CNTs microsphere via spray-drying for enhanced oxygen evolution electrocatalysis. Nano Res 13:437–446
Gao X, Bi J, Wang W, Liu H, Chen Y, Hao X, Sun X, Liu R (2020) Morphology-controllable synthesis of NiFe2O4 growing on graphene nanosheets as advanced electrode material for high performance supercapacitors. J Alloys Compd 826:154088
Bao S, Xiao Y, Li J, Yue B, Li Y, Sun W, Liu L, Huang Y, Wang L, Zhang P, Lai X (2020) Coral-like NiFe2O4/C composite as the high-performance anode material for lithium-ion batteries. Electron Mater Lett 16:207–215
Zeng X, Zhu L, Yang B, Yu R (2020) Necklace-like Fe3O4 nanoparticle beads on carbon nanotube threads for microwave absorption and supercapacitors. Mater Des 189:108517
Tang J, Wang K, Lu Y, Liang N, Qin X, Tian G, Zhang D, Feng S, Yue H (2020) Mesoporous core-shell structure NiFe2O4@polypyrrole micro-rod with efficient electromagnetic wave absorption in C, X. Ku wavebands J Magn Magn Mater 514:167268
Bai T, Guo Y, Liu H, Song G, Zhang D, Wang Y, Mi L, Guo Z, Liu C, Shen C (2020) Achieving enhanced electromagnetic shielding and absorption capacity of cellulose-derived carbon aerogels via tuning the carbonization temperature. J Mater Chem C 8:5191–5201
Zhang D, Liu T, Cheng J, Cao Q, Zheng G, Liang S, Wang H, Cao M-S (2019) Lightweight and high-performance microwave absorber based on 2D WS2-RGO heterostructures. Nanomicro Lett 11:38
Zhang Z, Lv Q, Chen Y, Yu H, Liu H, Cui G, Sun X, Li L (2019) NiS2@rGO nanosheet wrapped with PPy aerogel: a sandwich-like structured composite for excellent microwave absorption. Nanomaterials 9:833
Yan J, Huang Y, Han X, Gao X, Liu P (2019) Metal organic framework (ZIF-67)-derived hollow CoS2/N-doped carbon nanotube composites for extraordinary electromagnetic wave absorption. Compos B Eng 163:67–76
Wu F, Liu P, Wang J, Shah T, Ahmad M, Zhang Q, Zhang B (2020) Fabrication of magnetic tubular fiber with multi-layer heterostructure and its microwave absorbing properties. J Colloid Interface Sci 577:242–255
Wang Y, Gao X, Wu X, Zhang W, Luo C, Liu P (2019) Facile design of 3D hierarchical NiFe2O4/N-GN/ZnO composite as a high performance electromagnetic wave absorber. Chem Eng J 375:121942
Acknowledgements
The research was financially supported by National Natural Science Foundation of China (Nos. 51803191, 12072325), National Key R&D Program of China (2019YFA0706802), the 111 project (D18023), and Key Scientific and Technological Project of Henan Province (202102210038).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Guo, Y., Wang, D., Bai, T. et al. Electrostatic self-assembled NiFe2O4/Ti3C2Tx MXene nanocomposites for efficient electromagnetic wave absorption at ultralow loading level. Adv Compos Hybrid Mater 4, 602–613 (2021). https://doi.org/10.1007/s42114-021-00279-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42114-021-00279-0