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Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra

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Chemical Research in Chinese Universities Aims and scope

Abstract

Polyoxometalate-based metal-organic polyhedra(MOPs) were of particular concern because of the various exquisite building blocks and the suitable constructional characteristics. To further understand the design and particularity of polyoxovanadate-based MOPs, (NH2Me)8{[V6O6(OCH3)9(C6H5PO3)]4·(BPT)4}·2DMF(HNU-74) and (NH2Me)12{[V6O6(OCH3)9(C6H5PO3)]4·(HBCBAIP)4}(SO4)2·MeOH·DMF(HNU-75) were constructed by a face-directed synthesis strategy. Both structures were assembled with four secondary building units as vertexes and four organic ligands served as faces. Different from HNU-74, HNU-75 showed a carboxyl group free during the coordination process, resulting in the pore channels being blocked and the free carboxyl group linking outwards, paving the way for the formation of the 3D structure. Due to the pore channels of HNU-74, the adsorption of I2 was studied and the adsorption capacity was 148 mg/g.

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Acknowledgements

This work was supported by the Natural Science Foundation of Hainan Province, China(Nos.221QN169, 221QN171), the National Natural Science Foundation of China(No.22101067), the Innovation Program for Young Scientific and Technological Talents of Hainan Association of Science and Technology, China(No. QCQTXM202207), the Start-up Research Foundation of Hainan University, China(No.RZ2100003143), the Science and Technology Special Fund of Hainan Province, China(No.ZDYF2022SHFZ298), the International Science & Technology Cooperation Program of Hainan Province, China(No.GHYF2022006), the Specific Research Fund of the Innovation Platform for Academicians of Hainan Province, China(No.YSPTZX202321) and the Innovation Platform for Academicians of Hainan Province, China.

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Authors and Affiliations

  1. Key Laboratory of Advanced Materials of Tropical Island Resources, Ministry of Education, School of Science, Hainan University, Haikou, 570228, P. R. China

    Huiping Chen, Yaru Gong, Qiangqiang Chu, Xiao Pang, Xiaojing Huang, Xudong Tian, Weiting Yang, Qinhe Pan, Zhongmin Su & Xinlong Wang

  2. School of Chemical Engineering and Technology, Hainan University, Haikou, 570228, P. R. China

    Huiping Chen, Qiangqiang Chu, Xiao Pang, Xiaojing Huang, Xudong Tian, Weiting Yang & Qinhe Pan

  3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Zhongmin Su

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  1. Huiping Chen
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Correspondence to Yaru Gong, Qinhe Pan or Xinlong Wang.

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Chen, H., Gong, Y., Chu, Q. et al. Face-directed Strategy for the Construction of Polyoxovanadate-based Metal-Organic Tetrahedra. Chem. Res. Chin. Univ. 39, 954–959 (2023). https://doi.org/10.1007/s40242-023-2335-7

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