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A Cage-based Porous Metal-organic Framework for Efficient C2H2 Storage and Separation

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Chemical Research in Chinese Universities Aims and scope

Abstract

Exploring the application potentials of metal-organic frameworks(MOFs) in the field of light hydrocarbons storage and separation is of great significance for solving the critical energy problem. However, designing porous materials with efficient separation capacity is still a challenging task. In this work, we synthesized a cage-based porous materiel(FJI-H32) with a large surface area. After activation, FJI-H32 exhibits the feature of high C2H2 storage capacity(113 cm3/g) and promising C2H2/CO2 separation ability at 298 K and under 100 kPa. More importantly, the C2H2/CO2 separation was verified by actual breakthrough experiments.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos.21871266, 21731006), the Natural Science Foundation of Fujian Province, China(No.2020J06034), the Key Research Program of Frontier Science, CAS (No.QYZDY-SSW-SLH025), the Fund of the Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZR120), and the Fund of the Youth Innovation Promotion Association of CAS.

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Authors and Affiliations

  1. College of Chemistry, Fuzhou University, Fuzhou, 350108, P. R. China

    Hengbo Li, Kuikui Wang, Mingyan Wu & Maochun Hong

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China

    Hengbo Li, Kuikui Wang, Mingyan Wu & Maochun Hong

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  1. Hengbo Li
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  2. Kuikui Wang
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  3. Mingyan Wu
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Correspondence to Maochun Hong.

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Li, H., Wang, K., Wu, M. et al. A Cage-based Porous Metal-organic Framework for Efficient C2H2 Storage and Separation. Chem. Res. Chin. Univ. 38, 82–86 (2022). https://doi.org/10.1007/s40242-021-1361-6

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  • DOI: https://doi.org/10.1007/s40242-021-1361-6

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