Abstract
This study introduces a novel method of electric field sintering for preparing NdFeB magnets. NdFeB alloy compacts were all sintered by electric fields for 8 min at 1000°C with different preset heating rates. The characteristics of electric field sintering and the effects of heating rate on the sintering densification of NdFeB alloys were also studied. It is found that electric field sintering is a new non-pressure rapid sintering method for preparing NdFeB magnets with fine grains at a relatively lower sintering temperature and in a shorter sintering time. Using this method, the sintering temperature and process of the compacts can be controlled accurately. When the preset heating rate increasing from 5 to 2000°C/s the densification of NdFeB sintered compacts gradually improves. As the preset heating rate is 2000°C/s, Nd-rich phases are small, dispersed and uniformly distributed in the sintered compact, and the magnet has a better microstructure than that made by conventional vacuum sintering. Also, the maximum energy product of the sintered magnet reaches 95% of conventionally vacuum sintered magnets.
Similar content being viewed by others
References
M. Yue, A.L. Cao, G.P. Wang, W.Q. Liu, D.T. Zhang, and J.X. Zhang, Mechanical properties of spark plasma sintering NdFeB permanent magnets, J. Funct. Mater. Devices, 14(2008), No.3, p.683.
W.J. Mo, L.T. Zhang, A.D. Shan, and J.S. Wu, Study on microstructure of NdFeB magnet prepared by spark plasma sintering, Rare Met. Mater. Eng., 36(2007), No.12, p.2140.
M. Yue, J.X. Zhang, W.Q. Liu, and G.P. Wang, Chemical stability and microstructure of Nd-Fe-B magnet prepared by spark plasma sintering, J. Magn. Magn. Mater., 271(2004), No.2-3, p.364.
W.Q. Liu, M. Yue, D.T. Zhang, and J.X. Zhang, Corrosion behavior of conventional and spark plasma-sintered Nd-Fe-B permanent magnets in different solutions, Corrosion, 65(2009), No.7, p.501.
M. Yue, M. Tian, J.X. Zhang, D.T. Zhang, P.L. Niu, and F. Yang, Microstructure and magnetic properties of anisotropic Nd-Fe-B magnets produced by spark plasma sintering technique, Mater. Sci. Eng. B, 131(2006), No.1-3, p.18.
M. Yue, J.X. Zhang, G.P. Wang, W.Q. Liu, and M.L. Zhou, Microstructure and properties of Nd-Fe-B magnets prepared by spark plasma sintering, Mater. Sci. Technol., 20(2004), No.5, p.666.
M. Yue, J.X. Zhang, Y.F. Xiao, G.P. Wang, and T. Li, New kind of NdFeB magnet prepared by spark plasma sintering, IEEE Trans. Magn., 39(2003), No.6, p.3551.
M. Yue, G.P. Wang, J.X. Zhang, M.L. Zhou, and T.Y. Zuo, Study on a new kind of NdFeB magnet prepared by spark plasma sintering, Rare Met. Mater. Eng., 32(2003), No.10, p.844.
T. Li, M. Yue, A.Z. Sun, B.Q. Qiu, Y.F. Xiao, and J.X. Zhang, Corrosion behaviors of NdFeB magnets prepared by spark plasma sintering, J. Univ. Sci. Technol. Beijing, 11(2004), No.2, p.147.
M. Yue, A.L. Cao, G.P. Wang, W.Q. Liu, and J.X. Zhang, Spark plasma sintering NdFeB permanent magnets with good all-around property, J. Beijing Univ. Technol., 34(2008), No.3, p.314.
K.Q. Feng, C.G. Bai, and Y. Yang, Study on combustion synthesis of 75wt%Fe-25wt%(Ti+C) system based on action of electric field, Hot Work. Technol., 35(2006), No.24, p.19.
J. Liu, Y. Yang, K.Q. Feng, and D. Lu, Study on the effect of current on reactive sintering of the W-C-Co mixture under an electric field, J. Alloys Compd., 476(2009), No.1–2, p.207.
S.Z. Zhou and Q.F. Dong, Super Permanent Magnet, Metallurgical Industry Press, Beijing, 2004, p.89.
Y. Yang, K.Q. Feng, K.Z. Shen, H. He, and H.M. Lin, Low temperature combustion synthesis for preparation of TiC reinforced Fe based composites under electric field, Powder Metall., 49(2006), No.2, p.135.
Y. Yang, K.Q. Feng, K.Z. Shen, H. He, and L.B. Guo, Low-temperature combustion synthesis of Fe-Ti-C system: study on heating-up characteristics and shrinkage kinetics of a compact, Rare Met. Mater. Eng., 33(2004), Suppl., p.110.
Author information
Authors and Affiliations
Corresponding author
Additional information
This work was financially supported by the National Natural Science Foundation of China (No.50945018).
Rights and permissions
About this article
Cite this article
Yang, G., Yang, Y., Lu, D. et al. Effect of heating rate on the densification of NdFeB alloys sintered by an electric field. Int J Miner Metall Mater 19, 1023–1028 (2012). https://doi.org/10.1007/s12613-012-0664-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12613-012-0664-5