Abstract
In this study, the natural polysaccharides chitosan and guar gum-based hydrogel crosslinked with glyoxal was synthesized to examine the efficacy of organic dye removal by adsorption. The maximum swelling capacity of 815% was achieved by optimization studies. The synthesis of hydrogel was proved by the analyses involving XRD, FT-IR, FESEM, and EDS techniques. The adsorption effectiveness of a CH-gl-GG-based hydrogel was examined by adsorbing cationic model dyes Malachite Green (MG) and Auramine O (AO) under various reaction parameters (e.g., dye solution concentration, temperature, adsorption time, and pH). Adsorption equilibrium data showed excellent fit to the Langmuir model for MG (R2 = 0.99) and AO (R2 = 0.99). The adsorption kinetics study indicated that the removal process for both the dyes would be better described by the pseudo-second-order kinetic model. The thermodynamic study demonstrated the spontaneous and endothermic nature of MG and AO dye adsorption. The maximal adsorption capacity (qm) was found to be 40.69 mg/g for MG while 30.51 mg/g for AO. In summary, the CH-gl-GG hydrogel has shown its potential as an environment-friendly and efficient adsorbent for the adsorption of cationic dyes from contaminated water.
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Abbreviations
- CH :
-
Chitosan
- GG :
-
Guar Gum
- Gl :
-
Glyoxal
- AO :
-
Auramine Orange
- MG :
-
Malachite Green
References
L. Zeng, M. Xie, Q. Zhang, Y. Kang, X. Guo, H. Xiao, Y. Peng, J. Luo, Carbohydr. Polym. 123, 89–98 (2015). https://doi.org/10.1016/j.carbpol.2015.01.021
N. Sharma, D.P. Tiwari, S.K. Singh, Int. J. Chem. Environ. Eng. 5, 83 (2014)
A. Çelekli, B. Küçükgüner, H. Bozkurt, Desalin. Water Treat. 57, 25242–25255 (2016). https://doi.org/10.1080/19443994.2016.1149740
J. Fan, D. Chen, N. Li, Q. Xu, H. Li, J. He, J. Lu, Chemospherem 191, 315–323 (2018). https://doi.org/10.1016/j.chemosphere.2017.10.042
K. Kaur, R. Jindal, Carbohydr. Polym. 207, 398–410 (2019). https://doi.org/10.1016/j.carbpol.2018.12.002
C.T. Cesco, A.J.M. Valente, A.T. Paulino, Pharmaceutics 13, 1 (2021). https://doi.org/10.3390/pharmaceutics13060842
A.K. Sharma, B.S. Priya, N. Kaith, J.K. Sharma, V. Bhatia, S.P. Tanwar, S. Bajaj, Int. J. Biol. Macromol. 124, 331 (2019)
A. Da̧browski, Adv. Colloid Interf. Sci. 93, 135 (2001). https://doi.org/10.1016/S0001-8686(00)00082-8
A. Asfaram, M. Ghaedi, S. Agarwal, I. Tyagi, V.K. Gupta, RSC Adv 5, 18438 (2015). https://doi.org/10.1039/c4ra15637d
A.K. Kushwaha, N. Gupta, M.C. Chattopadhyaya, J. Saudi Chem. Soc. 18, 200 (2014). https://doi.org/10.1016/j.jscs.2011.06.011
T. Etemadinia, A. Allahrasani, B. Barikbin, Polym. Bull. 76, 6089 (2019). https://doi.org/10.1007/s00289-019-02681-7
M. Vinuth, H.S.B. Naik, B.M. Vinoda, H. Gururaj, N. Thomas, G. Arunkumar, Mater. Today Proc. 4, 424 (2017). https://doi.org/10.1016/j.matpr.2017.01.041
R. Bhattacharyya, S.K. Ray, J. Ind. Eng. Chem. 20, 3714 (2014). https://doi.org/10.1016/j.jiec.2013.12.071
I.M. Banat, P. Nigam, D. Singh, R. Marchant, Bioresour. Technol. 58, 217 (1996). https://doi.org/10.1016/S0960-8524(96)00113-7
E.L.H. Mohammadine, S. Rachid, M. Rachid, S. Nabil, R. Mohamed, L. Saïd, J. Eng. Stud. Res. 18(3), 43 (2012)
N. Xu, N. Ma, X. Yang, G. Ling, J. Yu, P. Zhang, Eur. Polym. J. 137, 109951 (2020). https://doi.org/10.1016/j.eurpolymj.2020.109951
K. Amel, M.A. Hassen, D. Kerroum, Energy Proced. 19, 286 (2012)
M.A. Ahmad, R. Alrozi, Chem. Eng. J. 168, 280 (2011). https://doi.org/10.1016/j.cej.2011.01.005
K. Kaur, R. Jindal, R. Tanwar, J. Polym. Environ. 27, 19 (2019). https://doi.org/10.1007/s10924-018-1321-5
K. Kaur, R. Jindal, and Meenu. Carbohydr. Polym. 225, 115245 (2019). https://doi.org/10.1016/j.carbpol.2019.115245
T.A. Buhani, S. Wijayanti, M. Ansori, Sustain Environ. Res. 31, 17 (2021). https://doi.org/10.1186/s42834-021-00090-y
S. Ordóez, H. Sastre, F.V. Díez, J. Hazard. Mater. 81, 103 (2001). https://doi.org/10.1016/S0304-3894(00)00317-4
D. Pathania, G. Sharma, R. Thakur, Chem. Eng. J. 267, 235–244 (2015). https://doi.org/10.1016/j.cej.2015.01.004
M.A. Khalil, M.F. El-Kady, G.M. El-Subruiti, E.M. El-Sayed, Desalin. Water Treat. 181, 436 (2020). https://doi.org/10.5004/dwt.2020.25125
R. Bushra, M. Naushad, G. Sharma, A. Azam, Z.A. Alothman, Korean J. Chem. Eng. 34, 1970 (2017). https://doi.org/10.1007/s11814-017-0076-3
V. Vaid, R. Jindal, J. Drug Deliv. Sci. Technol. 67, 102976 (2022). https://doi.org/10.1016/j.jddst.2021.102976
W. Zhao, X. Jin, Y. Cong, J. Fu, J. Chem. Technol. Biotechnol. 88, 327 (2012). https://doi.org/10.1002/jctb.3970
Khushbu and R. Jindal, (2021) J Drug Deliv. Sci. Technol., 61:102325. https://doi.org/10.1016/j.jddst.2021.102325
R. He, D. Xu, B. Cheng, J. Yu, W. Ho, Nanoscale Horizons 3, 464–504 (2018). https://doi.org/10.1039/c8nh00062j
Y. Pan, T. Wu, H. Bao, L. Li, Carbohydr. Polym. 83, 1908 (2011). https://doi.org/10.1016/j.carbpol.2010.10.054
G.Z. Kyzas, D.N. Bikiaris, M. Seredych, T.J. Bandosz, E.A. Deliyanni, Bioresour. Technol. 152, 399 (2014). https://doi.org/10.1016/j.biortech.2013.11.046
H. Lei, M. Xie, Y. Zhao, F. Zhang, Y. Xu, J. Xie, Ceram. Int. 42, 17798 (2016). https://doi.org/10.1016/j.ceramint.2016.08.108
M. Rani, A. Agarwal, Y.S. Negi, J. Biomater. Nanobiotechnol. 2, 71 (2011). https://doi.org/10.4236/jbnb.2011.21010
X. Yuan, R.A. Praphakar, M.A. Munusamy, A.A. Alarfaj, S.S. Kumar, M. Rajan, Carbohydr. Polym. 206, 1 (2019). https://doi.org/10.1016/j.carbpol.2018.10.098
J. Maity, S.K. Ray, Int. J. Biol. Macromol. 89, 246 (2016). https://doi.org/10.1016/j.ijbiomac.2016.04.036
L. Wang, J.P. Stegemann, Acta Biomater. 7, 2410 (2011). https://doi.org/10.1016/j.actbio.2011.02.029
R. Jindal, Mol. Pharm. 18, 3795 (2021). https://doi.org/10.1021/acs.molpharmaceut.1c00340
K. Kaur, R.R. Jindal, D. Jindal, Int. J. Biol. Macromol. 146, 987 (2020). https://doi.org/10.1016/j.ijbiomac.2019.09.223
H. Mittal, S.M. Alhassan, S.S. Ray, J. Environ. Chem. Eng. 6, 7119 (2018). https://doi.org/10.1016/j.jece.2018.11.010
Y.S. Ho, Scientometrics 59, 171 (2004)
H.A. El-Araby, A.M.M.A. Ibrahim, A.H. Mangood, A.A.H. Abdel-Rahman, J. Geosci. Environ. Prot. 05, 109 (2017). https://doi.org/10.4236/gep.2017.57011
K. Kaur, R. Jindal, D. Jindal, J. Drug Deliv. Sci. Technol. 48, 161 (2018). https://doi.org/10.1016/j.jddst.2018.09.003
D. Mudgil, S. Barak, B.S. Khatkar, Int. J. Biol. Macromol. 50, 1035 (2012). https://doi.org/10.1016/j.ijbiomac.2012.02.031
F.S. Matty, M.T. Sultan, A.K. Amine, Ibn Al-Haitham J. Pure Appl. Sci. 28, 136 (2015)
M.T. Yagub, T.K. Sen, S. Afroze, H.M. Ang, Adv. Colloid Interface Sci. 209, 172 (2014). https://doi.org/10.1016/j.cis.2014.04.002
M. Ahmaruzzaman, S.L. Gayatri, Chem. Eng. J. 158, 173 (2010). https://doi.org/10.1016/j.cej.2009.12.027
T.K. Arumugam, P. Krishnamoorthy, N.R. Rajagopalan, S. Nanthini, D. Vasudevan, Int. J. Biol. Macromol. 128, 655 (2019). https://doi.org/10.1016/j.ijbiomac.2019.01.185
S.J. Peighambardoust, O. Aghamohammadi-Bavil, R. Foroutan, N. Arsalani, Int. J. Biol. Macromol. 159, 1122 (2020). https://doi.org/10.1016/j.ijbiomac.2020.05.093
M. Ghaedi, S. Hajati, M. Zare, M. Zare, S.Y. Shajaripour Jaberi, RSC. Adv. 5, 38939 (2015). https://doi.org/10.1039/c5ra02531a
I.D. Mall, V.C. Srivastava, N.K. Agarwal, I.M. Mishra, Colloids Surf. A Physicochem. Eng. Asp. 264, 17 (2005). https://doi.org/10.1016/j.colsurfa.2005.03.027
I.D. Mall, V.C. Srivastava, N.K. Agarwal, J. Hazard. Mater. 143, 386 (2007). https://doi.org/10.1016/j.jhazmat.2006.09.059
S. Chaudhary, J. Sharma, B.S. Kaith, S. Yadav, A.K. Sharma, A. Goel, Ecotoxicol. Environ. Saf. 149, 150 (2018). https://doi.org/10.1016/j.ecoenv.2017.11.030
J. Sukriti, V. Sharma, P. Pruthi, A.P.S. Anand, J.B. Chaddha, B.S. Kaith, RSC Adv. 6, 74300 (2016). https://doi.org/10.1039/c6ra12715k
Acknowledgements
The authors, Khushbu and Vasudha Vaid are grateful to the Ministry of Human Resources and Development, Delhi India for funding research. For the characterizations, the author is grateful to SAIF/CIL Punjab University Chandigarh, Material Research Centre Jaipur, and CIF Lovely Professional University Jalandhar.
Funding
Ministry of Human Resource Development, Reg no. Khushbu Yadav (18511103), Vasudha Vaid (19511114).
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Vaid, V., Khushbu, Kaur, K. et al. Removal of Organic Dyes from Aqueous Solutions by Adsorption of Chitosan-Guar Gum-Based Glyoxal Crosslinked Hydrogel. Fibers Polym 24, 383–401 (2023). https://doi.org/10.1007/s12221-023-00080-4
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DOI: https://doi.org/10.1007/s12221-023-00080-4