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Cobalt sulphide/graphene aerogel nanocomposite with enhanced anode performance for lithium energy storage

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Abstract

Cobalt sulphide/graphene aerogel nanocomposite (CGA) is successfully fabricated via a one-pot hydrothermal approach aided with ethylenediamine. CoS nanoparticles constructed by nanoplates are uniformly anchored and well distributed on the loose graphene aerogel framework. Owing to a synergistic effect combining nanosized CoS with graphene aerogel advantages, CGA as an anode material for lithium energy storage exhibits high reversible capacity, superior long-cycle property and excellent high-rate capability. Prominently, CGA maintains a high capacity approaching ~1100 mAh g−1 after 200 cycles at 100 mA g−1. Even at 1 A g−1, CGA still delivers a capacity of 460 mAh g−1. This approach can be readily applicable to prepare other graphene aerogel-based nanocomposites as anode materials.

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References

  1. Chen W Y, Zhang X M, Peng Y Q, Mo L E, Li Z Q, Zhang Y S et al 2019 J. Power Sources 438 227041

    Article  Google Scholar 

  2. Wang H J, Ma J J, Liu S, Nie L Y, Chai Y Q, Yang X et al 2016 J. Alloys Compd. 676 551

    Article  CAS  Google Scholar 

  3. Long B, Zhou X Y, Tang J J and Yang J 2018 Chem. Phys. Lett. 710 129

    Article  CAS  Google Scholar 

  4. Zhang J Y, Yu L and Lou X W D 2017 Nano Res. 10 4298

    Article  CAS  Google Scholar 

  5. Wang Y, Guo X M, Wang Z K, Lv M F, Wu B, Wang Y et al 2017 J. Mater. Chem. A 5 25562

    Article  CAS  Google Scholar 

  6. Zhao J J, Liu D X, Gu C P, Zhu M Y, Ryu S O and Huang J R 2018 Mater. Chem. Phys. 217 102

    Article  CAS  Google Scholar 

  7. Guo J X, Li F F, Sun Y F, Zhang X and Tang L 2015 Electrochim. Acta 167 32

    Article  CAS  Google Scholar 

  8. Li Z P, Li W Y, Xue H T, Kang W P, Yang X, Sun M L et al 2014 RSC Adv. 4 37180

    Article  CAS  Google Scholar 

  9. Xu C, Jing Y, He J R, Zhou K R, Chen Y F, Li Q et al 2017 J. Alloys Compd. 708 1178

    Article  CAS  Google Scholar 

  10. Chen Y J, Liu Z E, Sun L, Lu Z W and Zhuo K L 2018 J. Power Sources 390 215

    Article  CAS  Google Scholar 

  11. Kong W Q, Duan X D, Ge Y J, Liu H T, Hu J W and Duan X F 2016 Nano Res. 9 2458

    Article  CAS  Google Scholar 

  12. Tang S, Sun J, Xia D S, Zang B, Gao Y H, Chen C X et al 2019 Talanta 195 165

    Article  CAS  Google Scholar 

  13. Zhang B H, Wang H X, Zuo Z, Wang H S and Zhang J T 2018 J. Mater. Chem. A 6 15728

    Article  CAS  Google Scholar 

  14. Hummers W S and Offeman R E 1958 J. Am. Chem. Soc. 80 1339

    Article  CAS  Google Scholar 

  15. Zhu J, Zhou W T, Zhou Y Z, Cheng X N and Yang J 2019 J. Electron. Mater. 48 1531

    Article  CAS  Google Scholar 

  16. Dai K, Li D P, Lu L H, Liu Q, Lv J L and Zhu G P 2014 RSC Adv. 4 29216

    Article  CAS  Google Scholar 

  17. Lin H L, Liu F, Wang X J, Ai Y N, Yao Z Q, Chu L et al 2016 Electrochim. Acta 191 705

    Article  CAS  Google Scholar 

  18. Fan L L, Li X F, Yan B, Li X J, Xiong D B, Li D J et al 2016 Appl. Energy 175 529

    Article  CAS  Google Scholar 

  19. Wang Y H, Wu B H, He X Y, Zhang Y Y, Li H, Peng Y Y et al 2017 Electrochim. Acta 230 299

    Article  CAS  Google Scholar 

  20. Huang K J, Zhang J Z, Shi G W and Liu Y M 2014 Mater. Lett. 131 45

    Article  CAS  Google Scholar 

  21. Xu Y, Sheng K, Li C and Shi G 2010 ACS Nano 4 4324

    Article  CAS  Google Scholar 

  22. Zhang Y F, Zheng J Q, Jing X Y and Meng C G 2018 Dalton Trans. 47 8052

    Article  CAS  Google Scholar 

  23. Choi J, Yang M and Kim S K 2017 Appl. Surf. Sci. 422 316

    Article  CAS  Google Scholar 

  24. Sharma G and Gosavi S G 2017 Ceram. Int. 43 4888

    Article  CAS  Google Scholar 

  25. Zhao R R, Li K, Liu R Z, Sarfraz M, Shakir I and Xu Y X 2017 J. Mater. Chem. A 5 19098

    Article  CAS  Google Scholar 

  26. Zheng F C, Yin Z C, Xia H Y and Zhang Y G 2017 Mater. Lett. 197 188

    Article  Google Scholar 

  27. Wang B R, Wen Z Y, Jin J, Hong X H, Zhang S P and Rui K 2017 J. Power Sources 342 521

    Article  CAS  Google Scholar 

  28. Zhang K X, Yang H X, Lv M F, Yan C, Wu H P, Yuan A H et al 2018 J. Alloys Compd. 731 646

    Article  CAS  Google Scholar 

  29. Huang M, Mi K, Zhang J H, Liu H L, Yu T T, Yuan A H et al 2017 J. Mater. Chem. A 5 266

    Article  CAS  Google Scholar 

  30. Wu C Y, Chang W E, Sun Y G, Wu J M and Duh J G 2018 Mater. Chem. Phys. 219 311

    Article  CAS  Google Scholar 

  31. Zhu J, Jin M H and Tang S 2019 J. Nanosci. Nanotechnol. 19 5921

    Article  CAS  Google Scholar 

  32. Huang X K, Cui S M, Chang J B, Hallac P B, Fell C R, Luo Y T et al 2015 Angew. Chem. Int. Ed. 54 1490

    Article  CAS  Google Scholar 

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Acknowledgement

This study was financially supported by Natural Science Foundation of China (Grant No. 21705060).

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Authors and Affiliations

  1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, People’s Republic of China

    Jia Zhu, Yi Zhao, Peixiang Ning & Sheng Tang

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  1. Jia Zhu
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  2. Yi Zhao
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  3. Peixiang Ning
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  4. Sheng Tang
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Correspondence to Jia Zhu.

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Zhu, J., Zhao, Y., Ning, P. et al. Cobalt sulphide/graphene aerogel nanocomposite with enhanced anode performance for lithium energy storage. Bull Mater Sci 44, 4 (2021). https://doi.org/10.1007/s12034-020-02275-4

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