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Toward a new generation of fertilizers with the approach of controlled-release fertilizers: a review

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Abstract

Coping with the growth of the global population and the necessity for food, the agricultural sector has been compelled to rely heavily on fertilizers as a means to enhance both the quantity and quality of agricultural products. The drastic depletion of these fertilizers (30-50%) poses a serious risk to both human safety and the environment. Researchers have introduced new-generation fertilizers (NGFs) to tackle these challenges. This study initially examined the pros and cons, nitrogen loss, and global usage of traditional fertilizers. Subsequently, it categorized different types of NGFs, with a particular focus on the utilization of controlled-release fertilizers (CRFs). Afterward, the research delved into studying the nutrient release mechanism, the type of coating materials, the techniques employed for coating, the advantages and challenges related to CRFs, and the impact of specific parameters on the mechanism of CRFs. In conclusion, we have presented a comprehensive overview of several commercially manufactured variants of CRFs. The utilization of CRFs is experiencing a notable upward trend, exhibiting a compound annual growth rate (CAGR) of 6.37%. Moreover, this growth includes active involvement from governments, farmers, and industries.

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References

  1. Brown, ME, Hintermann, B, Higgins, N, “Markets, Climate Change, and Food Security in West Africa.” Environ. Sci. Technol., 43 (21) 8016–8020 (2009) https://doi.org/10.1021/es901162d

    Article  CAS  Google Scholar 

  2. Karp, A, Richter, GM, “Meeting the Challenge of Food and Energy Security.” J. Exp. Botany, 62 (10) 3263–3271 (2011) https://doi.org/10.1093/jxb/err099

    Article  CAS  Google Scholar 

  3. Prosekov, AY, Ivanova, SA, “Food Security: The Challenge of the Present.” Geoforum, 91 73–77 (2018) https://doi.org/10.1016/j.geoforum.2018.02.030

    Article  Google Scholar 

  4. Plimmer, JR, Encyclopedia of Agrochemicals. John Wiley & Sons, Inc. (2003) https://doi.org/10.1002/047126363X

  5. Shaviv, A, “Advances in Controlled-Release Fertilizers.” Adv. Agronom., 71 1–49 (2001) https://doi.org/10.1016/S0065-2113(01)71011-5

    Article  CAS  Google Scholar 

  6. Liu, L, Zhang, X, Xu, W, Liu, X, Li, Y, Wei, J, Gao, M, Bi, J, Lu, X, Wang, Z, “Challenges for Global Sustainable Nitrogen Management in Agricultural Systems.” J. Agric. Food Chem., 68 (11) 3354–3361 (2020) https://doi.org/10.1021/acs.jafc.0c00273

    Article  CAS  Google Scholar 

  7. Oertli, J, “Controlled-Release Fertilizers.” Fertilizer Res., 1 (2) 103–123 (1980) https://doi.org/10.1007/BF01073182

    Article  Google Scholar 

  8. Hauck, RD, “Slow-Release and Bioinhibitor-Amended Nitrogen Fertilizers.” Fertilizer Technol. Use (1985) https://doi.org/10.2136/1985.fertilizertechnology.c8

    Article  Google Scholar 

  9. Azeem, B, KuShaari, K, Man, Z, “Effect of Coating Thickness on Release Characteristics of Controlled Release Urea Produced in Fluidized Bed Using Waterborne Starch Biopolymer as Coating Material.” Procedia Eng., 148 282–289 (2016) https://doi.org/10.1016/j.proeng.2016.06.615

    Article  CAS  Google Scholar 

  10. Beig, B, Niazi, MBK, Jahan, Z, Hussain, A, Zia, MH, Mehran, MT, “Coating Materials for Slow Release of Nitrogen from Urea Fertilizer: A Review.” J. Plant Nutrition, 43 (10) 1510–1533 (2020) https://doi.org/10.1080/01904167.2020.1744647

    Article  CAS  Google Scholar 

  11. Sharma, N, Singh, A, “A Review on Changes in Fertilizers: From Coated Controlled Release Fertilizers (CRFs) to Nanocomposites of CRFs.” Int. J. Agric. Sci. Res., 9 (2) 53–74 (2019) https://doi.org/10.24247/ijasrpr20197

  12. Trenkel, ME, “Slow- and Controlled-Release and Stabilized Fertilizers: An Option for Enhancing Nutrient Use Efficiency in Agriculture.” IFA, Int. Fertilizer Ind. Assoc. (2010) https://www.fertilizer.org/images/Library_Downloads/2010_Trenkel_slow%20release%20book.pdf

  13. Calabi-Floody, M, Medina, J, Rumpel, C, Condron, LM, Hernandez, M, Dumont, M, de la Luz Mora, M, “Smart Fertilizers as a Strategy for Sustainable Agriculture.” In: Adv. Agronom., pp. 119–157. Elsevier, Inc. (2018) https://doi.org/10.1016/bs.agron.2017.10.003

  14. Chen, J, Lü, S, Zhang, Z, Zhao, X, Li, X, Ning, P, Liu, M, “Environmentally Friendly Fertilizers: A Review of Materials Used and their Effects on the Environment.” Sci. Total Environ., 613 829–839 (2018) https://doi.org/10.1016/j.scitotenv.2017.09.186

  15. Hazra, G, “Different Types of Eco-Friendly Fertilizers: An Overview.” Sustain. Environ., 1 (1) 54–70 (2016) https://doi.org/10.22158/se.v1n1p54

  16. Bokhtiar, S, Sakurai, K, “Effects of Organic Manure and Chemical Fertilizer on Soil Fertility and Productivity of Plant and Ratoon Crops of Sugarcane.” Arch. Agron. Soil Sci., 51 (3) 325–334 (2005) https://doi.org/10.1080/03650340500098006

  17. Das, SK, “Role of Micronutrient in Rice Cultivation and Management Strategy in Organic Agriculture—A Reappraisal.” Agricultural Sci., 5 765–769 (2014) https://doi.org/10.4236/as.2014.59080

  18. Tripathi, DK, Singh, VP, Chauhan, DK, Prasad, SM, Dubey, NK, “Role of Macronutrients in Plant Growth and Acclimation: Recent Advances and Future Prospective.” In: Ahmad, P, Wani, MR, Azooz, MM, Phan Tran, LS (eds.) Improvement of Crops in the Era of Climatic Changes, pp. 197–216. Springer, New York, NY (2014) https://doi.org/10.1007/978-1-4614-8824-8_8

  19. Chandini, KR, Kumar, R, Prakash, O, “The Impact of Chemical Fertilizers on Our Environment and Ecosystem.” Res. Trends Environ. Sci., pp. 69–86 (2019) https://www.researchgate.net/publication/331132826

  20. Bergstrand, K-J, “Organic Fertilizers in Greenhouse Production Systems–A Review.” Sci. Horticulturae, 295 110855 (2022) https://doi.org/10.1016/j.scienta.2021.110855

  21. Singh, RP, Organic Fertilizers: Types, Production and Environmental Impact. Nova Science Publishers (2012) https://www.researchgate.net/publication/274896698_Organic_Fertilizers_Types_Production_and_Environmental_Impact

  22. Falls, J, Siegel, S, “Fertilizers.” In: Encyclopedia of Analytical Science (Second Edition), pp. 1–8 (2005) https://doi.org/10.1016/B0-12-369397-7/00150-3

  23. Barker, AV, “Fertilizers.” In: Paul, W, Colin, P, Alan, T, Manuel, M (eds.) Encyclopedia of Analytical Science (Third Edition), pp. 134–144. Academic Press (2019) https://doi.org/10.1016/B978-0-12-409547-2.00142-6

  24. Halpern, M, Bar-Tal, A, Ofek, M, Minz, D, Muller, T, Yermiyahu, U, “The Use of Biostimulants for Enhancing Nutrient Uptake.” In: Sparks, DL (ed.) Advances in Agronomy, pp. 141–174. Elsevier (2015) https://doi.org/10.1016/bs.agron.2014.10.001

  25. Habibi, A, Heidari, G, Sohrabi, Y, Badakhshan, H, Mohammadi, K, “Influence of Bio, Organic and Chemical Fertilizers on Medicinal Pumpkin Traits.” J. Med. Plants Res., 5 (23) 5590–5597 (2011) https://doi.org/10.14720/aas.2014.103.1.08

  26. Seo, HJ, Park, AR, Kim, S, Yeon, J, Yu, NH, Ha, S, Chang, JY, Park, HW, Kim, J-C, “Biological Control of Root-Knot Nematodes by Organic Acid-Producing Lactobacillus brevis WiKim0069 Isolated from Kimchi.” Plant Pathol. J., 35 (6) 662 (2019) https://doi.org/10.5423/PPJ.OA.08.2019.0225

  27. Perrott, K, Sarathchandra, S, Dow, B, “Seasonal and Fertilizer Effects on the Organic Cycle and Microbial Biomass in a Hill Country Soil Under Pasture.” Soil Res., 30 (3) 383–394 (1992) https://doi.org/10.1071/SR9920383

  28. Steinshamn, H, Thuen, E, Bleken, MA, Brenøe, UT, Ekerholt, G, Yri, C, “Utilization of Nitrogen (N) and Phosphorus (P) in an Organic Dairy Farming System in Norway.” Agriculture, Ecosyst. Environ., 104 (3) 509–522 (2004) https://doi.org/10.1016/j.agee.2004.01.022

  29. Black, CA, “Reducing American Exposure to Nitrate, Nitrite, and Nitroso Compounds: The National Network to Prevent Birth Defects Proposal.” pp. 1–14. Council for Agricultural Science and Technology (1989) https://www.cast-science.org/wp-content/uploads/1989/06/CAST-CC1989-1_Reducing-American-Exposure-to-Nitrates.pdf

  30. Newbould, P, “The Use of Nitrogen Fertiliser in Agriculture. Where do we go Practically and Ecolotically?” Plant and Soil, 115 (2) 297–311 (1989) https://doi.org/10.1007/978-94-009-1021-8_27

  31. Fenn, L, Hossner, L, “Ammonia Volatilization from Ammonium or Ammonium-Forming Nitrogen Fertilizers.” In: Stewart, BA (ed.) Advances in Soil Science, pp. 123–169. Springer New York, New York, NY (1985) https://doi.org/10.1007/978-1-4612-5046-3_4

  32. Skiba, U, “Denitrification.” In: Sven, EJ, Fath, BD (eds.) Encyclopedia of Ecology, pp. 866–871. Academic Press (2008) https://doi.org/10.1016/B978-008045405-4.00264-0

  33. Tenkorang, F, Lowenberg-DeBoer, J, “Forecasting Long-Term Global Fertilizer Demand.” Nutrient Cycli. Agroecosyst., 83 (3) 233 (2009) https://doi.org/10.1007/s10705-008-9214-y

  34. FAO, “World Fertilizer Trends and Outlook to 2020: Summary Report.” pp. 1–27. FAO Rome (2017) http://www.fao.org/3/a-i6895e.pdf

  35. Wei, X, Chen, J, Gao, B, Wang, Z, “Role of Controlled and Slow Release Fertilizers in Fruit Crop Nutrition.” In: Srivastava, AK, Hu, C (eds.) Fruit Crops, pp. 555–566. Elsevier (2020) https://doi.org/10.1016/B978-0-12-818732-6.00039-3

  36. Ghorbanpour, M, Bhargava, P, Varma, A, Choudhary, DK, Biogenic Nano-Particles and their Use in Agro-Ecosystems. Springer (2020) https://doi.org/10.1007/978-981-15-2985-6

  37. Liu, R, Lal, R, “Potentials of Engineered Nanoparticles as Fertilizers for Increasing Agronomic Productions.” Sci. Total Environ., 514 131–139 (2015) https://doi.org/10.1016/j.scitotenv.2015.01.104

  38. Cantarella, H, Otto, R, Soares, JR, de Brito Silva, AG, “Agronomic Efficiency of NBPT as a Urease Inhibitor: A Review.” J. Adv. Res., 13 19–27 (2018) https://doi.org/10.1016/j.jare.2018.05.008

  39. Weiske, A, Benckiser, G, Ottow, JC, “Effect of the New Nitrification Inhibitor DMPP in Comparison to DCD on Nitrous Oxide (N2O) Emissions and Methane (CH4) Oxidation During 3 Years of Repeated Applications in Field Experiments.” Nutrient Cycl. Agroecosyst., 60 (1-3) 57–64 (2001) https://doi.org/10.1023/A:1012669500547

  40. Whitehurst, GB, Whitehurst, BM, “NBPT Solutions for Preparing Urease Inhibited Urea Fertilizers Pepared from N-Substituted Morpholines.” (2014) https://patents.google.com/patent/US8888886B1/en

  41. Weston, CW, Peacock, LA, Thornsberry Jr, WL, “Fluid Urea-Containing Fertilizer.” (2014) https://patents.google.com/patent/CA2117866C/en

  42. Liu, H, Jiamin, W, Gomes, A, Shanmuga, K, Chen, Z, “Stabilized DCD and/or Alkyl Thiophosphoric Triamide Solvent Systems and Use in Agricultural Applications.” (2018) https://patents.google.com/patent/WO2018005743A1/en

  43. Timilsena, YP, Adhikari, R, Casey, P, Muster, T, Gill, H, Adhikari, B, “Enhanced Efficiency Fertilisers: A Review of Formulation and Nutrient Release Patterns.” J. Sci. Food Agriculture, 95 (6) 1131–1142 (2015) https://doi.org/10.1002/jsfa.6812

  44. Mikula, K, Izydorczyk, G, Skrzypczak, D, Mironiuk, M, Moustakas, K, Witek-Krowiak, A, Chojnacka, K, “Controlled Release Micronutrient Fertilizers for Precision Agriculture–A Review.” Sci. Total Environ., 712 136365 (2020) https://doi.org/10.1016/j.scitotenv.2019.136365

  45. DeRosa, MC, Monreal, C, Schnitzer, M, Walsh, R, Sultan, Y, “Nanotechnology in Fertilizers.” Nature Nanotechnol., 5 (2) 91 (2010) https://doi.org/10.1038/nnano.2010.2

  46. Sekhon, BS, “Nanotechnology in Agri-Food Production: An Overview.” Nanotechnol. Sci. Appl., 7 31 (2014) https://doi.org/10.2147/NSA.S39406

  47. Pereira, EI, da Cruz, CC, Solomon, A, Le, A, Cavigelli, MA, Ribeiro, C, “Novel Slow-Release Nanocomposite Nitrogen Fertilizers: The Impact of Polymers on Nanocomposite Properties and Function.” Ind. Eng. Chem. Res., 54 (14) 3717–3725 (2015) https://doi.org/10.1021/acs.iecr.5b00176

  48. Preetha, PS, Balakrishnan, N, “A Review of Nano Fertilizers and Their Use and Functions in Soil.” Int. J. Curr. Microbiol. App. Sci., 6 (12) 3117–3133 (2017) https://doi.org/10.20546/ijcmas.2017.612.364

  49. Vicente, T, Mota, JP, Peixoto, C, Alves, PM, Carrondo, MJ, “Rational Design and Optimization of Downstream Processes of Virus Particles for Biopharmaceutical Applications: Current Advances.” Biotechnol. Adv., 29 (6) 869–878 (2011) https://doi.org/10.1016/j.biotechadv.2011.07.004

  50. Wilson, MA, Tran, NH, Milev, AS, Kannangara, GK, Volk, H, Lu, GM, “Nanomaterials in Soils.” Geoderma, 146 (1–2) 291–302 (2008) https://doi.org/10.1016/j.geoderma.2008.06.004

  51. Guo, H, White, JC, Wang, Z, Xing, B, “Nano-Enabled Fertilizers to Control the Release and Use Efficiency of Nutrients.” Current Opinion in Environ. Sci. Health, 6 77–83 (2018) https://doi.org/10.1016/j.coesh.2018.07.009

  52. Mikkelsen, R, “Nanofertilizer and Nanotechnology: A Quick Look.” Better Crops with Plant Food, 102 (3) 18–19 (2018) https://doi.org/10.24047/BC102318

  53. Guha, T, Gopal, G, Kundu, R, Mukherjee, A, “Nanocomposites for Delivering Agrochemicals: A Comprehensive Eeview.” J. Agricultural and Food Chem., 68 (12) 3691–3702 (2020) https://doi.org/10.1021/acs.jafc.9b06982

  54. Sempeho, SI, Kim, HT, Mubofu, E, Hilonga, A, “Meticulous Overview on the Controlled Release Fertilizers.” Adv. Chem., 2014 1–16 (2014) https://doi.org/10.1155/2014/363071

  55. Trenkel, ME, Controlled-Release and Stabilized Fertilizers in Agriculture. International Fertilizer Industry Association Paris (1997) http://www.wnkgroup.com/Controlled-Release%20fertilizer%20in%20Agriculture.pdf

  56. Jarrell, W, Boersma, L, “Release of Urea by Granules of Sulfur‐Coated Urea.” Soil Sci. Soci. America J., 44 (2) 418–422 (1980) https://doi.org/10.2136/sssaj1980.03615995004400020042x

  57. Mann, M, Kruger, JE, Andari, F, McErlean, J, Gascooke, JR, Smith, JA, Worthington, MJ, McKinley, CC, Campbell, JA, Lewis, DA, “Sulfur Polymer Composites as Controlled-Release Fertilisers.” Organic & Biomolecular Chem., 17 (7) 1929–1936 (2019) https://doi.org/10.1039/C8OB02130A

  58. Baboo, P, “Sulphur Coated Urea.” National Fertilizers Ltd. Vijaipur, India (2016) https://www.researchgate.net/publication/301799338

  59. Detrick, JH, Hargrove, GL, “Polymer-Sulfur-Polymer Coated Fertilizers.” Google Patents (2002) https://patents.google.com/patent/US6338746B1/en

  60. Sharma, N, Singh, A, “A Review on Changes in Fertilizers: From Coated Controlled Release Fertilizers (CRFs) to Nanocomposites of CRFs.” Int. J. Agricultural Sci. Res. (IJASR), 9 (2) 53–74 (2019) https://doi.org/10.24247/ijasrapr20197

  61. Lawrencia, D, Wong, SK, Low, DYS, Goh, BH, Goh, JK, Ruktanonchai, UR, Soottitantawat, A, Lee, LH, Tang, SY, “Controlled Release Fertilizers: A Review on Coating Materials and Mechanism of Release.” Plants, 10 (2) 238 (2021) https://doi.org/10.3390/plants10020238

  62. Rajan, M, Shahena, S, Chandran, V, Mathew, L, “Controlled Release of Fertilizers—Concept, Reality, and Mechanism.” Controll. Release Fertiliz. Sustain. Agriculture, pp. 41–56. Elsevier (2021) https://doi.org/10.1016/B978-0-12-819555-0.00003-0

  63. Essays, U, “A Review Of Controlled Release Fertilizers Biology Essay.” (2018) https://www.ukessays.com/essays/biology/a-review-of-controlled-release-fertilizers-biology-essay.php?vref=1

  64. Babar, S, Shah, Z, Rajpar, I, Yusop, M, Taban, S, “Developing a Novel Coated Urea with Biodegradable Polymer and Urease Inhibitors to Enhance the Yield of Rice Grown Under an Ustic Torrifluent.” J. Animal and Plant Sci., 32 (6) (2022) https://doi.org/10.36899/JAPS.2022.6.0572

  65. Ghumman, ASM, Shamsuddin, R, Nasef, MM, Yahya, WZN, Abbasi, A, Almohamadi, H, “Sulfur Enriched Slow-Release Coated Urea Produced from Inverse Vulcanized Copolymer.” Sci. Total Environ., 846 157417 (2022) https://doi.org/10.3390/polym14204323

  66. Hamidi, RM, Siyal, AA, Luukkonen, T, Shamsuddin, RM, Moniruzzaman, M, “Fly Ash Geopolymer as a Coating Material for Controlled-Release Fertilizer Based on Granulated Urea.” RSC Adv., 12 (51) 33187–33199 (2022) https://doi.org/10.1039/D2RA06056F

  67. Kontárová, S, Přikryl, R, Škarpa, P, Kriška, T, Antošovský, J, Gregušková, Z, Figalla, S, Jašek, V, Sedlmajer, M, Menčík, P, “Slow-Release Nitrogen Fertilizers with Biodegradable Poly (3-hydroxybutyrate) Coating: Their Effect on the Growth of Maize and the Dynamics of N Release in Soil.” Polymers, 14 (20) 4323 (2022) https://doi.org/10.3390/polym14204323

  68. Zhang, M, Lianbu, W, Yuechao, Y, Jianqiu, C, Li, M, Haining, C, “Reclaim the Production Method of Thermoplastic Resin and Thermosetting Resin Multi-Layer Composite Coated Controlled-Release Fertilizer.” (2019) https://patents.google.com/patent/CN100567222C/en

  69. Zhang, M, Yuechao, Y, Lianbu, W, “Coated Controlled Release Fertilizer of Degradable Film Prepared by Reclaiming Thermoplastic Resin.” (2006) https://patents.google.com/patent/CN1603288A/en

  70. Hongkun, C, Lianbu, W, Lingchao, F, Hengjun, X, Huaisheng, C, “Water Soluble Alkyd Resin-Sulfur Coated Controlled Release Fertilizer and Preparation Thereof.” (2011) https://patents.google.com/patent/US20110072871A1/en

  71. Lianbu, W, Lingchao, F, Qingling, Z, Deqing, C, Yiwu, G, Hongkun, C, “Emulsion Polymer Coating Agent, Coated Controlled-Release Fertilizer and Preparation Thereof.” (2009) https://patents.google.com/patent/WO2009143653A1/en

  72. Abhiram, G, Bishop, P, Jeyakumar, P, Grafton, M, Davies, CE, McCurdy, M, “Formulation and Characterization of Polyester-Lignite Composite Coated Slow-Release Fertilizers.” J. Coat. Technol. Res., 20 (1) 307–320 (2023) https://doi.org/10.1007/s11998-022-00670-6

  73. Yuan, S, Cheng, L, Tan, Z, “Characteristics and Preparation of Oil-Coated Fertilizers: A Review.” J. Controll. Release (2022) https://doi.org/10.1016/j.jconrel.2022.03.040

  74. Liang, D, Zhang, Q, Zhang, W, Liu, L, Liang, H, Quirino, RL, Chen, J, Liu, M, Lu, Q, Zhang, C, “Tunable Thermo-Physical Performance of Castor Oil-Based Polyurethanes with Tailored Release of Coated Fertilizers.” J. Clean. Prod., 210 1207–1215 (2019) https://doi.org/10.1016/j.jclepro.2018.11.047

  75. Bortoletto‐Santos, R, Ribeiro, C, Polito, WL, “Controlled Release of Nitrogen‐Source Fertilizers by Natural‐Oil‐Based Poly (Urethane) Coatings: The Kinetic Aspects of Urea Release.” J. Appl. Polym. Sci., 133 (33) (2016) https://doi.org/10.1002/app.43790

  76. Xie, J, Yang, Y, Gao, B, Wan, Y, Li, YC, Xu, J, Zhao, Q, “Biomimetic Superhydrophobic Biobased Polyurethane-Coated Fertilizer with Atmosphere “Outerwear”.” ACS Appl. Mater. Interfaces, 9 (18) 15868–15879 (2017) https://doi.org/10.1021/acsami.7b02244

  77. Naik, MR, Kumar, BK, Manasa, K, “Polymer Coated Fertilizers as Advance Technique in Nutrient Management.” Asian J. Soil Sci., 12 (1) 228–232 (2017) https://doi.org/10.15740/HAS/AJSS/12.1/228-232

  78. Li, Y, Jia, C, Zhang, X, Jiang, Y, Zhang, M, Lu, P, Chen, H, “Synthesis and Performance of Bio-Based Epoxy Coated Urea as Controlled Release Fertilizer.” Prog. Org. Coat., 119 50–56 (2018) https://doi.org/10.1016/j.porgcoat.2018.02.013

  79. Fertahi, S, Bertrand, I, Ilsouk, M, Oukarroum, A, Zeroual, Y, Barakat, A, “New Generation of Controlled Release Phosphorus Fertilizers Based on Biological Macromolecules: Effect of Formulation Properties on Phosphorus Release.” Int. J. Biol. Macromol., 143 153–162 (2020) https://doi.org/10.1016/j.ijbiomac.2019.12.005

  80. Liu, X, Yang, Y, Gao, B, Li, Y, “Organic Silicone‐Modified Transgenic Soybean Oil as Bio‐Based Coating Material for Controlled‐Release Urea Fertilizers.” J. Appl. Polym. Sci., 133 (41) 1–8 (2016) https://doi.org/10.1002/app.44097

  81. Lu, H, Tian, H, Zhang, M, Liu, Z, Chen, Q, Guan, R, Wang, H, “Water Polishing Improved Controlled-Release Characteristics and Fertilizer Efficiency of Castor Oil-Based Polyurethane Coated Diammonium Phosphate.” Sci. Rep., 10 (1) 1–10 (2020) https://doi.org/10.1038/s41598-020-62611-w

  82. Lu, P, Zhang, Y, Jia, C, Li, Y, Zhang, M, Mao, Z, “Degradation of Polyurethane Coating Materials from Liquefied Wheat Straw for Controlled Release Fertilizers.” J. Appl. Polym. Sci., 133 (41) (2016) https://doi.org/10.1002/app.44021

  83. Bortoletto‐Santos, R, Ribeiro, C, Polito, WL, “Controlled Release of Nitrogen‐Source Fertilizers by Natural‐Oil‐Based Poly (Urethane) Coatings: The Kinetic Aspects of Urea Release.” J. Appl. Polym. Sci., 133 (33) 1–8 (2016) https://doi.org/10.1002/app.43790

  84. Yang, Y-c, Zhang, M, Li, Y, Fan, X-h, Geng, Y-q, “Improving the Quality of Polymer-Coated Urea with Recycled Plastic, Proper Additives, and Large Tablets.” J. Agricultural Food Chem., 60 (45) 11229–11237 (2012) https://doi.org/10.1021/jf302813g

  85. Mathews, AS, Narine, S, “Poly [N‐isopropyl Acrylamide]‐Co‐Polyurethane Copolymers for Controlled Release of Urea.” J. Polymer Sci. Part A: Polym. Chem., 48 (15) 3236–3243 (2010) https://doi.org/10.1002/pola.24090

  86. Han, WY, Ma, LF, Shi, YZ, Ruan, JY, Kemmitt, SJ, “Nitrogen Release Dynamics and Transformation of Slow Release Fertiliser Products and their Effects on Tea Yield and Quality.” J. Sci. Food Agriculture, 88 (5) 839–846 (2008) https://doi.org/10.1002/jsfa.3160

  87. Jintakanon, N, Opaprakasit, P, Petchsuk, A, Opaprakasit, M, “Controlled-Release Materials for Fertilizer Based on Lactic Acid Polymers.” Proc. Adv. Mater. Res., 55 905–908 (2008) https://doi.org/10.4028/www.scientific.net/AMR.55-57.905

  88. Qiu, X, Zhu, D, Tao, S, Chen, C, Ren, X, Hu, S, “1‐Naphthylacetic‐Acid‐Functionalized Polyacrylate‐Coated Urea with Dual Controlled‐Release Properties.” J. Appli. Polym. Sci., 129 (2) 559–567 (2013) https://doi.org/10.1002/app.38656

  89. Tomaszewska, M, Jarosiewicz, A, Karakulski, K, “Physical and Chemical Characteristics of Polymer Coatings in CRF Formulation.” Desalination, 146 (1-3) 319–323 (2002) https://doi.org/10.1016/S0011-9164(04)90196-8

  90. Costa, MM, Cabral-Albuquerque, EC, Alves, TL, Pinto, JC, Fialho, RL, “Use of Polyhydroxybutyrate and Ethyl Cellulose for Coating of Urea Granules.” J. Agricultural Food Chem., 61 (42) 9984–9991 (2013) https://doi.org/10.1021/jf401185y

  91. Heuchan, SM, Fan, B, Kowalski, JJ, Gillies, ER, Henry, HA, “Development of Fertilizer Coatings from Polyglyoxylate–Polyester Blends Responsive to Root-Driven pH Change.” J. Agricultural Food Chem., 67 (46) 12720–12729 (2019) https://doi.org/10.1021/acs.jafc.9b04717

  92. Guo, M, Liu, M, Zhan, F, Wu, L, “Preparation and Properties of a Slow-Release Membrane-Encapsulated Urea Fertilizer with Superabsorbent and Moisture Preservation.” Ind. Eng. Chem. Res., 44 (12) 4206–4211 (2005) https://doi.org/10.1021/ie0489406

  93. Liang, R, Liu, M, “Preparation and Properties of a Double-Coated Slow-Release and Water-Retention Urea Fertilizer.” J. Agricultural Food Chem., 54 (4) 1392–1398 (2006) https://doi.org/10.1021/jf052582f

  94. Ni, B, Liu, M, Lu, S, Xie, L, Wang, Y, “Environmentally Friendly Slow-Release Nitrogen Fertilizer.” J. Agricultural Food Chem., 59 (18) 10169–10175 (2011) https://doi.org/10.1021/jf202131z

  95. Yang, Y, Tong, Z, Geng, Y, Li, Y, Zhang, M, “Biobased Polymer Composites Derived from Corn Stover and Feather Meals as Double-Coating Materials for Controlled-Release and Water-Retention Urea Fertilizers.” J. Agricultural Food Chem., 61 (34) 8166–8174 (2013) https://doi.org/10.1021/jf402519t

  96. Wang, Y, Liu, M, Ni, B, Xie, L, “κ-Carrageenan–Sodium Alginate Beads and Superabsorbent Coated Nitrogen Fertilizer with Slow-release, Water-Retention, and Anticompaction Properties.” Ind. Eng. Chem. Res., 51 (3) 1413-–422 (2012) https://doi.org/10.1021/ie2020526

  97. Anggoro, DD, “Producing Slow Release Urea by Coating with Starch/Acrylic Acid in Fluid Bed Spraying.” Int. J. Eng. Technol., 11 (06) 62–66 (2011) http://www.ijens.org/Vol_11_I_06/112506-7474-IJET-IJENS.pdf

  98. Ito, R, Golman, B, Shinohara, K, “Design of Multi-layer Coated Particles with Sigmoidal Release Pattern.” Chem. Eng. Sci., 60 (20) 5415–5424 (2005) https://doi.org/10.1016/j.ces.2005.04.023

  99. Mulder, W, Gosselink, R, Vingerhoeds, M, Harmsen, P, Eastham, D, “Lignin Based Controll. Release Coatings” Ind. Crops and Products, 34 (1) 915–920 (2011) https://doi.org/10.1016/j.indcrop.2011.02.011

  100. Moradi, S, Shayesteh, K, Behbudi, G, “Preparation and Characterization of Biodegradable Lignin-Sulfonate Nanoparticles Using the Microemulsion Method to Enhance the Acetylation Efficiency of Lignin-Sulfonate.” Int. J. Biol. Macromol., (2020) https://doi.org/10.1016/j.ijbiomac.2020.05.157

  101. Sadeghi, N, Shayesteh, K, Lotfiman, S, “Effect of Modified Lignin Sulfonate on Controlled-Release Urea in Soil.” J. Polym. Environ., 25 (3) 792–799 (2017) https://doi.org/10.1007/s10924-016-0848-6

  102. Garcia, C, Vallejo, A, Diéz, JA, García, L, Cartagena, MC, “Nitrogen Use Efficiency with the Application of Controlled Release Fertilizers Coated with Kraft Pine Lignin.” Soil Sci. Plant Nutrition, 43 (2) 443–449 (1997) https://doi.org/10.1080/00380768.1997.10414768

  103. Flores-Céspedes, F, Daza-Fernández, I, Villafranca-Sánchez, M, Fernández-Pérez, M, Morillo, E, Undabeytia, T, “Lignin and Ethylcellulose in Controlled Release Formulations to Reduce Leaching of Chloridazon and Metribuzin in Light-Textured Soils.” J. Hazardous Mater., 343 227–234 (2018) https://doi.org/10.1016/j.jhazmat.2017.09.012

  104. Jamnongkan, T, Kaewpirom, S, “Controlled-Release Fertilizer Based on Chitosan Hydrogel: Phosphorus Release Kinetics.” Sci. J. UBU, 1 (1) 43–50 (2010) https://www.researchgate.net/publication/45258204

  105. Kusumastuti, Y, Istiani, A, Purnomo, CW, “Chitosan-based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer.” Adv. Mater. Sci. Eng., 2019 (2019) https://doi.org/10.1155/2019/2958021

  106. Perez, JJ, Francois, NJ, “Chitosan-Starch Beads Prepared by Ionotropic Gelation as Potential Matrices for Controlled Release of Fertilizers.” Carbohydr. Polym., 148 134–142 (2016) https://doi.org/10.1016/j.carbpol.2016.04.054

  107. Chen, C, Gao, Z, Qiu, X, Hu, S, “Enhancement of the Controlled-Release Properties of Chitosan Membranes by Crosslinking with Suberoyl Chloride.” Molecules, 18 (6) 7239–7252 (2013) https://doi.org/10.3390/molecules18067239

  108. Zohourian, MM, Kabiri, K, “Superabsorbent Polymer Materials: A Review.” Iranian Polym. J., 17 (6) 447–451 (2008) https://www.researchgate.net/publication/242582443

  109. Zheng, Y, Wang, A, “Superadsorbent with Three-Dimensional Networks: From Bulk Hydrogel to Granular Hydrogel.” Eur. Polym. J., 72 661–686 (2015) https://doi.org/10.1016/j.eurpolymj.2015.02.031

  110. Muharam, S, Fitri, A, Yuningsih, LM, Putri, YMTA, Rahmawati, I, “Synthesis and Characterization of Controlled-Release Urea Fertilizer from Superabsorbent Hydrogels.” Indonesian J. Chem., 20 (3) 616–625 (2020) https://doi.org/10.22146/ijc.44230

  111. Mignon, A, De Belie, N, Dubruel, P, Van Vlierberghe, S, “Superabsorbent Polymers: A Review on the Characteristics and Applications of Synthetic, Polysaccharide-Based, Semi-Synthetic and ‘Smart’ Derivatives.” Eur. Polym. J., 117 165–178 (2019) https://doi.org/10.1016/j.eurpolymj.2019.04.054

  112. Rashidzadeh, A, Olad, A, Salari, D, Reyhanitabar, A, “On the Preparation and Swelling Properties of Hydrogel Nanocomposite Based on Sodium Alginate-g-poly (Acrylic Acid-co-Acrylamide)/clinoptilolite and Its Application as Slow Release Fertilizer.” J. Polym. Res., 21 (2) 344 (2014) https://doi.org/10.1007/s10965-013-0344-9

  113. Xiao, X, Yu, L, Xie, F, Bao, X, Liu, H, Ji, Z, Chen, L, “One-Step Method to Prepare Starch-Based Superabsorbent Polymer for Slow Release of Fertilizer.” Chem. Eng. J., 309 607–616 (2017) https://doi.org/10.1016/j.cej.2016.10.101

  114. Qiao, D, Liu, H, Yu, L, Bao, X, Simon, GP, Petinakis, E, Chen, L, “Preparation and Characterization of Slow-Release Fertilizer Encapsulated by Starch-based Superabsorbent Polymer.” Carbohydr. Polym., 147 146–154 (2016) https://doi.org/10.1016/j.carbpol.2016.04.010

  115. Ramakrishna, S, Huang, Z-M, “Biocomposites.” Comprehensive Structural Integrity. Reference Module in Materials Science and Materials Engineering (2003) https://doi.org/10.1016/B978-0-12-803581-8.00965-6

  116. Ramakrishna, S, Huang, Z-M, V Kumar, G, Batchelor, AW, Mayer, J, An Introduction to Biocomposites. Imperial College Press (2004) https://doi.org/10.1142/p311

  117. Jyothi, AN, Pillai, SS, Aravind, M, Salim, SA, Kuzhivilayil, SJ, “Cassava Starch‐Graft‐Poly (Acrylonitrile)‐Coated Urea Fertilizer with Sustained Release and Water Retention Properties.” Adv. Polym. Technol., 37 (7) 2687–2694 (2018) https://doi.org/10.1002/adv.21943

  118. Adam, GA, “Lignin-Based Multipurpose Fertilizers.” (2015) https://patents.google.com/patent/US9039803B2/en

  119. Dallmeyer, I, Chowdhury, S, Kadla, JF, “Preparation and Characterization of Kraft Lignin-Based Moisture-Responsive Films with Reversible Shape-Change Capability.” Biomacromolecules, 14 (7) 2354–2363 (2013) https://doi.org/10.1007/978-3-030-14618-4_12

  120. Behin, J, Sadeghi, N, “Utilization of Waste Lignin to Prepare Controlled-Slow Release Urea.” Int. J. Recycl. Organic Waste in Agriculture, 5 (4) 289–299 (2016) https://doi.org/10.1007/s40093-016-0139-1

  121. Savitri, E, Purwanto, E, Kodrat, A, Yonathan, E, “Controlled Release Fertilizer Based on Starch Chitosan Encapsulation.” Proc. IOP Conf. Series: Mater. Sci. Eng., 703 012019 (2019) https://doi.org/10.1088/1757-899X/703/1/012019

  122. Wang, J, Liu, S, Qin, Y, Chen, X, Yu, H, Li, K, Li, P, “Preparation and Characterization of Controlled-Release Fertilizers Coated with Marine Polysaccharide Derivatives.” Chinese J. Oceanol. Limnol., 35 (5) 1086–1093 (2017) https://doi.org/10.1007/s00343-017-6074-9

  123. Siafu, SI, “Silicone Doped Chitosan-Acrylamide Coencapsulated Urea Fertilizer: An Approach to Controlled Release Fertilizers.” J. Nanotechnol., 2017 1–7 (2017) https://doi.org/10.1155/2017/8490730

  124. Zhong, K, Lin, Z-T, Zheng, X-L, Jiang, G-B, Fang, Y-S, Mao, X-Y, Liao, Z-W, “Starch Derivative-Based Superabsorbent with Integration of Water-Retaining and Controlled-Release Fertilizers.” Carbohydr. Polym., 92 (2) 1367–1376 (2013) https://doi.org/10.1016/j.carbpol.2012.10.030

  125. Zhang, S, Yang, Y, Gao, B, Li, YC, Liu, Z, “Superhydrophobic Controlled-Release Fertilizers Coated with Bio-Based Polymers with Organosilicon and Nano-Silica Modifications.” J. Mater. Chem. A, 5 (37) 19943–19953 (2017) https://doi.org/10.1039/C7TA06014A

  126. Nongbet, A, Mishra, AK, Mohanta, YK, Mahanta, S, Ray, MK, Khan, M, Baek, K-H, Chakrabartty, I, “Nanofertilizers: A Smart and Sustainable Attribute to Modern Agriculture.” Plants, 11 (19) 2587 (2022) https://doi.org/10.3390/plants11192587

  127. Pereira, EI, Minussi, FB, da Cruz, CC, Bernardi, AC, Ribeiro, C, “Urea–Montmorillonite-Extruded Nanocomposites: A Novel Slow-Release Material.” J. Agric. Food Chem., 60 (21) 5267–5272 (2012) https://doi.org/10.1021/jf3001229

  128. Mikhak, A, Sohrabi, A, Kassaee, MZ, Feizian, M, “Synthetic Nanozeolite/nanohydroxyapatite as a Phosphorus Fertilizer for German Chamomile (Matricariachamomilla L.).” Ind. Crops Prod., 95 444–452 (2017) https://doi.org/10.1016/j.indcrop.2016.10.054

  129. Lateef, A, Nazir, R, Jamil, N, Alam, S, Shah, R, Khan, MN, Saleem, M, “Synthesis and Characterization of Zeolite Based Nano–Composite: An Environment Friendly Slow Release Fertilizer.” Microporous and Mesoporous Mater., 232 174–183 (2016) https://doi.org/10.1016/j.micromeso.2016.06.020

  130. Perrin, TS, Drost, DT, Boettinger, JL, Norton, JM, “Ammonium‐Loaded Clinoptilolite: A Slow‐Release Nitrogen Fertilizer for Sweet Corn.” J. Plant Nutr., 21 (3) 515–530 (1998) https://doi.org/10.1080/01904169809365421

  131. Roshanravan, B, Mahmoud Soltani, S, Mahdavi, F, Abdul Rashid, S, Khanif Yusop, M, “Preparation of Encapsulated Urea-Kaolinite Controlled Release Fertiliser and their Effect on Rice Productivity.” Chem. Speciat. Bioavailab., 26 (4) 249–256 (2014) https://doi.org/10.3184/095422914X14146901352512

  132. Roshanravan, B, Soltani, SM, Rashid, SA, Mahdavi, F, Yusop, MK, “Enhancement of Nitrogen Release Properties of Urea–Kaolinite Fertilizer with Chitosan Binder.” Chem. Speciat. Bioavailab., 27 (1) 44–51 (2015) https://doi.org/10.1080/09542299.2015.1023090

  133. Songkhum, P, Wuttikhun, T, Chanlek, N, Khemthong, P, Laohhasurayotin, K, “Controlled Release Studies of Boron and Zinc from Layered Double Hydroxides as the Micronutrient Hosts for Agricultural Application.” Appl. Clay Sci., 152 311–322 (2018) https://doi.org/10.1016/j.clay.2017.11.028

  134. Bortoletto-Santos, R, Plotegher, F, Majaron, VF, da Silva, MG, Polito, WL, Ribeiro, C, “Polyurethane Nanocomposites Can Increase the Release Control in Granulated Fertilizers by Controlling Nutrient Diffusion.” Appl. Clay Sci., 199 105874 (2020) https://doi.org/10.1016/j.clay.2020.105874

  135. Kottegoda, N, Sandaruwan, C, Priyadarshana, G, Siriwardhana, A, Rathnayake, UA, Berugoda Arachchige, DM, Kumarasinghe, AR, Dahanayake, D, Karunaratne, V, Amaratunga, GA, “Urea-Hydroxyapatite Nanohybrids for Slow Release of Nitrogen.” ACS Nano, 11 (2) 1214–1221 (2017) https://doi.org/10.1021/acsnano.6b07781

  136. Kottegoda, N, Munaweera, I, Madusanka, N, Karunaratne, V, “A Green Slow-release Fertilizer Composition Based on Urea-Modified Hydroxyapatite Nanoparticles Encapsulated Wood.” Current Sci., 73–78 (2011) https://www.researchgate.net/publication/269709591

  137. Wanyika, H, Gatebe, E, Kioni, P, Tang, Z, Gao, Y, “Mesoporous Silica Nanoparticles Carrier for Urea: Potential Applications in Agrochemical Delivery Systems.” J. Nanosci. Nanotechnol., 12 (3) 2221–2228 (2012) https://doi.org/10.1166/jnn.2012.5801

  138. Hossain, K-Z, Monreal, CM, Sayari, A, “Adsorption of Urease on PE-MCM-41 and its Catalytic Effect on Hydrolysis of Urea.” Coll. Surfaces B: Biointerfaces, 62 (1) 42–50 (2008) https://doi.org/10.1016/j.colsurfb.2007.09.016

  139. Patel, KD, Singh, RK, Kim, H-W, “Carbon-Based Nanomaterials as an Emerging Platform for Theranostics.” Mater. Horizons, 6 (3) 434–469 (2019) https://doi.org/10.1039/C8MH00966J

  140. Ashfaq, M, Verma, N, Khan, S, “Carbon Nanofibers as a Micronutrient Carrier in Plants: Efficient Translocation and Controlled Release of Cu Nanoparticles.” Environ. Sci.: Nano, 4 (1) 138–148 (2017) https://doi.org/10.1039/C6EN00385K

  141. Kumar, R, Ashfaq, M, Verma, N, “Synthesis of Novel PVA–starch Formulation-Supported Cu–Zn Nanoparticle Carrying Carbon Nanofibers as a Nanofertilizer: Controlled Release of Micronutrients.” J. Mater. Sci., 53 (10) 7150–7164 (2018) https://doi.org/10.1007/s10853-018-2107-9

  142. Tan, X-m, Lin, C, Fugetsu, B, “Studies on Toxicity of Multi-Walled Carbon Nanotubes on Suspension Rice Cells.” Carbon, 47 (15) 3479–3487 (2009) https://doi.org/10.1016/j.carbon.2009.08.018

  143. Lin, C, Fugetsu, B, Su, Y, Watari, F, “Studies on Toxicity of Multi-Walled Carbon Nanotubes on Arabidopsis T87 Suspension Cells.” J. Hazardous Mater., 170 (2-3) 578–583 (2009) https://doi.org/10.1016/j.jhazmat.2009.05.025

  144. Kashyap, PL, Xiang, X, Heiden, P, “Chitosan Nanoparticle Based Delivery Systems for Sustainable Agriculture.” Int. J. Biol. Macromole., 77 36–51 (2015) https://doi.org/10.1016/j.ijbiomac.2015.02.039

  145. Corradini, E, De Moura, M, Mattoso, L, “A Preliminary Study of the Incorparation of NPK Fertilizer into Chitosan Nanoparticles.” Exp. Polym. Lett., 4 (8) (2010) https://doi.org/10.3144/expresspolymlett.2010.64

  146. Aziz, HMA, Hasaneen, MN, Omer, AM, “Nano Chitosan-NPK Fertilizer Enhances the Growth and Productivity of Wheat Plants Grown in Sandy Soil.” Spanish J. Agricultural Res., 14 (1) 17 (2016) https://doi.org/10.5424/sjar/2016141-8205

  147. Hasaneen, M, Abdel-Aziz, H, El-Bialy, D, Omer, AM, “Preparation of Chitosan Nanoparticles for Loading with NPK Fertilizer.” African J. Biotechnol., 13 (31) (2014) https://doi.org/10.5897/AJB2014.13699

  148. Mohanty, SR, Coumar, V, Saha, JK, Patra, AK, “Reduction in Nitrous Oxide (N2O) Emission from Nano Zinc Oxide and Nano Rockphosphate Coated Urea.” Agrochimica, 60 (2) 59–70 https://doi.org/10.12871/0021857201611

  149. Yuvaraj, M, Subramanian, K, “Controlled-Release Fertilizer of Zinc Encapsulated by a Manganese Hollow Core Shell.” Soil Sci. Plant Nutrition, 61 (2) 319–326 (2015) https://doi.org/10.1080/00380768.2014.979327

  150. Jyothi, NVN, Prasanna, PM, Sakarkar, SN, Prabha, KS, Ramaiah, PS, Srawan, G, “Microencapsulation Techniques, Factors Influencing Encapsulation Efficiency.” J. Microencapsulation, 27 (3) 187–197 (2010) https://doi.org/10.3109/02652040903131301

  151. Fu, F, Hu, L, “Temperature Sensitive Colour-Changed Composites.” In: Advanced High Strength Natural Fibre Composites in Construction, pp. 405–423. Elsevier (2017) https://doi.org/10.1016/B978-0-08-100411-1.00015-7

  152. Jacquot, M, Pernetti, M, “Spray Coating and Drying Processes.” In: Nedović, V, Willaert, R (eds.) Fundamentals of Cell Immobilisation Biotechnology, pp. 343–356. Springer, Dordrecht (2004) https://doi.org/10.1007/978-94-017-1638-3_19

  153. Chavda, VP, Soniwala, MM, Chavda, JR, “Particle Coating: From Conventional to Advanced.” Int. J. Pharma. Med. Res., 1 1–17 (2013) http://www.ijpmr.org/pdf/Particle-coating-From-conventional-to-advanced.pdf

  154. Iley, W, “Effect of Particle Size and Porosity on Particle film Coatings.” Powder Technol., 65 (1–3) 441–445 (1991) https://doi.org/10.1016/0032-5910(91)80205-W

  155. Hariri, MH, Arastoopour, H, Rehmat, A, “Agglomeration of Polyolefin Particles in a Fluidized Bed with a Central Jet Part I. Experimental Study.” Powder Technol., 74 (3) 231–238 (1993) https://doi.org/10.1016/0032-5910(93)85031-4

  156. Xu, S, Li, X, Wang, Y, Hu, Z, Wang, R, “Characterization of Slow‐release Collagen‐g‐poly (Acrylic Acid‐co‐2‐acrylamido‐2‐methyl‐1‐propane Sulfonic Acid)–iron (III) Superabsorbent Polymer Containing Fertilizer.” J. Appl. Polym. Sci., 136 (11) 47178 (2019) https://doi.org/10.1002/app.47178

  157. Babadi, FE, Yunus, R, Rashid, SA, Salleh, MAM, Ali, S, “New Coating Formulation for the Slow Release of Urea Using a Mixture of Gypsum and Dolomitic Limestone.” Particuology, 23 62–67 (2015) https://doi.org/10.1016/j.partic.2014.12.011

  158. Tsai, BS, “Continuous Spouted bed Process for Sulphur-Coating Urea.” Chem. Eng. Univ. British Columbia, (1986) https://open.library.ubc.ca/media/download/pdf/831/1.0058910/1

  159. Choi, MM, Meisen, A, “Sulfur Coating of Urea in Shallow Spouted Beds.” Chem. Eng. Sci., 52 (7) 1073–1086 (1997) https://doi.org/10.1016/S0009-2509(96)00377-6

  160. Ayub, G, Rocha, S, Perrucci, A, “Analysis of the Surface Quality of Sulphur-Coated Urea Particles in a Two-Dimensional Spouted Bed.” Brazilian J. Chem. Eng., 18 (1) 13–22 (2001) https://doi.org/10.1590/S0104-66322001000100002

  161. Detrick, JH, Hargrove, GL, “Polymer-Sulfur-Polymer Coated Fertilizers.” https://patents.google.com/patent/US6338746B1/en (2019)

  162. Liang, R, Liu, M, Wu, L, “Controlled Release NPK Compound Fertilizer with the Function of Water Retention.” React. Func. Polym., 67 (9) 769–779 (2007) https://doi.org/10.1016/j.reactfunctpolym.2006.12.007

  163. Liu, L, Kost, J, Fishman, ML, Hicks, KB, “A Review: Controlled Release Systems for Agricultural and Food Applications.” In: Parris, N, Liu, L, Song, C, Shastri, V (eds.) New Delivery Systems for Controlled Drug Release From Naturally Occurring Materials, pp. 265–281. ACS Symposium series (2008) https://doi.org/10.1021/bk-2008-0992.ch014

  164. Donida, MW, Rocha, SC, “Coating of Urea with an Aqueous Polymeric Suspension in a Two-Dimensional Spouted Bed.” Drying Technol., 20 (3) 685–704 (2002) https://doi.org/10.1081/DRT-120002824

  165. Ni, B, Liu, M, Lü, S, “Multifunctional Slow-Release Urea Fertilizer From Ethylcellulose and Superabsorbent Coated Formulations.” Chem. Eng. J., 155 (3) 892–898 (2009) https://doi.org/10.1016/j.cej.2009.08.025

  166. Hanafi, M, Eltaib, S, Ahmad, M, “Physical and Chemical Characteristics of Controlled Release Compound Fertiliser.” Eur. Polym. J., 36 (10) 2081–2088 (2000) https://doi.org/10.1016/S0014-3057(00)00004-5

  167. Hudson, AP, “Controlled Release Fertilizers Utilizing an Epoxy Polymer Primer Coat and Methods of Production.” Google Patents (1997) https://patents.google.com/patent/US5698002A/en

  168. Tomaszewska, M, Jarosiewicz, A, “Encapsulation of Mineral Fertilizer by Polysulfone Using a Spraying Method.” Desalination, 198 (1–3) 346–352 (2006) https://doi.org/10.1016/j.desal.2006.01.032

  169. Rosenthal, E, Padgett Jr, LE, “Polyurethane Encapsulated Fertilizer.” Google Patents (2007) https://patents.google.com/patent/US7267707B2/en

  170. Hon, DN-S, “Encapsulated Fertilizers and Pesticides and Process.” Google Patents (1997) https://patents.google.com/patent/US5679129A/en

  171. Ozores-Hampton, M, Carson, LC, “Methods for Measuring Nitrogen Release from Controlled-Release Fertilizer Used for Vegetable Production.” Hort. Tech. 22 (1) 20–24 (2013) https://doi.org/10.21273/HORTTECH.22.1.20

  172. Trinh, TH, KuShaari, K, Basit, A, “Modeling the Release of Nitrogen from Controlled-Release Fertilizer with Imperfect Coating in Soils and Water.” Ind. Eng. Chem. Res., 54 (26) 6724–6733 (2015) https://doi.org/10.1021/acs.iecr.5b01281

  173. Kochba, M, Gambash, S, Avnimelech, Y, “Studies on Slow Release Fertilizers: 1. Effects of Temperature, Soil Moisture, and Water Vapor Pressure.” Soil Sci., 149 (6) 339–343 (1990) https://doi.org/10.1097/00010694-199006000-00004

  174. Fujinuma, R, Balster, NJ, Norman, JM, “An Improved Model of Nitrogen Release for Surface‐Applied Controlled‐Release Fertilizer.” Soil Sci. Soc. Am. J., 73 (6) 2043–2050 (2009) https://doi.org/10.2136/sssaj2009.0085

  175. Haifa-Group, “Products, Controlled Release Fertilizers (CRF).” (2020) https://www.haifa-group.com/controlled-release-fertilizers-crf

  176. Kingenta, “Product Center, Controlled Release Fertilizer.” (2020) http://en.kingenta.com/Goods/show/cid/28.html

  177. Fortune Business Insights, Fertilizers Market Research Report, “Controlled Release Fertilizers (CRF) Market Size, Share & Industry Analysis, By Type (Slow-release, Coated & Encapsulated, and Nitrogen Stabilizers), Application (Cereals, Oilseeds & Pulses, Fruits & Vegetables, & Others), and Regional Forecasts, 2019–2026.” (2020) https://www.fortunebusinessinsights.com/controlled-release-fertilizers-crf-market-101973

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  1. Department of Chemical Engineering, University of Mohaghegh Ardabili, P.O. Box 179, Ardabil, Iran

    Samira Moradi, Aziz Babapoor, Samaneh Ghanbarlou & Masoomeh Yari Kalashgarani

  2. Department of Polymer Processing, Iran Polymer and Petrochemical Institute, Tehran, Iran

    Iman Salahshoori

  3. Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Iman Salahshoori

  4. School of Mechanical Engineering, University of Adelaide, Adelaide, Australia

    Ahmad Seyfaee

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Moradi, S., Babapoor, A., Ghanbarlou, S. et al. Toward a new generation of fertilizers with the approach of controlled-release fertilizers: a review. J Coat Technol Res 21, 31–54 (2024). https://doi.org/10.1007/s11998-023-00817-z

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  • DOI: https://doi.org/10.1007/s11998-023-00817-z

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