Abstract
Non-covalent modification of graphene is prepared by sodium carboxymethyl cellulose via ball milling. Adsorption and thermogravimetric analyzer (TG) indicate interaction of graphene with sodium carboxymethyl cellulose. Particle size and zeta potential results show sodium carboxymethyl cellulose with high DS play more role in assisting stabilization of graphene dispersion. The adsorption of sodium carboxymethyl cellulose onto graphene is inhibited under acidic conditions and the dispersion stability deteriorates sharply. Under neutral and alkaline conditions, the dispersions maintain stable. Embedding a small percentage of well-dispersed graphene nanosheets (CGr1.5%) in waterborne epoxy coating has remarkably improved anticorrosion performance, which is attributed to the synergistic effects of barrier properties of well-dispersed graphene nanosheets and CMC in the epoxy matrix. Open circuit potential (OCP), Tafel and electrochemical impedance spectroscopy (EIS) analysis confirmed that the corrosion rate exhibited by composite coatings with 1.5 wt% graphene is lower than that of neat epoxy coating.
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References
Zhong, F, He, Y, Wang, P, Chena, C, Lin, Y, Wu, Y, Chen, J, “Self-Assembled Graphene Oxide-Graphene Hybrids for Enhancing the Corrosion Resistance of Waterborne Epoxy Coating.” Appl. Surf. Sci., 488 801–812 (2019)
Parviz, D, Das, S, Tanvir Ahmed, HS, Irin, F, Bhattacharia, S, Green, MJ, “Dispersions of Non-Covalently Functionalized Graphene with Minimal Stabilizer.” ACS Nano, 6 (10) 8857–8867 (2012)
Sarsam, WS, Amiri, A, Kazi, SN, Badarudin, A, “Stability and Thermophysical Properties of Non-Covalently Functionalized Graphene Nanoplatelets Nanofluids.” Energy Convers. Manag., 116 101–111 (2016)
Cui, M, Ren, S, Chen, J, Liu, S, Zhang, G, Zhao, H, Wang, L, Xue, Q, “Anticorrosive Performance of Waterborne Epoxy Coatings Containing Water-Dispersible Hexagonal Boron Nitride (h-BN) Nanosheets.” Appl. Surf. Sci., 397 77–86 (2017)
Zhang, M, Zhao, X, Jia, H, Xing, H, Zhang, H, Wang, X, Liu, C, “Anticorrosion Properties of Modified Basalt Powder/Epoxy Resin Coating.” J. Coat. Technol. Res., 19 (5) 1409–1420 (2022)
Ahangari, M, Johar, MH, Saremi, M, “Hydroxyapatite-Carboxymethyl Cellulose-Graphene Composite Coating Development on AZ31 Magnesium Alloy: Corrosion Behavior and Mechanical Properties.” Ceram. Int., 47 3529–3539 (2021)
Li, C, Zhang, C, He, Y, Li, H, Zhao, Y, Li, Z, Sun, D, Yin, X, “Benzotriazole Corrosion Inhibitor Loaded Nanocontainer Based on g-C3N4 and Hollow Polyaniline Spheres Towards Enhancing Anticorrosion Performance of Waterborne Epoxy Coatings.” Prog. Org. Coat., 174 107276 (2023)
Zhang, J, Zhao, J, Wang, J, Tabish, M, Zhang, J, “Enhancing the Corrosion Resistance of Waterborne Epoxy Coating by Fumarate Intercalated LDHs Prepared by High Gravity Technology.” Prog. Org. Coat., 174 107271 (2023)
Jagtap, A, Wagle, PG, Jagtiani, E, More, AP, “Layered Double Hydroxides (LDHs) for Coating Applications.” J. Coat. Technol. Res., 19 (4) 1009–1032 (2022)
Liu, S, Gu, L, Zhao, H, Chen, J, Yu, H, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 425–431 (2016)
Chilkoor, G, Sarder, R, Islam, J, ArunKumar, KE, Ratnayake, I, Star, S, Jasthi, BK, Sereda, G, Koratkar, N, Meyyappan, M, Gadhamshetty, V, “Maleic Anhydride-Functionalized Graphene Nanofillers Render Epoxy Coatings Highly Resistant to Corrosion And Microbial Attack.” Carbon, 159 586–597 (2020)
Loh, KP, Bao, Q, Ang, PK, Yang, J, “The Chemistry of Graphene.” J. Mater. Chem., 20 2277–2289 (2010)
Johnson, DW, Dobson, BP, Coleman, KS, “A Manufacturing Perspective on Graphene Dispersions.” Curr. Opin. Colloid Interface Sci., 20 367–382 (2015)
Georgakilas, V, Otyepka, M, Bourlinos, AB, Chandra, V, Kim, N, Kemp, KC, Hobza, P, Zboril, R, Kim, KS, “Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications.” Chem. Rev., 112 6156–6214 (2012)
Qiu, S, Liu, G, Li, W, Zhao, H, Wang, L, “Noncovalent Exfoliation of Graphene and Its Multifunctional Composite Coating with Enhanced Anticorrosion and Tribological Performance.” J. Alloy. Compd., 747 60–70 (2018)
Gu, L, Liu, S, Zhao, HC, Yu, HB, “Facile Preparation of Water-Dispersible Graphene Sheets Stabilized by Carboxylated Oligoanilines and Their Anticorrosion Coatings.” ACS Appl. Mater. Interfaces, 7 17641–17648 (2015)
Verma, C, Olasunkanmi, LO, Akpan, ED, Quraishi, MA, Dagdag, O, El Gouri, M, Sherif, ESM, Ebenso, EE, “Epoxy Resins as Anticorrosive Polymeric Materials: A Review.” React. Functi. Polym., 156 104741 (2020)
Lee, JH, Kang, SG, Lee, SG, “Mechanism of Adhesion of the Diglycidyl Ether of Bisphenol A (DGEBA) to the Fe(100) Surface.” Compos. Sci. Technol., 126 9–16 (2016)
Yang, Q, Pan, XJ, Huang, F, et al. “Fabrication of High-Concentration and Stable Aqueous Suspensions of Graphene Nanosheets by Noncovalent Functionalization with Lignin and Cellulose Derivatives.” J. Phys. Chem. C, 114 (9) 3811–3816 (2010)
Chen, Y, Li, J, Yang, W, Gao, S, Cao, R, “Enhanced Corrosion Protective Performance of Graphene Oxide-based Composite Films on AZ31 Magnesium Alloys in 3.5 wt% NaCl Solution.” Appl. Surf. Sci., 493 1224–1235 (2019)
Mousavi, SM, Afra, E, Tajvidi, M, Bousfield, D, Dehghani-Firouzabadi, M, “Cellulose Nanofiber/Carboxymethyl Cellulose Blends as an Efficient Coating to Improve the Structure and Barrier Properties of Paperboard.” Cellulose, 24 3001–3014 (2017)
Rao, Z, Ge, H, Liu, L, Zhu, C, Min, L, Liu, M, Fan, L, Li, D, “Carboxymethyl Cellulose Modified Graphene Oxide as pH-Sensitive Drug Delivery System.” Int. J. Biol. Macromol., 107 1184–1192 (2018)
Li, M, Lu, X, Jiang, J, Gao, L, Gao, J, Jiang, D, “Green Modification of Graphene Dispersion with High Nanosheet Content, Good Dispersibility, and Long Storage Stability.” RSC Adv., 12 6037 (2022)
Xu, H, Hu, H, Wang, H, Li, Y, Li, Y, “Corrosion Resistance of Graphene/Waterborne Epoxy Composite Coatings in CO2-Saturated NaCl Solution.” R. Soc. Open Sci., 7 191943 (2020)
Rahman, MS, Hasan, MS, Nitai, AS, Nam, S, Karmakar, AK, Ahsan, MS, Shiddiky, MJA, Ahmed, MB, “Recent Developments of Carboxymethyl Cellulose.” Polymers, 13 (8) 1345 (2021)
Mazinani S, Ajji A, Dubois C, "Rheological/Morphological Study of PS/CNT Nanocomposite Electrospun Fibers." The XV International Congress on Rheology: The Society of Rheology 80th Annual Meeting, 2008
Basu, S, Gupta, PCD, “Studies on Polyelectrolytes. I. Sodium Carboxymethylcellulose.” J. Colloid Sci., 7 53–70 (1952)
Nazaria, B, Ranjbara, Z, Hashjina, RR, Moghaddama, AR, Momenc, G, Ranjbar, B, “Dispersing Graphene in Aqueous Media: Investigating the Effect of Different Surfactants.” Colloids Surf., 582 123870 (2019)
Fadla, AM, Abdoua, MI, Al-Elaab, SA, Hamzac, MA, Sadeek, SA, “Evaluation the Anti-Corrosion Behavior, Impact Resistance, Acids and Alkali Immovability of Nonylphenol Ethoxylate/TiO2 Hybrid Epoxy Nanocomposite Coating Applied on the Carbon Steel Surface.” Prog. Org. Coat., 136 105263 (2019)
Wetzel, B, Haupert, F, Qiu Zhang, M, “Epoxy Nanocomposites with High Mechanical and Tribological Performance.” Compos. Sci. Technol., 63 2055–2067 (2003)
Ponnuchamy, V, Esakkimuthu, ES, “Density Functional Theory Study of Lignin, Carboxymethylcellulose and Unsustainable Binders with Graphene for Electrodes in Lithium-Ion Batteries.” Appl. Surf. Sci., 573 151461 (2022)
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Wang, R., Yi, H. Mechanical-induced functionalization of graphene with sodium carboxymethyl cellulose toward enhancing anticorrosion performance of waterborne epoxy coatings. J Coat Technol Res 20, 2069–2080 (2023). https://doi.org/10.1007/s11998-023-00802-6
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DOI: https://doi.org/10.1007/s11998-023-00802-6