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Anticorrosion properties of modified basalt powder/epoxy resin coating

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Abstract

The epoxy resin coating has been widely used; however, its anticorrosion performance still needs to be improved. Basalt materials have been used as fillers in the field of anticorrosive coatings due to their good corrosion resistance and acid and alkali resistance. In this paper, 3-aminopropyltrimethoxysilane (APTMS) was used as a coupling agent to modify the surface of basalt powder. The modified basalt powder (MBP) was characterized by scanning electron microscope (SEM) and Fourier transform infrared-attenuated total reflectance (FTIR-ATR). The MBP was added to epoxy resin in different proportions as fillers, and the coatings with different MBP contents were prepared by applying the mixture on the metal substrates. The hardness of coatings can be enhanced up to 0.25 GPa with the increase in MBP, and the elastic of coatings increases to the highest of 4.97 GPa for MBP-10/EP. Their water absorption rates after soaking in water for 21 h decreased to 0.75%. Meanwhile, the anticorrosion performance of the coatings on substrates during exposure to 3.5 wt% NaCl solution was investigated by using electrochemical impedance spectroscopy (EIS), and the circuit-fitting of EIS tests was also performed. The corrosion resistance of EP coating has been obviously improved by adding MBP, with the low-frequency impedance value (|Z|0.01Hz) of MBP-10/EP up to 2.43 × 108 Ω·cm2 after being immersed in 3.5 wt% NaCl solution for 15 d, which was 7.8 times higher than that of neat epoxy coating (MBP-0/EP).

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Acknowledgment

We acknowledge financial support by the Fundamental Research Funds for the Central Universities (DUT20LAB305).

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Authors and Affiliations

  1. Department of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, China

    Manxia Zhang, Xinyi Zhao, Haoran Xing, Hongjing Zhang & Xinyue Wang

  2. Department of Polymer Science and Materials, Dalian University of Technology, Dalian, 116024, China

    Hang Jia & Cheng Liu

Authors
  1. Manxia Zhang
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  2. Xinyi Zhao
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  3. Hang Jia
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  4. Haoran Xing
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  5. Hongjing Zhang
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  7. Cheng Liu
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Contributions

Manxia Zhang contributed to supervision and investigation. Xinyi Zhao contributed to writing—original draft and data processing. Hang Jia contributed to testing and data processing. Haoran Xing contributed to review and revision. Hongjing Zhang contributed to review and editing. Xinyue Wang contributed to revised writing. Cheng Liu contributed to supervision and funding acquisition. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Manxia Zhang or Cheng Liu.

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Zhang, M., Zhao, X., Jia, H. et al. Anticorrosion properties of modified basalt powder/epoxy resin coating. J Coat Technol Res 19, 1409–1420 (2022). https://doi.org/10.1007/s11998-022-00615-z

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  • DOI: https://doi.org/10.1007/s11998-022-00615-z

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