Abstract
Hierarchically porous zeolites are promising candidates in catalytic conversion of relatively bulky molecules, and their syntheses have attracted significant attention. From both industrial and scientific perspectives, different carbon materials have been widely employed as hard templates for the preparation of hierarchically porous zeolites during the past two decades. In this review, the progress in synthetic strategies using carbon materials as templates is comprehensively summarized. Depending on the affinity between the carbon templates and zeolite precursors, the substantial strategies for synthesizing hierarchical zeolites are introduced in direct templates and indirect templates. Direct templates methods, by which the carbon materials are directly mixed with precursors gel as hard templates, are first reviewed. Then, we discuss the indirect templates method (crystallization of carbon-silica composites), by which the carbon is produced by in situ pyrolysis of organic-inorganic precursors. In addition, the technique of encapsulating metal species into zeolites crystals with the assistance of carbon templates is also discussed. In the conclusion part, the factors affecting the synthesis of carbon-templated hierarchically porous zeolites are remarked. This review is expected to attract interest in the synthesis strategies of hierarchically porous zeolites, especially cost-effective and large-scale production methodologies, which are essential to the industrial application of hierarchical zeolites.
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Chen L H, Sun M H, Wang Z, Yang W M, Xie Z K, Su B L. Hierarchically structured zeolites: from design to application. Chemical Reviews, 2020, 120(20): 11194–11294
de Jong K P, Zečević J, Friedrich H, de Jongh P E, Bulut M, van Donk S, Kenmogne R, Finiels A, Hulea V, Fajula F. Zeolite Y crystals with trimodal porosity as ideal hydrocracking catalysts. Angewandte Chemie International Edition, 2010, 49(52): 10074–10078
Fu T J, Qi R Y, Wan W L, Shao J, Wen J Z, Li Z. Fabrication of hollow mesoporous nanosized ZSM-5 catalyst with superior methanol-to-hydrocarbons performance by controllable desilication. ChemCatChem, 2017, 9(22): 4212–4224
Fang Y H, Yang F, He X, Zhu X D. Dealumination and desilication for Al-rich HZSM-5 zeolite via steam-alkaline treatment and its application in methanol aromatization. Frontiers of Chemical Science and Engineering, 2019, 13(3): 543–553
Yang S T, Yu C X, Yu L L, Miao S, Zou M M, Jin C Z, Zhang D Z, Xu L Y, Huang S J. Bridging dealumination and desilication for the synthesis of hierarchical MFI zeolites. Angewandte Chemie International Edition, 2017, 56(41): 12553–12556
Li Q, Dou T, Zhang Y, Li Y P, Wang S, Sun F M. Synthesis, characterization and catalytic properties of mesoporous MCM-48 containing zeolite secondary building units. Frontiers of Chemical Science and Engineering, 2007, 1(1): 1–5
Zhang W M, Ming W X, Hu S F, Qin B, Ma J H, Li R F. A feasible one-step synthesis of hierarchical zeolite Beta with uniform nanocrystals via CTAB. Materials (Basel), 2018, 11(5): 651–662
Du S T, Li F, Sun Q M, Wang N, Jia M J, Yu J H. A green surfactant-assisted synthesis of hierarchical TS-1 zeolites with excellent catalytic properties for oxidative desulfurization. Chemical Communications (Cambridge), 2016, 52(16): 3368–3371
Xu H, Lei C, Wu Q M, Zhu Q Y, Meng X J, Dai D, Maurer S, Parvulescu A N, Müller U, Xiao F S. Organosilane surfactant-assisted synthesis of mesoporous SSZ-39 zeolite with enhanced catalytic performance in the methanol-to-olefins reaction. Frontiers of Chemical Science and Engineering, 2020, 14(2): 267–274
Xu S M, Zhang X X, Cheng D G, Chen F Q, Ren X H. Effect of hierarchical ZSM-5 zeolite crystal size on diffusion and catalytic performance of n-heptane cracking. Frontiers of Chemical Science and Engineering, 2018, 12(4): 780–789
Sun Q M, Wang N, Xi D Y, Yang M, Yu J H. Organosilane surfactant-directed synthesis of hierarchical porous SAPO-34 catalysts with excellent MTO performance. Chemical Communications (Cambridge), 2014, 50(49): 6502–6505
Liu J Y, Wang J G, Li N, Zhao H, Zhou H J, Sun P C, Chen T H. Polyelectrolyte-surfactant complex as a template for the synthesis of zeolites with intracrystalline mesopores. Langmuir, 2012, 28(23): 8600–8607
Guo D X, Shi C X, Zhao H, Chen R, Chen S H, Sun P C, Chen T H. Polyacrylic acid as mesoscale template for synthesis of MFI zeolite with plentiful intracrystalline mesopores. Microporous and Meso-porous Materials, 2020, 293: 109821–109828
Shao Y C, Wang Y C, Liu X F, Li T D, Haydel P R, Tatsumi T, Wang J G. A single-crystalline hierarchical zeolite via an oriented co-growth of nanocrystals based on synergy of polyelectrolytes and hetero-atoms. ChemCatChem, 2020, 12(10): 2702–2707
Zhu J, Zhu Y H, Zhu L K, Rigutto M, van der Made A, Yang C G, Pan S X, Wang L, Zhu L F, Jin Y Y, et al. Highly mesoporous single-crystalline zeolite Beta synthesized using a nonsurfactant cationic polymer as a dual-function template. Journal of the American Chemical Society, 2014, 136(6): 2503–2510
Jin D L, Ye G H, Zheng J W, Yang W M, Zhu K, Coppens M O, Zhou X G. Hierarchical silicoaluminophosphate catalysts with enhanced hydroisomerization selectivity by directing the orientated assembly of premanufactured building blocks. ACS Catalysis, 2017, 7(9): 5887–5902
Schmidt I, Boisen A, Gustavsson E, Ståhl K, Pehrson S, Dahl S, Carlsson A, Jacobsen C J H. Carbon nanotube templated growth of mesoporous zeolite single crystals. Chemistry of Materials, 2001, 13(12): 4416–4418
Chen H Y, Wydra J, Zhang X Y, Lee P S, Wang Z P, Fan W, Tsapatsis M. Hydrothermal synthesis of zeolites with three-dimensionally ordered mesoporous-imprinted structure. Journal of the American Chemical Society, 2011, 133(32): 12390–12393
Machoke A G, Beltrán A M, Inayat A, Winter B, Weissenberger T, Kruse N, Güttel R, Spiecker E, Schwieger W. Micro/Macroporous system: MFI-type zeolite crystals with embedded macropores. Advanced Materials, 2015, 27(6): 1066–1070
Weissenberger T, Leonhardt R, Zubiri B A, Pitínová-Štekrová M, Sheppard T L, Reiprich B, Bauer J, Dotzel R, Kahnt M, Schropp A, et al. Synthesis and characterisation of hierarchically structured titanium silicalite-1 zeolites with large intracrystalline macropores. Chemistry, 2019, 25(63): 14430–14440
Shi Y, Li X, Hu J K, Lu J H, Ma Y C, Zhang Y H, Tang Y. Zeolite microspheres with hierarchical structures: formation, mechanism and catalytic performance. Journal of Materials Chemistry, 2011, 21(40): 16223–16230
Wang P Q, Li Z B, Wang X T, Tong Y M, Yuan F L, Zhu Y J. One-pot synthesis of Cu/SAPO-34 with hierarchical pore using cupric citrate as a copper source for excellent NH3-SCR of NO performance. ChemCatChem, 2020, 12(19): 4871–4878
Sun Q M, Wang N, Bai R S, Chen X X, Yu J H. Seeding induced nano-sized hierarchical SAPO-34 zeolites: cost-effective synthesis and superior MTO performance. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2016, 4(39): 14978–14982
Zhang Q, Mayoral A, Terasaki O, Zhang Q, Ma B, Zhao C, Yang G J, Yu J H. Amino acid-assisted construction of single-crystalline hierarchical nanozeolites via oriented-aggregation and intraparticle ripening. Journal of the American Chemical Society, 2019, 141(9): 3772–3776
Ding K L, Corma A, Maciá-Agulló J A, Hu J G, Krämer S, Stair P C, Stucky G D. Constructing hierarchical porous zeolites via kinetic regulation. Journal of the American Chemical Society, 2015, 137(35): 11238–11241
Jacobsen C J H, Madsen C, Houzvicka J, Schmidt I, Carlsson A. Mesoporous zeolite single crystals. Journal of the American Chemical Society, 2000, 122(29): 7116–7117
Fang Y M, Hu H Q, Chen G H. Zeolite with tunable intracrystal mesoporosity synthesized with carbon aerogel as a secondary template. Microporous and Mesoporous Materials, 2008, 113(1–3): 481–489
Du J, Wang Q H, Wang Y, Guo Y N, Li R F. A hierarchical zeolite Beta with well-connected pores via using graphene oxide. Materials Letters, 2019, 250: 139–142
Cho H S, Ryoo R. Synthesis of ordered mesoporous MFI zeolite using CMK carbon templates. Microporous and Mesoporous Materials, 2012, 151: 107–112
Wei X T, Smirniotis P G. Synthesis and characterization of mesoporous ZSM-12 by using carbon particles. Microporous and Mesoporous Materials, 2006, 89(1–3): 170–178
Schwanke A, Villarroel-Rocha J, Sapag K, Díaz U, Corma A, Pergher S. Dandelion-like microspherical MCM-22 zeolite using BP 2000 as a hard template. ACS Omega, 2018, 3(6): 6217–6622
Schmidt F, Paasch S, Brunner E, Kaskel S. Carbon templated SAPO-34 with improved adsorption kinetics and catalytic performance in the MTO-reaction. Microporous and Mesoporous Materials, 2012, 164: 214–221
Chen H, Zhang X W, Zhang J F, Wang Q F. Controllable synthesis of hierarchical ZSM-5 for hydroconversion of vegetable oil to aviation fuel like hydrocarbons. RSC Advances, 2017, 7(73): 46109–46117
Varzaneh A Z, Towfighi J, Sahebdelfarb S, Bahrami H. Carbon nanotube templated synthesis of hierarchical SAPO-34 catalysts with different structure directing agents for catalytic onversion of methanol to light olefins. Journal of Analytical and Applied Pyrolysis, 2016, 121: 11–23
Manrique C, Guzmán A, Pérez-Pariente J, Márquez-Álvarez C, Echavarrí A. Vacuum gas-oil hydrocracking performance of Beta zeolite obtained by hydrothermal synthesis using carbon nanotubes as mesoporous template. Fuel, 2016, 182: 236–247
Li M R, Zhou Y P, Fang Y M. Functioned carbon nanotube templated hierarchical silicate-1 synthesis: on the existence of super-micropore. Microporous and Mesoporous Materials, 2016, 225: 392–398
Tao Y S, Kanoh H, Kaneko K. Uniform mesopore-donated zeolite Y using carbon aerogel templating. Journal of Physical Chemistry B, 2003, 107(40): 10974–10976
Tao Y S, Kanoh H, Kaneko K. ZSM-5 monolith of uniform mesoporous channels. Journal of the American Chemical Society, 2003, 125(20): 6044–6045
White R J, Fischer A, Goebel C, Thomas A. A sustainable template for mesoporous zeolite synthesis. Journal of the American Chemical Society, 2014, 136(7): 2715–2718
de la Iglesia Ó, Sánchez J L, Coronas J. Hierarchical silicalite-1 structures based on pyrolized materials. Materials Letters, 2011, 65(19–20): 3124–3127
Li D, Qiu L, Wang K, Zeng Y, Li D, Williams T, Huang Y, Tsapatsis M, Wang H T. Growth of zeolite crystals with graphene oxide nanosheets. Chemical Communications, 2012, 48(16): 2249–2251
Ren Z, Kim E, Pattinson S W, Subrahmanyam K S, Rao C N R, Cheetham A K, Eder D. Hybridizing photoactive zeolites with graphene: a powerful strategy towards superior photocatalytic properties. Chemical Science, 2012, 3(1): 209–216
Zhang L C, Sun X B, Pan M, Yang X N, Liu Y C, Sun J H, Wang Q H, Zheng J J, Wang Y, Ma J H, et al. Interfacial effects between carbon nanotube templates and precursors on fabricating a wall-crystallized hierarchical pore system in zeolite crystals. Journal of Materials Science, 2020, 55(24): 10412–10426
Han S Y, Wang Z, Meng L Y, Jiang N Z. Synthesis of uniform mesoporous ZSM-5 using hydrophilic carbon as a hard template. Materials Chemistry and Physics, 2016, 177: 112–117
Bértolo R, Silva J M, Ribeiroa F, Maldonado-Hódar F J, Fernandes A, Martins A. Effects of oxidant acid treatments on carbon-templated hierarchical SAPO-11 materials: synthesis, characterization and catalytic evaluation in n-decane hydroisomerization. Applied Catalysis A, General, 2014, 485: 230–237
Zhao S F, Wang W D, Wang L Z, Schwieger W, Wang W, Huang J. Tuning hierarchical ZSM-5 zeolite for both gas- and liquid-phase biorefining. ACS Catalysis, 2020, 10(2): 1185–1194
Yoo W C, Kumar S, Wang Z Y, Ergang N S, Fan W, Karanikolos G N, McCormick A V, Penn R L, Tsapatsis M, Stein A. Nanoscale reactor engineering: hydrothermal synthesis of uniform zeolite particles in massively parallel reaction chambers. Angewandte Chemie International Edition, 2008, 47(47): 9096–9099
Yoo W C, Kumar S, Penn R L, Tsapatsis M, Stein A. Growth patterns and shape development of zeolite nanocrystals in confined syntheses. Journal of the American Chemical Society, 2009, 131(34): 12377–12383
Wang Z P, Dornath P, Chang C C, Chen H Y, Fan W. Confined synthesis of three-dimensionally ordered mesoporous imprinted zeolites with tunable morphology and Si/Al ratio. Microporous and Mesoporous Materials, 2013, 181: 8–16
Chen H Y, Lee P S, Zhang X Y, Lu D. Structure replication and growth development of three-dimensionally ordered mesoporous-imprinted zeolites during confined growth. Journal of Materials Research, 2013, 28(10): 1356–1364
Cho H J, Dornath P, Fan W. Synthesis of hierarchical Sn-MFI as Lewis acid catalysts for isomerization of cellulosic sugars. ACS Catalysis, 2014, 4(6): 2029–2037
Wang J, Yang M F, Shang W J, Su X P, Hao Q Q, Chen H Y, Ma X X. Synthesis, characterization, and catalytic application of hierarchical SAPO-34 zeolite with three-dimensionally ordered mesoporous imprinted structure. Microporous and Mesoporous Materials, 2017, 252: 10–16
Wang J, Yang M F, Zhang J B, Zhang S P, Wang X X, Fu K, Wang M Y, Sahng W J, Chen H Y, Ma X X. Fabrication of *BEA/MFI zeolite nanocomposites by confined space synthesis. Materials Chemistry and Physics, 2018, 207: 167–174
Madsen C, Madsen C, Jacobsen C J H. Nanosized zeolite crystals-convenient control of crystal size distribution by confined space synthesis. Chemical Communications, 1999, 8(8): 673–674
Schmidt I, Madsen C, Jacobsen C J H. Confined space synthesis. A novel route to nanosized zeolites. Inorganic Chemistry, 2000, 39(11): 2279–2283
Jacobsen C J H, Madsen C, Janssens T V W, Jakobsen H J, Skibsted J. Zeolites by confined space synthesis-characterization of the acid sites in nanosized ZSM-5 by ammonia desorption and 27Al/29Si-MAS NMR spectroscopy. Microporous and Mesoporous Materials, 2000, 39(1–2): 393–401
Christensen C H, Johannsen K, Schmidt I, Christensen C H. Catalytic benzene alkylation over mesoporous zeolite single crystals: improving activity and selectivity with a new family of porous materials. Journal of the American Chemical Society, 2003, 125(44): 13370–13371
Schmidt I, Krogh A, Wienberg K, Carlsson A, Brorson M, Jacobsen C J H. Catalytic epoxidation of alkenes with hydrogen peroxide over first mesoporous titanium-containing zeolite. Chemical Communications, 2000, 21(21): 2157–2158
Kustova M Y, Hasselriis P, Christensen C H. Mesoporous MEL-type zeolite single crystal catalysts. Catalysis Letters, 2004, 96(3–4): 205–211
Kustova M Y, Rasmussen S B, Kustov A L, Christensen C H. Direct NO decomposition over conventional and mesoporous Cu-ZSM-5 and Cu-ZSM-11 catalysts: improved performance with hierarchically porous zeolites. Applied Catalysis B: Environmental, 2006, 67(1–2): 60–67
Xin H C, Zhao J, Xu S T, Li J P, Zhang W P, Guo X W, Hensen E J M, Yang Q H, Li C. Enhanced catalytic oxidation by hierarchically structured TS-1 zeolite. Journal of Physical Chemistry, 2010, 114(14): 6553–6559
Holm M S, Egeblad K, Vennestrøm P N R, Hartmann C G, Kustova M, Christensen C H. Enhancing the porosity of mesoporous carbon-templated ZSM-5 by desilication. European Journal of Inorganic Chemistry, 2008, 33(33): 5185–5189
Rimaz S, Halladj R, Askari S. Synthesis of hierarchal SAPO-34 nano catalyst with dry gel conversion method in the presence of carbon nanotubes as a hard template. Journal of Colloid and Interface Science, 2016, 464: 137–146
Deng Z Y, Zhang Y C, Zhu K, Qian G, Zhou X G. Carbon nanotubes as transient inhibitors in steam-assisted crystallization of hierarchical ZSM-5 zeolites. Materials Letters, 2015, 159: 466–469
Zhu K, Egeblad K, Christensen C H. Mesoporous carbon prepared from carbohydrate as hard template for hierarchically porous zeolites. European Journal of Inorganic Chemistry, 2007, 2007(25): 3955–3960
Song Y, Hua Z, Zhu Y, Zhou X, Wu W, Zhang L, Shi J. An in situ carbonaceous mesoporous template for the synthesis of hierarchical ZSM-5 zeolites by one-pot steam-assisted crystallization. Chemistry, an Asian Journal, 2012, 7(12): 2772–2776
Nandan D, Saxena S K, Viswanadham N. Synthesis of hierarchical ZSM-5 using glucose as a templating precursor. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(4): 1054–1059
Sun M H, Chen L H, Yu S, Li Y, Zhou X G, Hu Z Y, Sun H Y, Xu Y, Su B L. Micron-sized zeolite Beta single crystals featuring intracrystal interconnected ordered macro-meso-microporosity displaying superior catalytic performance. Angewandte Chemie International Edition, 2020, 59(44): 19582–19591
Sun M H, Zhou J, Hu Z Y, Chen L H, Li L Y, Wang Y D, Xie Z K, Turner S, Tendeloo G V, Hasan T, et al. Hierarchical zeolite single-crystal reactor for excellent catalytic efficiency. Mater, 2020, 3(4): 1226–1245
Fan W, Snyder M A, Kumar S, Lee P S, Yoo W C, Mccormick A V, Penn R L, Stein A, Tsapaysis M. Hierarchical nanofabrication of microporous crystals with ordered mesoporosity. Nature Materials, 2008, 7(12): 984–991
Ryoo R, Joo S H, Jun S. Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. Journal of Physical Chemistry B, 1999, 103(37): 7743–7746
Jun S, Joo S H, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O. Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. Journal of the American Chemical Society, 2000, 122(43): 10712–10713
Zhang Y W, Okubo T, Ogura M. Synthesis of mesoporous aluminosilicate with zeolitic characteristics using vapor phase transport. Chemical Communications, 2005, 1(21): 2719–2720
Ogura M, Zhang Y W, Elangovan S P, Okubo T. Formation of ZMM-n: the composite materials having both natures of zeolites and mesoporous silica materials. Microporous and Mesoporous Materials, 2007, 101(1–2): 224–230
Wang J, Vinu A, Coppens M O. Synthesis and structure of silicalite-1/SBA-15 composites prepared by carbon templating and crystallization. Journal of Materials Chemistry, 2007, 17(40): 4265–4273
Sun C, Du J M, Liu J, Yang Y, Ren N, Shen N, Xu H L, Tang Y. A facile route to synthesize endurable mesopore containing ZSM-5 catalyst for methanol to propylene reaction. Chemical Communications, 2010, 46(15): 2671–2673
Pei X Y, Liu X X, Liu X Y, Shan J L, Fu H, Xie Y, Yan X M, Meng X Z, Zheng Y C, Li G, et al. Synthesis of hierarchical titanium silicalite-1 using a carbon-silica-titania composite from aerogel mild carbonization. Catalysts, 2019, 9(8): 672–680
Xue C F, Zhang F, Wu L M, Zhao D Y. Vapor assisted “in situ” transformation of mesoporous carbon-silica composite for hierarchically porous zeolites. Microporous and Mesoporous Materials, 2012, 151: 495–500
Du J, Wang Y, Wang Y, Ma J H, Li R F. In situ recrystallization of mesoporous carbon-silica composite for the synthesis of hierarchically porous zeolites. Materials (Basel), 2020, 13(7): 1640–1649
Tanaka S, Yuan C, Miyake Y. Synthesis of silicalite-1 using an interspace of ordered mesoporous carbon-silica nanocomposites: introduction of mesoporosity in zeolite crystals. Microporous and Mesoporous Materials, 2008, 113(1–3): 418–426
Du J, Wang Y, Wang Y, Ma J H, Li R F. Preparation of hierarchical ZSM-5 zeolites by in-situ crystallization of mesoporous carbon-silica composite. ChemistrySelect, 2020, 5(44): 14130–14135
Kustova M, Egeblad K, Zhu K, Christensen C H. Versatile route to zeolite single crystals with controlled mesoporosity: in situ sugar decomposition for templating of hierarchically porous zeolites. Chemistry of Materials, 2007, 19(12): 2915–2917
Wang X, Li G, Wang W, Jin C, Chen Y. Synthesis, characterization and catalytic performance of hierarchical TS-1 with carbon template from sucrose carbonization. Microporous and Mesoporous Materials, 2011, 142(2–3): 494–502
Liu P, Jin L N, Jin C, Zhang J N, Bian S W. Synthesis of hierarchically porous silicate-1 and ZSM-5 by hydrothermal transformation of SiO2 colloid crystal/carbon composites. Microporous and Mesoporous Materials, 2018, 262: 217–226
Peng Z, Chen L H, Sun M H, Zhao H, Wang Z, Li Y, Li L Y, Zhou J, Liu Z C, Su B L. A hierarchical zeolitic Murray material with a mass transfer advantage promotes catalytic efficiency improvement. Inorganic Chemistry Frontiers, 2018, 5(11): 2829–2835
Hou Y X, Li X Y, Sun M H, Li C F, Bakhtiar S H, Lei K, Yu S, Wang Z, Hu Z, Chen L, et al. The effect of hierarchical single-crystal ZSM-5 zeolites with different Si/Al ratios on its pore structure and catalytic performance. Frontiers of Chemical Science and Engineering, 2021, 15(2): 269–278
Abildstrøm J O, Ali Z N, Mentzel U V, Mielby J, Kegnæs S, Kegnæs M. Mesoporous MEL, BEA, and FAU zeolite crystals obtained by in situ formation of carbon template over metal nanoparticles. New Journal of Chemistry, 2016, 40(5): 4223–4227
Abildstrøm J O, Kegnæs M, Hytoft G, Mielby J, Kegnæs S. Synthesis of mesoporous zeolite catalysts by in situ formation of carbon template over nickel nanoparticles. Microporous and Mesoporous Materials, 2016, 225: 232–237
Wattanakit C, Warakulwit C, Pantu P, Sunpetch B, Charoenpanich M, Limtrakul J. The versatile synthesis method for hierarchical micro- and mesoporous zeolite: an embedded nanocarbon cluster approach. Canadian Journal of Chemical Engineering, 2012, 90(4): 873–880
Imyen T, Wannapakdee W, Limtrakul J, Wattanakit C. Role of hierarchical micro-mesoporous structure of ZSM-5 derived from an embedded nanocarbon cluster synthesis approach in isomerization of alkenes, catalytic cracking and hydrocracking of alkanes. Fuel, 2019, 254: 115593–115605
Tao H X, Yang H, Zhang Y H, Ren J W, Liu X H, Wang Y Q, Lu G Z. Space-confined synthesis of nanorod oriented assembled hierarchical MFI zeolite microspheres. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2013, 1(44): 13821–13827
Yang H, Yang P P, Liu X H, Wang Y Q. Space-confined synthesis of zeolite Beta microspheres via steam-assisted crystallization. Chemical Engineering Journal, 2016, 299: 112–119
Huang Y, Ho J, Wang Z, Nakashima P, Hill A J, Wang H T. Mesoporous carbon confined conversion of silica nanoparticles into zeolite nanocrystals. Microporous and Mesoporous Materials, 2009, 117(1–2): 490–496
Cho S I, Choi S D, Kim J H, Kim G J. Synthesis of ZSM-5 films and monoliths with bimodal micro/mesoscopic structures. Advanced Functional Materials, 2004, 14(1): 49–54
Tong Y C, Zhao T B, Li F Y, Wang Y. Synthesis of monolithic zeolite Beta with hierarchical porosity using carbon as a transitional template. Chemistry of Materials, 2006, 18(18): 4218–4220
Martini A, Borfecchia E, Lomachenko K A, Pankin I A, Negri C, Berlier G, Beato P, Falsig H, Bordiga S, Lamberti C. Composition-driven Cu-speciation and reducibility in Cu-CHA zeolite catalysts: a multivariate XAS/FTIR approach to complexity. Chemical Science (Cambridge), 2017, 8(10): 6836–6851
Zhao Z C, Yu R, Zhao R R, Shi C, Gies H, Xiao F S, De Vos D, Yokoi T, Bao X H, Kolb U, et al. Cu-exchanged Al-rich SSZ-13 zeolite from organotemplate-free synthesis as NH3-SCR catalyst: effects of Na+ ions on the activity and hydrothermal stability. Applied Catalysis B: Environmental, 2017, 217: 421–428
Zhu P F, Yang G H, Sun J, Fan R, Zhang P P, Yoneyama Y, Tsubaki N. A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(18): 8599–8607
Gu J, Zhang Z Y, Ding L P, Huang K, Xue N H, Peng L M, Guo X F, Ding W P. Platinum nanoparticles encapsulated in HZSM-5 crystals as an efficient catalyst for green production of p-aminophenol. Catalysis Communications, 2017, 97: 98–101
Choi M, Wu Z J, Iglesia E. Mercaptosilane-assisted synthesis of metal clusters within zeolites and catalytic consequences of encapsulation. Journal of the American Chemical Society, 2010, 132(26): 9129–9137
Wang N, Sun Q M, Bai R S, Li X, Guo G Q, Yu J H. In situ confinement of ultrasmall Pd clusters within nanosized silicalite-1 zeolite for highly efficient catalysis of hydrogen generation. Journal of the American Chemical Society, 2016, 138(24): 7484–7487
Sánchez-Sánchez M, Manjón Sanz A, Díaz I, Mayoral Á, Sastre E. Micron-sized single-crystal-like CoAPO-5/carbon composites leading to hierarchical CoAPO-5 with both inter-and intracrystal-line mesoporosity. Crystal Growth & Design, 2013, 13(6): 2476–2485
Varzaneh A Z, Towfighi J, Sahebdelfar S. Carbon nanotube templated synthesis of metal containing hierarchical SAPO-34 catalysts: impact of the preparation method and metal avidities in the MTO reaction. Microporous and Mesoporous Materials, 2016, 236: 1–12
Flores C, Batalha N, Ordomsky V V, Zholobenko V L, Baaziz W, Marcilio N R, Khodakov A Y. Direct production of iso-paraffins from syngas over hierarchical cobalt-ZSM-5 nanocomposites synthetized by using carbon nanotubes as sacrificial templates. ChemCatChem, 2018, 10(10): 2291–2299
Flores C, Zholobenko V L, Gu B, Batalha N, Valtchev V, Baaziz W, Ersen O, Marcilio N R, Ordomsky V V, Khodakov A Y. Versatile roles of metal species in carbon nanotube templates for the synthesis of metal-zeolite nanocomposite catalysts. ACS Applied Nano Materials, 2019, 2(7): 4507–4517
Amoo C C, Li M, Noreen A, Fu Y, Maturura E, Du C, Yang R, Gao X, Xing C, Tsubaki N. Fabricating Fe nanoparticles embedded in zeolite Y microcrystals as active catalysts for Fischer-Tropsch synthesis. ACS Applied Nano Materials, 2020, 3(8): 8096–8103
Chen Y Y, Chang C J, Lee H V, Juan J C, Lin Y C. Gallium-immobilized carbon nanotubes as solid templates for the synthesis of hierarchical Ga/ZSM-5 in methanol aromatization. Industrial & Engineering Chemistry Research, 2019, 58(19): 7948–7956
Chang C J, Chen C H, Lee J F, Sooknoi T, Lin Y C. Ga-supported MFI zeolites synthesized using carbon nanotubes containing gallium oxide nanoparticles on exterior walls and in interior channels as hard templates for methanol aromatization. Industrial & Engineering Chemistry Research, 2020, 59(24): 11177–11186
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This work was supported by the National Natural Science Foundation of China (Grant No. 21773128).
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Wang, H., Du, G., Jia, J. et al. Hierarchically porous zeolites synthesized with carbon materials as templates. Front. Chem. Sci. Eng. 15, 1444–1461 (2021). https://doi.org/10.1007/s11705-021-2090-6
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DOI: https://doi.org/10.1007/s11705-021-2090-6