Abstract
This paper presents a comparative analysis of electrochromic properties of nonstoichiometric hydrated films CuWO3.7·2H2O, WO2.5·2H2O, and α-WO2.9·H2O obtained by combined electrochemical and chemical methods. The use of EDAX X-ray diffraction and UV VIS spectroscopy and the Smacula-Dexter equation helped to determine that of differences in spectral and electrochemical characteristics CuWO3.7·2H2O, WO2.5·2H2O, and α-WO2.9·H2O electrochromic process as results chemical composition, stoichiometry, and the structure films based on W oxide compounds, where the contribution to the electrochromic film coloration is mainly done using localized states of W5+, W4+, and additionally Cu+ in the case of CuWO3.7·2H2O. This allows CuWO3.7·2H2O extending light absorption at the electrochromic coloration in the 450–650 nm visible region spectrum. At the same time, diffusion processes are slowed down due to the complementary electrochromic coloration of copper oxide compounds, which reduces the rate and efficiency CuWO3.7·2H2O film compared to WO2.5·2H2O and α-WO2.9·H2O. This helped to establish that the metal tungstates can be effective electrochromic material as is WO3 with an additional absorption band provided that the dimensionally diffusion rates of protons or lithium ions in both oxide components are achieved.
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Li HZ, Firby CJ, Elezzabi AY (2019) Rechargeable aqueous hybrid Zn2+/Al3+ electrochromic batteries. Joule 3:2268–2278
Li HZ, McRae L, Firby CJ, Elezzabi AY (2019) Recharge able aqueous electrochromic batteries utilizing Ti-substituted tungsten molybdenum oxide based Zn2+ ion intercalation cathodes. Adv Mater 31:1807065–1807210
Zhang SL, Cao S, Zhang TR (2020) Overcoming the technical challenges in Al anode-based electrochromic energy storage windows. Small Methods 4:1900545–1900706
Ma D, Shi G, Wang H, Zhang Q, Li Y (2014) Controllable growth of high-quality metal oxide/conducting polymer hierarchical nanoarrays with outstanding electrochromic properties and solar-heat shielding ability. J Mater Chem A 2:13541–13549
Lee SJ, Choi DS, Kang SH, Yang WS, Nahm S, Han SH, Kim T (2019) VO2/WO3-based hybrid smart windows with thermochromic and electrochromic properties. ACS Sustain Chem Eng 7:7111–7117
Faughnan BW, Crandall RS, Heyman PM (1975) Model for the bleaching of WO3 electrochromic films by an electric field. Appl Phys Lett 27:275–277
Bechinger C, Burdis MS, Zhang J-G (1999) Electrochromic coloration efficiency of a-WO3-y thin films as a function of oxygen deficiency. Appl Phys Lett 75:1541–1543
Yoshimura T (1985) Oscillator strength of small-polaron absorption in WOx (x≤3) electrochromic thin films. J Appl Phys 57:911–919
Johansson M, Zietz B, Niklasson G, Österlund L (2014) Optical properties of nanocrystalline WO3 and WO3-x thin films prepared by DC magnetron Sputtering. J Appl Phys 115:213510–213526
Bechinger C, Burdis MS, Zhang J-G (1997) Comparison between electrochromic and photochromic coloration efficiency of tungsten oxide thin films. Solid State Commun 101:753–756
Iguchi E, Miyagi H (1993) A study on the stability of polarons in monoclinic WO3. J Phys Chem Solids 54:403–409
Berggren L, Azens A, Niklasson GA (2001) Polaron absorption in amorphous tungsten oxide films. J Appl Phys 90:1860–1863
Saenger MF, Höing T, Hofmann T, Schubert M (2008) Polaron transitions in charge intercalated amorphous tungsten oxide thin films. Phys Status Solidi A 4:914–917
Ozkana E, Leea S-H, Tracy CE, Pittsa JR, Deb SK (2003) Comparison of electrochromic amorphous and crystalline tungsten oxide films. Sol Energy Mater Sol Cells 79:439–448
Miyake K, Kaneko H, Sano M, Suedomi N (1984) Physical and electrochromic properties of the amorphous and crystalline tungsten oxide thick films prepared under reducing atmosphere. J Appl Phys 55:2747–2753
Antonaia A, Addonizio ML, Minarini C, Polichetti T, Vittori-Antisari M (2001) Improvement in electrochromic response for an amorphous: crystalline WO3 double layer. Electrochim Acta 46:2221–2227
Sun SS, Holloway PR (1984) Modification of the electrochromic response of WO3 thin films by oxygen backfilling. J Vac Sci A 2:336–340
Bondarenko N, Eriksson O, Skorodumova NV (2015) Polaron mobility in oxygen-deficient and lithium-doped tungsten trioxide. Phys Rev B 92:165119–165127
Wang Z, Gong W, Wang X, Chen Z, Chen X, Chen J, Sun H, Song G, Cong S, Geng F, Zhao Z (2020) Remarkable near-infrared electrochromism in tungsten oxide driven by interlayer water-induced battery-to-pseudocapacitor transition. ACS Appl Mater Interfaces 12:33917–43392
Nayak AK, Verma M, Sohn Y, Deshpande PA, Pradhan D (2017) Highly active tungsten oxide nanoplate electrocatalysts for the hydrogen evolution reaction in acidic and near neutral electrolytes. ACS Omega 2:7039–7047
Thongpan W, Louloudakis D, Pooseekheaw P, Kumpika T, Kantarak E, Sroila W, Panthawan A, Thongsuwan W, Singjai P (2019) Porous CuWO4/WO3 composite films with improved electrochromic properties prepared by sparking method. Mater Lett 257:126747–126760
Yuan C, Lin H, Lu H, Xing E, Xie ZY, B, (2015) Anodic deposition and capacitive property of nano-WO3·H2O/MnO2 composite as supercapacitor electrode material. Mater Lett 148:167–170
Nishiyamaa K, Matsuo R, Sasano J, Yokoyama S, Izaki M (2017) Solid state tungsten oxide hydrate/tin oxide hydrate electrochromic device prepared by electrochemical reactions. AIP Adv 7:035004
Santos L, Neto JP, Crespo A, Baião P, Barquinha P, Pereira L, Martins R, Fortunato E (2015) Electrodeposition of WO3 nanoparticles for sensing applications. In: Aliofkhazraei M (ed) Electroplating of Nanostructures, IntechOpen, London, https://doi.org/10.5772/61216
Mineo G, Ruffino F, Mirabella S, Bruno E (2020) Investigation of WO3 electrodeposition leading to nanostructured. Thin Films Nanomater 10(8):1493–1505
Esmail A, Hashem H, Soltan S, Hammam M, Ramadan A (2016) Thickness dependence of electro-optical properties of WO3 films as an electrochromic functional material for energy-efficient applications. Phys Status Solidi A 214:1–9
Khanapuram U, Bhat SD, Aryasomayajula S (2019) Electrochromic device with magnetron sputtered tungsten oxide (WO3) and nafion membrane: performance with varying tungsten oxide thickness- a report. Mater Res Express 6:045513
Krasnov YS, Volkov SV, Kolbasov GY (2006) Optical and kinetic properties of cathodically deposited amorphous tungsten oxide films. J Non-Cryst Solids 352:3995–4002
Fomanyuk SS, Krasnov YuS, Kolbasov GYa, (2013) Kinetics of electrochromic process in thin films of cathodically deposited nickel hydroxide. J Solid State Electrochem 17:2643–2649
Lerner LS (1997) Physics for scientists and engineers. Jones & Bartlett Publishers Inc., Boston
Hssi A, Atourki L, Labchir N, Ouafi M, Abouabassi K, Elfanaoui A, Ihlal A, Bouabid K (2020) Optical and dielectric properties of electrochemically deposited p-Cu2O films. Mater Res Express 7:16424
Wilson S. (2015) Zn-VI/Cu2O heterojunctions for earth-abundant photovoltaics dissertation, California Institute of Technology
Yagi S (2011) Potential-pH diagrams for oxidation-state control of nanoparticles synthesized via chemical reduction. In: Moreno-Piraján JC (ed) Thermodynamics - Physical Chemistry of Aqueous Systems, IntechOpen, London, https://doi.org/10.5772/21548.
Rezaie HR, Hashempour M, Razavizadeh H, Mehrjoo H, Salehi MT, Ardestani M (2010) Investigation on fabrication of W-Cu nanocomposite via a thermochemical co-precipitation method and its consolidation behavior. J Nano Res 11:57–66
Li Y, Wang N, Xu J, Liu Z, Yu H (2019) Significant effect of advanced catalysts Co3S4 modified CuWO4·2H2O under visible light condition photocatalytic hydrogen production. J Nanopart Res 21:80
Kavitha B, Karthiga R (2020) Synthesis and characterization of CuWO4 as nano-adsorbent for removal of Nile blue and its antimicrobial studies. J Mater Environ Sci 11:57–68
Liang L, Zhang J, Zhou Y, Xie J, Zhang X, Guan M, Pan B, Xie Y (2013) High-performance flexible electrochromic device based on facile semiconductor-to-metal transition realized by WO3·2H2O ultrathin nanosheets. Sci Rep 3:1936
Gao X, Yang C, Xiao F, Zhu Y, Wang J, Su X (2012) WO3·0.33H2O nanoplates: Hydrothermal synthesis, photocatalytic and gas-sensing properties. Mater Lett 84:151–153
Kadam AV, Patil SB (2018) Polyaniline globules as a catalyst for WO3 nanoparticles for supercapacitor application. Mater Res Express 5:085036
Naik SJ, Salker AV (2010) Solid state studies on cobalt and copper tungstates nano materials. Solid State Sci 12:2065–2072
Momeni MM, Ghayeb Y, Menati M (2019) Highly efficient and photostable photocathodes based on CuWO4/Cu2O nanostructured thin films. J Iran Chem Soc 17:1–14
Jin P, Wei D, Wen Y, Luo M, Wang X, Tang M (2011) A combined experimental and DFT study of active structures and self-cycle mechanisms of mononuclear tungsten peroxo complexes in oxidation reactions. J Mol Struct 992:19–26
Markham AE, Kobe KA (1941) The solubility of carbon dioxide in aqueous solutions of sulfuric and perchloric acids at 25. J Am Chem Soc 63:1165–1166
Dolson D, Battino R, Letcher T, Pegel K, Revaprasadu N (1995) Carbohydrate dehydration demonstrations. J Chem Educ 72:927–929
Kumar VB, Mohanta D (2011) Formation of nanoscale tungsten oxide structures and colouration characteristics. Bull Mater Sci 34:435–442
Boruah PJ, Khanikar RR, Bailung H (2020) Synthesis and characterization of oxygen vacancy induced narrow bandgap tungsten oxide (WO3−x) nanoparticles by plasma discharge in liquid and its photocatalytic activity, plasma chemistry and plasma processing 3:1−18.
Uppachai P, Harnchana V, Pimanpang S, Amornkitbamrung V, Brown AP, Brydson RMD (2014) A substoichiometric tungsten oxide catalyst provides a sustainable and efficient counter electrode for dye-sensitized solar cells. J Electrochim Acta 145:27–33
Sawant SS, Bhagwat AD, Mahajan CM (2016) Synthesis of cuprous oxide (Cu2O) nanoparticles – a review. J Nano- Electron Phys 8:1–5
Chen K, Song S, Xue D (2015) Faceted Cu2O structures with enhancing Li-ion battery anode performances. Cryst Eng Comm 17:2110–2117
Darmawi S, Burkhardt S, Leichtweiss T, Weber DA, Wenzel S, Janek J, Elm MT, Klar PJ (2015) Correlation of electrochromic properties and oxidation states in nanocrystalline tungsten trioxide. Phys Chem Chem Phys 17:15903–15911
Dexter DL (1956) Absorption of light by atoms in solids. Phys Rev 101:48–55
Velevska J, Stojanov N, Pecovska-Gjorgjevich M, Najdoski M (2017) Electrochromism in tungsten oxide thin films prepared by chemical bath deposition. J Electrochem Sci Eng 7:27–37
Zimmer A, Gilliot M, Tresse M et al (2019) Coloration mechanism of electrochromic NaxWO3 thin films. Opt Lett 44:1104–1107
Somani PR, Radhakrishnan S (2002) Electrochromic materials and devices: present and future. Mater Chem Phys 77:117–133
Smela E (1999) A microfabricated movable electrochromic pixel based on polypyrrole. Adv Mater 11:1343–1345
Krasnov YS, Kolbasov GY (2004) Electrochromism and reversible changes in the position of fundamental absorption edge in cathodically deposited amorphous WO3. Electrochim Acta 49:2425–2433
Kondaiah P, Hussain O, Uthanna S (2012) Structural, optical, and luminescence properties of reactive magnetron sputtered tungsten oxide thin films. ISRN Optics. https://doi.org/10.5402/2012/801468
Gavrilyuk AI, Gusinskii GM, Lanskaya TG (1994) Determination of oscillator strength of an optical transition for color centers in WO3 thin films. Tech Phys Lett 20:295–297
Nakamura K, Moriga T, Sumi A, Kashu Y, Michihiro Y, Nakabayashi I, Kanashiroa T (2005) NMR study on the Li+ ion diffusion in LiCuO2 with layered structure. Solid State Ionics 176:837–840
Azam A, Kim J, Park J, Novak TG, Tiwari AP, Song SH, Kim B, Jeon S (2018) Two-dimensional WO3 nanosheets chemically converted from layered WS2 for high-performance electrochromic devices. Nano Lett 18:5646–5651
Randin J-P (1982) Viennet R Proton diffusion in tungsten trioxide thin films. J Electrochem Soc 129:2349–2354
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Smilyk, V.O., Fomanyuk, S.S., Rusetskyi, I.A. et al. Electrochromism in CuWO4 and WO3 thin films synthesized by combined electrochemical and chemical methods. Ionics 28, 4011–4023 (2022). https://doi.org/10.1007/s11581-022-04607-2
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DOI: https://doi.org/10.1007/s11581-022-04607-2