Abstract
As a visible-light response semiconductor materials, bismuth vanadate (BiVO4) is extensively applied in photodegradation organic dye field. In this study, we synthesized C3N5 nanosheets and coupled with decahedral BiVO4 to construct a Z-scheme C3N5/BiVO4 heterostructure with close interface contact. By introducing C3N5 into BiVO4, the built Z-scheme transfer pathway provides silky channel for charge carrier migration between different moieties and enables photoexcited electrons and holes accumulated on the surface of BiVO4 and C3N5. The accelerated separation of charge carriers ensures C3N5/BiVO4 heterostructures with a powerful oxidation capacity compared with pure BiVO4. Due to the synergistic effect in Z-scheme heterostructure, the C3N5/BiVO4 demonstrated an improved photodegradation ability of rhodamine B (RhB) and methylene blue (MB) that of bare BiVO4.
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References
Akhavan O (2009) Silver nanocube crystals on titanium nitride buffer layer. J Phys D: Appl Phys 42:105305. http://iopscience.iop.org/0022-3727/42/10/105305
Chang JS, Phuan YW, Chong MN, Ocon JD (2020) Exploration of a novel Type II 1D-ZnO nanorods/BiVO4 heterojunction photocatalyst for water depollution. J Ind Eng Chem 83:303–314. https://doi.org/10.1016/j.jiec.2019.12.002
Chen X, Zhou JB, Chen Y, Zhou Y, Ding LD, Liang H, Li X (2021) Degradation of tetracycline hydrochloride by coupling of photocatalysis and peroxymonosulfate oxidation processes using CuO-BiVO4 heterogeneous catalyst. Process Saf Environ Prot 145:364–377. https://doi.org/10.1016/j.psep.2020.08.016
Chuang PK, Wu KH, Yeh TF, Teng H (2016) Extending the π-conjugation of g-C3N4 by incorporating aromatic carbon for photocatalytic H2 evolution from aqueous solution. ACS Sustain Chem Eng 4:5989–5997. https://doi.org/10.1021/acssuschemeng.6b01266
Dong PY, Zhang ACJ, Pan JK, Gao KJ, Wang ZJ, Xi XG (2023) An all-organic S-scheme heterojunction containing donor–acceptor type conjugated polymer and C3N4 nanosheets assembled via π–π interaction for photocatalytic H2 generation. Appl Surf Sci 615:156414. https://doi.org/10.1016/j.apsusc.2023.156414
Dou K, Peng CY, Wang RC, Cao HP, Yao C, Qiu JF, Liu JL, Tsidaeva N, Wang W (2023) S-scheme tubular g-C3N4/BiOI heterojunctions for boosting photodegradation of tetracycline and Cr(VI): mechanism insight, degradation pathway and DFT calculation. Chem Eng J 455:140813. https://doi.org/10.1016/j.cej.2022.140813
Ebrahimi M, Akhavan O (2022) Nanomaterials for photocatalytic degradations of analgesic, mucolytic and anti-biotic/viral/inflammatory drugs widely used in controlling SARS-CoV-2. Catalysts 12:667. https://doi.org/10.3390/catal12060667
Farani MR, Farsadrooh M, Zare I, Gholami A, Akhavan O (2023) Green synthesis of magnesium oxide nanoparticles and nanocomposites for photocatalytic antimicrobial, antibiofilm and antifungal applications. Catalysts 13:642. https://doi.org/10.3390/catal13040642
Guo WQ, Luo HL, Jiang Z, Shangguan WF (2022) In-situ pressure-induced BiVO4/Bi0.6Y0.4VO4 S-scheme heterojunction for enhanced photocatalytic overall water splitting activity. Chin J Catal 43:316–328. https://doi.org/10.1016/S1872-2067(21)63846-9
He SX, Chen YX, Li X, Zeng LX, Zhu MS (2022) Heterogeneous photocatalytic activation of persulfate for the removal of organic contaminants in water: a critical review. ACS EST Eng 2:527–546. https://doi.org/10.1021/acsestengg.1c00330
Hu YD, Gao Y, Liu FJ, Tian YX, Wang QQ, Zeng DN, Shen TZ, Song J, Guan RF, Yuan HB (2023) The 0 1 0 and 1 1 0 facets of BiVO4 were selectively modified by Cu and g-C3N4 to enhance its visible light photocatalytic performance. Sep Purif Technol 323:124471. https://doi.org/10.1016/j.seppur.2023.124471
Li YL, Liu Y, Hao YJ, Wang XJ, Liu RH, Li FT (2020) Fabrication of core-shell BiVO4@Fe2O3 heterojunctions for realizing photocatalytic hydrogen evolution via conduction band elevation. Mater Des 187:108379. https://doi.org/10.1016/j.matdes.2019.108379
Li CG, Tian Q, Zhang YL, Li YY, Yang XM, Zheng H, Chen LY, Li FM (2022a) Sequential combination of photocatalysis and microalgae technology for promoting the degradation and detoxification of typical antibiotics. Water Res 210:117985. https://doi.org/10.1016/j.watres.2021.117985
Li SJ, Wang CC, Cai MJ, Yang F, Liu YP, Chen JL, Zhang P, Li X, Chen XB (2022b) Facile fabrication of TaON/Bi2MoO6 core–shell S-scheme heterojunction nanofibers for boosting visible-light catalytic levofloxacin degradation and Cr(VI) reduction. Chem Eng J 428:131158. https://doi.org/10.1016/j.cej.2021.131158
Li SJ, Cai MJ, Liu YP, Zhang JL, Wang CC, Zang SH, Li YJ, Zhang P, Li X (2022c) In situ construction of a C3N5 nanosheet/Bi2WO6 nanodot S-scheme heterojunction with enhanced structural defects for the efficient photocatalytic removal of tetracycline and Cr(VI). Inorg Chem Front 9:2479–2497. https://doi.org/10.1039/D2QI00317A
Li WX, Wang ZZ, Li Y, Ghasemi JB, Li J, Zhang GK (2022d) Visible-NIR light-responsive 0D/2D CQDs/Sb2WO6 nanosheets with enhanced photocatalytic degradation performance of RhB: unveiling the dual roles of CQDs and mechanism study. J Hazard Mater 424:127595. https://doi.org/10.1016/j.jhazmat.2021.127595
Liang JC, Li XQ, Zuo JL, Lin J, Liu ZL (2021) Hybrid 0D/2D heterostructures: in-situ growth of 0D g-C3N4 on 2D BiOI for efficient photocatalyst. Adv Compos Hybrid Mater 4:1122–1136. https://doi.org/10.1007/s42114-021-00341-x
Liu TY, Yang GJ, Wang W, Wang CX, Wang M, Sun XN, Xu P, Zhang JT (2020) Preparation of C3N5 nanosheets with enhanced performance in photocatalytic methylene blue (MB) degradation and H2-evolution from water splitting. Environ Res 188:109741. https://doi.org/10.1016/j.envres.2020.109741
Liu LZ, Hu TP, Dai K, Zhang JF, Liang CH (2021) A novel step-scheme BiVO4/Ag3VO4 photocatalyst for enhanced photocatalytic degradation activity under visible light irradiation. Chin J Catal 42:46–55. https://doi.org/10.1016/S1872-2067(20)63560-4
Liu F, Wang YQ, Xu D, Sun F, Zhang SC, Wang WL, Li XY, Yu WS, Yu H, Dong XT (2023) Full-spectrum-responsive 1D/2D BiVO4:Er3+, Yb3+/BiOCl core-shell S-scheme heterostructure with boosted charge transport and redox capacity for the efficient removal of organic pollutants. Ceram Int 49:13371–13385. https://doi.org/10.1016/j.ceramint.2022.12.212
Luo XL, Yang SY, Wang ZL, Xu YH (2023) Synthesis of Z-scheme Bi2S3/RGO/BiVO4 photocatalysts with superior visible light photocatalytic effectiveness for pollutant degradation. Sep Purif Technol 318:123966. https://doi.org/10.1016/j.seppur.2023.123966
Monga D, Basu S (2023) Novel MoS2/C3N5 composites with extended spectral response towards highly efficient photocatalytic abatement of hazardous pollutants. J Environ Manag 336:117570. https://doi.org/10.1016/j.jenvman.2023.117570
Qin HM, Wang K, Jiang LS, Li J, Wu XY, Zhang GK (2020) Ultrasonic-assisted fabrication of a direct Z-scheme BiOI/Bi2O4 heterojunction with superior visible light-responsive photocatalytic performance. J Alloys Compd 821:153417. https://doi.org/10.1016/j.jallcom.2019.153417
Qin TJ, Wei JS, Zhou CC, Zeng XR, Zhou J, Li YY (2023) Directional crystal facets deposition constructed BiVO4/Ag/MnO2 with plasmon resonance for enhanced photocatalytic degradation of antibiotics in water. Sep Purif Technol 317:123793. https://doi.org/10.1016/j.seppur.2023.123793
Qiu XY, Zhang Y, Zhu YF, Long C, Su L, Liu SQ, Tang ZY (2021) Applications of nanomaterials in asymmetric photocatalysis: recent progress, challenges, and opportunities. Adv Mater 33:2001731. https://doi.org/10.1002/adma.202001731
Rafiq A, Ikram M, Ali S, Niaz F, Khan M, Khan Q, Maqbool M (2021) Photocatalytic degradation of dyes using semiconductor photocatalysts to clean industrial water pollution. J Ind Eng Chem 97:111–128. https://doi.org/10.1016/j.jiec.2021.02.017
Rajendran S, Chellapandi T, UshaVipinachandran V, Venkata Ramanaiah D, Dalal C, Sonkar SK, Madhumitha G, Bhunia SK (2022) Sustainable 2D Bi2WO6/g-C3N5 heterostructure as visible light-triggered abatement of colorless endocrine disruptors in wastewater. Appl Surf Sci 577:151809. https://doi.org/10.1016/j.apsusc.2021.151809
Reddy CV, Nagar A, Shetti NP, Reddy IN, Basu S, Shim J, Kakarla RR (2023) Novel g-C3N4/BiVO4 heterostructured nanohybrids for high efficiency photocatalytic degradation of toxic chemical pollutants. Chemosphere 322:138146. https://doi.org/10.1016/j.chemosphere.2023.138146
Safaeia J, Ullahb H, Mohameda NA, Noha MFM, Soha MF, Tahirb AA, Ludina NA, Ibrahima MA, Isahakc WNRW, Teridia MAM (2018) Enhanced photoelectrochemical performance of Z-scheme g-C3N4/BiVO4 photocatalyst. Appl Catal b: Environ 234:296–310. https://doi.org/10.1016/j.apcatb.2018.04.056
Shan LW, Li JC, Wu Z, Dong LM, Chen HT, Li D, Suriyaprakash J, Zhang XL (2022) Unveiling the intrinsic band alignment and robust water oxidation features of hierarchical BiVO4 phase junction. Chem Eng J 436:131516. https://doi.org/10.1016/j.cej.2021.131516
Sun JJ, Li XY, Zhao QD, Tadé MO, Liu SM (2017) Construction of p-n heterojunction β-Bi2O3/BiVO4 nanocomposite with improved photoinduced charge transfer property and enhanced activity in degradation of ortho-dichlorobenzene. Appl Catal B: Environ 219:259–268. https://doi.org/10.1016/j.apcatb.2017.07.052
Tan MH, Shi WP, Wang HF, Di GL, Xie ZX, Fan SS, Tang J, Dong FS (2023) Effective photodegradation of antibiotics by guest-host synergy between photosensitizer and bismuth vanadate: underlying mechanism and toxicity assessment. Chemosphere 325:138362. https://doi.org/10.1016/j.chemosphere.2023.138362
Theerthagiri J, Lee SJ, Karuppasamy K, Park J, Yu Y, Kumari MLA, Chandrasekaran S, Kim HS, Choi MY (2021) Fabrication strategies and surface tuning of hierarchical gold nanostructures for electrochemical detection and removal of toxic pollutants. J Hazard Mater 420:126648. https://doi.org/10.1016/j.jhazmat.2021.126648
Tian MS, Hu CY, Yu JX, Chen LG (2023) Carbon quantum dots (CQDs) mediated Z-scheme g-C3N4-CQDs/BiVO4 heterojunction with enhanced visible light photocatalytic degradation of paraben. Chemosphere 323:138248. https://doi.org/10.1016/j.chemosphere.2023.138248
Vadivel S, Hariganesh S, Paul B, Rajendran S, Habibi-Yangjeh A, Maruthamani D, Kumaravel M (2020a) Synthesis of novel AgCl loaded g-C3N5 with ultrahigh activity as visible light photocatalyst for pollutants degradation. Chem Phys Lett 738:136862. https://doi.org/10.1016/j.cplett.2019.136862
Vadivel S, Hariganesh S, Paul B, Mamba G, Puviarasu P (2020b) Highly active novel CeTi2O6/g-C3N5 photocatalyst with extended spectral response towards removal of endocrine disruptor 2,4-dichlorophenol in aqueous medium. Colloids Surf A Physicochem Eng Asp 592:124583. https://doi.org/10.1016/j.colsurfa.2020.124583
Wang GW, Cheng HF (2023) Boosting catalytic efficiency via BiVO4 surface heterojunction-induced interfacial Z-scheme NiFe2O4/{0 1 0}BiVO4 composite. Sep Purif Technol 318:123949. https://doi.org/10.1016/j.seppur.2023.123949
Wang WY, Wang XW, Gan L, Ji XF, Wu ZL, Zhang RB (2021) All-solid-state Z-scheme BiVO4−Bi6O6(OH)3(NO3)3 heterostructure with prolonging electron-hole lifetime for enhanced photocatalytic hydrogen and oxygen evolution. J Mater Sci Technol 77:117–125. https://doi.org/10.1016/j.jmst.2020.09.051
Wang XT, Ren YY, Li Y, Zhang GK (2022b) Fabrication of 1D/2D BiPO4/g-C3N4 heterostructured photocatalyst with enhanced photocatalytic efficiency for NO removal. Chemosphere 287:132098. https://doi.org/10.1016/j.chemosphere.2021.132098
Wang XT, Wang ZZ, Li Y, Wang JT, Zhang GK (2022a) Efficient photocatalytic CO2 conversion over 2D/2D Ni-doped CsPbBr3/ Bi3O4Br Z-scheme heterojunction: Critical role of Ni doping, boosted charge separation and mechanism study. Appl Catal b: Environ 319:121895. https://doi.org/10.1016/j.apcatb.2022.121895
Wang ZZ, Li WX, Wang JT, Li Y, Zhang GK (2023) Novel Z-scheme AgI/Sb2WO6 heterostructure for efficient photocatalytic degradation of organic pollutants under visible light: interfacial electron transfer pathway, DFT calculation and mechanism unveiling. Chemosphere 311:137000. https://doi.org/10.1016/j.apcatb.2022.121895
Wu M, Jing QF, Feng XY, Chen LM (2018) BiVO4 microstructures with various morphologies: synthesis and characterization. Appl Surf Sci 427:525–532. https://doi.org/10.1016/j.apsusc.2017.07.299
Wu BY, Sun TK, Liu N, Lu LL, Zhang RZ, Shi W, Cheng P (2022) Modulation of Z-scheme heterojunction interface between ultrathin C3N5 nanosheets and metal–organic framework for boosting photocatalysis. ACS Appl Mater Interfaces 14:26742–26751. https://doi.org/10.1021/acsami.2c04729
Yang RJ, Chen QQ, Ma YY, Zhu RS, Fan YY, Huang JY, Niu HN, Dong Y, Li D, Zhang YF, Mei L, Chen BY, Zeng ZY (2021) Highly efficient photocatalytic hydrogen evolution and simultaneous formaldehyde degradation over Z-scheme ZnIn2S4-NiO/BiVO4 hierarchical heterojunction under visible light irradiation. Chem Eng J 423:130164. https://doi.org/10.1016/j.cej.2021.130164
Yang C, Qin C, Zhong JB, Li JZ, Huang ST, Wang Q, Ma L (2022a) Photocatalytic enhancement mechanism insight for BiVO4 induced by plasma treatment under different atmospheres. J Alloys Compd 890:161883. https://doi.org/10.1016/j.jallcom.2021.161883
Yang ZX, Wang ZZ, Wang JT, Li Y, Zhang GK (2022b) Facet-dependent activation of oxalic acid over magnetic recyclable Fe3S4 for efficient pollutant removal under visible light irradiation: enhanced catalytic activity, DFT calculations, and mechanism insight. Environ Sci Technol 56:18008–18017. https://doi.org/10.1021/acs.est.2c06571
Yu J, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–2169. https://doi.org/10.1002/adfm.200500799
Yu HJ, Shi R, Zhao YX, Bian T, Zhao YF, Zhou C, Waterhouse GIN, Wu LZ, Tung CH, Zhang TR (2017) Alkali-assisted synthesis of nitrogen deficient graphitic carbon nitride with tunable band structures for efficient visible-light-driven hydrogen evolution. Adv Mater 29:1605148. https://doi.org/10.1002/adma.201605148
Yue S, Chen L, Zhang MK, Liu Z, Chen T, Xie MZ, Cao Z, Han WH (2021) Electrostatic field enhanced photocatalytic CO2 conversion on BiVO4 nanowires. Nano-Micro Lett 14:15. https://doi.org/10.1007/s40820-021-00749-6
Zhang GH, Meng Y, Xie B, Ni ZM, Lu HF, Xia SJ (2021a) Precise location and regulation of active sites for highly efficient photocatalytic synthesis of ammonia by facet-dependent BiVO4 single crystals. Appl Catal B: Environ 296:120379. https://doi.org/10.1016/j.apcatb.2021.120379
Zhang JL, Tao HC, Wu SS, Yang JL, Zhu MS (2021b) Enhanced durability of nitric oxide removal on TiO2 (P25) under visible light: enabled by the direct Z-scheme mechanism and enhanced structure defects through coupling with C3N5. Appl Catal B: Environ 296:120372. https://doi.org/10.1016/j.apcatb.2021.120372
Zhang JL, Li Z, He J, Tao HC, Chen MS, Zhou YT, Zhu MS (2022) Reinforced photogenerated electrons in few-layer C3N5 for enhanced catalytic NO oxidation and CO2 reduction. ACS Catal 13:785–795. https://doi.org/10.1021/acscatal.2c05545
Zhao X, Hu J, Yao X, Chen S, Chen Z (2018) Clarifying the roles of oxygen vacancy in W-doped BiVO4 for solar water splitting. ACS Appl Energ Mater 1:3410–3419. https://doi.org/10.1021/acsaem.8b00559
Zhu K, Wang WY, Zhang BB, Chen XW, Ma DQ, Wang XW, Zhang RB, Liu Y, Dong PY, Xi XG (2022) Interface engineering of a 2D/2D BiVO4/Bi4V2O10 heterostructure with improved photocatalytic photoredox activity. Langmuir 38:7558–7566. https://doi.org/10.1021/acs.langmuir.2c00609
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Financial support was provided by the National Natural Science Foundation of China (51772258 and 21403184), the funding for the school-level research projects of the Yancheng Institute of Technology (xjr2021003), Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant nos. 22KJD150007 and 22KJA430008), the Qinglan Project of Jiangsu Province, and the funding for the graduate research and practice innovation project of the Yancheng Institute of Technology (KYCX23_XZ008).
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Dongqi Ma and Wuyou Wang: conceptualization, methodology, writing—original draft. Qinzheng Wang: software. Yelan Dai: resources. Kai Zhu: investigation. Haocheng Xu: supervision. Cheng Yuan: data curation. Pengyu Dong: writing—review and editing. Xinguo Xi: writing—review and editing.
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Ma, D., Wang, W., Wang, Q. et al. A novel visible-light-driven Z-scheme C3N5/BiVO4 heterostructure with enhanced photocatalytic degradation performance. Environ Sci Pollut Res 31, 19687–19698 (2024). https://doi.org/10.1007/s11356-024-32086-7
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DOI: https://doi.org/10.1007/s11356-024-32086-7