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Enhanced Photocatalytic Degradation of Malachite Green Using Highly Efficient Copper Oxide/Graphene Oxide Nanocomposites

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Abstract

In recent years, enormous attention has been paid to environmental contamination, especially human exposure to dyes because of their extensive use in industries including textiles, paper, plastics, tannery paints etc. These dyes impart colour to water and thereby impede light penetration which can eventually degrade the water quality and thus inhibits the photosynthetic activity in aquatic organisms. Due to the favourable reaction conditions, high rate of degradation and wide application area. Photocatalysis is a viable approach for addressing such environmental issues. In the present study, we have successfully synthesized an efficient photocatalyst based on copper oxide/graphene oxide (CuO/GO) nanocomposites in a short period of time through a cost-effective and environment-friendly method. A new area of bioremediation has been made possible by the enhanced ability of these nanocomposites to absorb light and improved heterogeneous catalytic efficiency. Various techniques such as UV–VIS spectroscopy, XRD, FTIR, SEM EDX and HR-TEM have been used to characterize the nanocomposites. The photocatalytic activity of the nanocomposites has been investigated using Malachite Green (MG) dyes as a model for water contaminants. The effect of time, dye concentration, photocatalyst dosage, and pH value on the efficiency of the photocatalyst and the photodegradation kinetics has been analysed in detail. The results indicate that the CuO/GO nanocomposites have the potential to function as an effective and versatile photocatalyst for the degradation of MG.

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References

  1. Singh P, Shandilya P, Raizada P, Sudhaik A, Rahmani-Sani A, Bandegharaei AH (2020) Review on various strategies for enhancing photocatalytic activity of graphene based nanocomposites for water purification. Arab J Chem 13:3498–3520

    Article  CAS  Google Scholar 

  2. Sreelekshmi PB, Pillai RR, Meera AP (2022) Controlled synthesis of novel graphene oxide nanoparticles for the photodegradation of organic dyes. Top Catal 65:5–6

    Google Scholar 

  3. Li Z, Chen X, Wang M, Zhang X, Liao L, Fang T, Li B (2021) Photocatalytic degradation of Congo red by using the Cu2O/α-Fe2O3 composite catalyst. Desalin Water Treat 215:222–231

    Article  CAS  Google Scholar 

  4. Fang X, Bando Y, Gautam UK, Ye C, Golberg D (2008) Inorganic semiconductor nanostructures and their field-emission applications. J Mater Chem 18:509–522

    Article  CAS  Google Scholar 

  5. Vinesh V, Shaheer ARM, Neppolian B (2019) Reduced graphene oxide (rGO) supported electron deficient B-doped TiO2 (Au/B-TiO2/rGO) nanocomposite: an efficient visible light sonophotocatalyst for the degradation of Tetracycline (TC). Ultrason Sonochem 50:302–310

    Article  CAS  Google Scholar 

  6. Wang H, Pan Q, Zhao J, Chen W (2009) Fabrication of CuO/C films with sisal-like hierarchical microstructures and its application in lithium ion batteries. J Alloys Compd 476:408–413

    Article  CAS  Google Scholar 

  7. Li F, Liu X, Zhang Q, Kong T, Jin H (2012) Fabrication and photocatalytic property of CuO nanosheets via a facile solution route. Cryst Res Technol 47:1140–1147

    Article  CAS  Google Scholar 

  8. Asiya SI, Pal K, Kralj S, El-Sayyade GS, de Souza FG, Narayanan T (2020) Sustainable preparation of gold nanoparticles via green chemistry approach for biogenic applications. Mater Today Chem 17:100327

    Article  Google Scholar 

  9. Kerour A, Boudjadar S, Bourzami R, Allouche B (2018) Ecofriendly synthesis of cuprous oxide (Cu2O) nanoparticles and improvement of their solar photocatalytic activities. J Solid State Chem 263:79–83

    Article  CAS  Google Scholar 

  10. Ijaz F, Shahid S, Khan SA, Ahmad W, Zaman S (2017) Green synthesis of copper oxide nanoparticles using Abutilon indicum leaf extract: antimicrobial, antioxidant and photocatalytic dye degradation activity. Trop J Pharm Res 16:743–753

    Article  CAS  Google Scholar 

  11. Manjari G, Saran S, Arun T, Rao AVB, Devipriya SP (2017) Catalytic and recyclability properties of phytogenic copper oxide nanoparticles derived from Aglaia elaeagnoidea flower extract. J Saudi Chem Soc 21:610–618

    Article  CAS  Google Scholar 

  12. Maruthupandy M, Zuo Y, Chen JS, Song JM, Niu HL, Mao CJ, Zhang SY, Shen YH (2017) Synthesis of metal oxide nanoparticles (CuO and ZnO NPs) via biological template and their optical sensor applications. Appl Surf Sci 397:167–174

    Article  CAS  Google Scholar 

  13. Ochoa L, Medina-Velo IA, Barrios AC, Bonilla-Bird NJ, Hernandez-Viezcas JA, Peralta-Videa JR, Gardea-Torresdey JL (2017) Modulation of CuO nanoparticles toxicity to green pea (Pisum sativum Fabaceae) by the phytohormone indole-3-acetic acid. Sci Total Environ 598:513–524

    Article  CAS  Google Scholar 

  14. Prasad KS, Patra A, Shruthi G, Chandan S (2017) Aqueous extract of Saraca indica leaves in the synthesis of copper oxide nanoparticles: finding a way towards going green. J Nanotechnol 2017:7502610

    Article  Google Scholar 

  15. Praburaman L, Jang LS, Muthusamy G, Arumugam S, Manoharan K, Cho KM, Min C, Kamala-Kannan S, Byung-Taek O (2016) Piper betle-mediated synthesis, characterization, antibacterial and rat splenocyte cytotoxic effects of copper oxide nanoparticles. Artif Cells Nanomed Biotechnol 44:1400–1405

    Article  CAS  Google Scholar 

  16. Jadhav MS, Kulkarni S, Raikar P, Barretto DA, Vootla SK, Raikar US (2018) Green biosynthesis of CuO & Ag–CuO nanoparticles from Malus domestica leaf extract and evaluation of antibacterial, antioxidant and DNA cleavage activities. New J Chem 42:204–213

    Article  CAS  Google Scholar 

  17. Bordbar M, Sharifi-Zarchi Z, Khodadadi B (2017) Green synthesis of copper oxide nanoparticles/clinoptilolite using Rheum palmatum L. root extract: high catalytic activity for reduction of 4-nitro phenol, rhodamine B, and methylene blue. J Sol–Gel Sci Technol 81:724–733

    Article  CAS  Google Scholar 

  18. Chaudhary S, Rohilla D, Umar A, Kaur N, Shanavas A (2019) Synthesis and characterizations of luminescent copper oxide nanoparticles: toxicological profiling and sensing applications. Ceram Int 45:15025–15035

    Article  CAS  Google Scholar 

  19. Sajan CP, Wageh S, Al-Ghamdi AA, Yu J, Cao S (2016) TiO2 nanosheets with exposed 001 facets for photocatalytic applications. Nano Res 9:3–27

    Article  CAS  Google Scholar 

  20. Jiang W, Liu Y, Wang J, Zhang M, Luo W, Zhu Y (2016) Separation-free polyaniline/TiO2 3D hydrogel with high photocatalytic activity. Adv Mater Interfaces 3:1500502

    Article  Google Scholar 

  21. Pal K, Si A, El-Sayyad GS, Abd Elkodous M, Kumar R, El-Batal AI, Kralj S, Thomas S (2020) Cutting edge development on graphene derivatives modified by liquid crystal and CdS/TiO2 hybrid matrix: optoelectronics and biotechnological aspects. Crit Rev Solid State Mater Sci 46:385–449

    Article  Google Scholar 

  22. Sehar S, Sher F, Zhang S, Khalid U, Sulejmanovic J, Lima EC (2020) Thermodynamic and kinetic study of synthesised graphene oxide–CuO nanocomposites: a way forward to fuel additive and photocatalytic potentials. J Mol Liq 313:113494

    Article  CAS  Google Scholar 

  23. Rukhsar B, Nutan S, Sharoni G, Chetna A, Rakshit A, Pinki BP (2022) A facile synthesis of GO/CuO nanocomposite with enhancing photocatalytic activity for the degradation of azure-B dye and its antimicrobial behavior. Arab J Sci Eng 47:365–378

    Article  Google Scholar 

  24. Darvishi M, Mohseni-Asgerani G, Seyed-Yazdi J (2017) Simple microwave irradiation procedure for the synthesis of CuO/Graphene hybrid composite with significant photocatalytic enhancement. Surf Interfaces 7:69–73

    Article  CAS  Google Scholar 

  25. Bai X, Wang L, Zong R, Lv Y, Sun Y, Zhu Y (2013) Performance enhancement of ZnO photocatalyst via synergic effect of surface oxygen defect and graphene hybridization. Langmuir 29:3097–3105

    Article  CAS  Google Scholar 

  26. Subramanian V, Wolf EE, Kamat PV (2004) Catalysis with TiO2/gold nanocomposites. Effect of metal particle size on the Fermi level equilibration. J Am Chem Soc 126:4943–4950

    Article  CAS  Google Scholar 

  27. Soliman IE, El Sheikha HM, Gaber A, Shawky A, Ahmed AI (2020) Highly efficient sunlight-driven photocatalytic degradation of malachite green dye over reduced graphene oxide-supported CuS nanoparticles. J Alloy Compd 849:156573

    Article  Google Scholar 

  28. Iqbal S, Bibi I, Majid F, Jilani K, Kamal S, Iqbal M, Ata S, Nazar N, Albalawi H, Alwadai N (2022) The electrochemical, dielectric, and ferroelectric properties of Gd and Fe doped LaNiO3 with an efficient solar-light driven catalytic activity to oxidize malachite green dye. J Colloid Interface Sci 607:568–583

    Article  CAS  Google Scholar 

  29. Sakthive S, Periakaruppan R, Vallinayagam S, Gandhi S, Tappa MM, Sharma VK, Sivaramakrishnan R, Suresh S, Gurusamy A (2022) Synthesis and characterization of paddy straw chitosan nanocomposite as an efficient photocatalytic bio-adsorbent for the removal of rhodamine B and malachite green dye from aqueous solution. Appl Nanosci. https://doi.org/10.1007/s13204-021-02141-7

    Article  Google Scholar 

  30. Nazim M, Parwaz Khan AA, Asiri AM, Kim JH (2021) Exploring rapid photocatalytic degradation of organic pollutants with porous CuO nanosheets: synthesis, dye removal, and kinetic studies at room temperature. ACS Omega 6:2601–2612

    Article  CAS  Google Scholar 

  31. Ahmmad B, Kusumoto Y, Islam MS (2010) One-step and large scale synthesis of non-metal doped TiO2 submicrospheres and their photocatalytic activity. Adv Powder Technol 21:292–297

    Article  CAS  Google Scholar 

  32. Khorsand Zak R, Razali R, Majid WHA, Darroudi M (2011) Green synthesis and evolution of metabolic activity of starchmediated nanoceria. Int J Nanomed 6:1399–1403

    Article  CAS  Google Scholar 

  33. Altikatoglu M, Attar A, Erci F, Marilena Cristache C, Isildak I (2017) Green synthesis of copper oxide nanoparticles using Ocimum basilicum extract and their antibacterial activity. Fresenius Environ Bull 26:7832–7837

    CAS  Google Scholar 

  34. Altin I (2022) CuO-TiO2/graphene ternary nanocomposite for highly efficient visible-light-driven photocatalytic degradation of bisphenol A. J Mol Struct 1252:132199

    Article  CAS  Google Scholar 

  35. Zhao J, Nguyen DCT, Areerob Y, Oh WC (2019) Novel synthesis of nano needle-like Cu2O–GO–TiO2 and CuO–GO–TiO2 for the high photocatalytic performance of anionic and cationic pollutants. Solid State Sci 91:77–88

    Article  CAS  Google Scholar 

  36. Sreelekshmi PB, Pillai RR, Meera AP (2022) Evaluation of antimicrobial activity of bio synthesised zinc oxide nanoparticles using Morinda umbellata leaf extract. ECS Trans 107:15953–15964

    Article  Google Scholar 

  37. Wang H, Pan Q, Zhao J, Yin G, Zuo P (2007) Fabrication of CuO film with network-like architectures through solution-immersion and their application in lithium ion batteries. J Power Sources 167:206–211

    Article  CAS  Google Scholar 

  38. Zhang Q, Zhang K, Xu D, Yang G, Huang H, Nie F, Liu C, Yang S (2014) CuO nanostructures: synthesis, characterization, growth mechanisms, fundamental properties, and applications. Prog Mater Sci 60:208–337

    Article  CAS  Google Scholar 

  39. Gopal P, Mira P, Kim HY, Lee SY, Park SJ (2015) Electrospun ZnO hybrid nanofibers for photodegradation of wastewater containing organic dyes. A review. J Ind Eng Chem 21:26–35

    Article  Google Scholar 

  40. Jang YJ, Simer C, Ohm T (2006) Comparison of zinc oxide nanoparticles and its nano-crystalline particles on the photocatalytic degradation of methylene blue. Mater Res Bull 41:67–77

    Article  CAS  Google Scholar 

  41. Wang H, Xie C, Zhang W, Cai S, Yang Z, Gui Y (2007) Comparison of dye degradation efficiency using ZnO powders with various size scales. J Hazard Mater 141:645–652

    Article  CAS  Google Scholar 

  42. Purkait MK, Maiti A, Das Gupta S, De S (2007) Removal of Congo red using activated and its regeneration. J Hazard Mater 145:287–295

    Article  CAS  Google Scholar 

  43. Wan J, Jiang X, Li H, Chen K (2012) Facile synthesis of zinc ferrite nanoparticles as non-lanthanide T1 MRI contrast agents. J Mater Chem 22:13500–13505

    Article  CAS  Google Scholar 

  44. Yin Z, Zhou W, Gao Y, Ma D, Kiely CJ, Bao X (2012) Supported Pd–Cu bimetallic nanoparticles that have high activity for the electrochemical oxidation of methanol. Chem Eur J 18:4887–4893

    Article  CAS  Google Scholar 

  45. Cao S, Yeung KL, Kwan JKC, To PMT, Yu SCT (2009) An investigation of the performance of catalytic aerogel filters. Appl Catal B 86:127–136

    Article  CAS  Google Scholar 

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Acknowledgements

We thankfully acknowledge University of Kerala for the financial assistance. The support from STIC, Cochin, Kerala and CIF Pondicherry, Tamil Nadu is greatly acknowledged.

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Authors and Affiliations

  1. Research and Post Graduate Department of Chemistry, K.S.M. Devaswom Board College, Sasthamcotta, Kollam, Kerala, 690521, India

    P. B. Sreelekshmi, Reshma R. Pillai & A. P. Meera

  2. Department of Physics & Nanotechnology, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, 603 203, India

    B. Binish

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Sreelekshmi, P.B., Pillai, R.R., Binish, B. et al. Enhanced Photocatalytic Degradation of Malachite Green Using Highly Efficient Copper Oxide/Graphene Oxide Nanocomposites. Top Catal 65, 1885–1898 (2022). https://doi.org/10.1007/s11244-022-01693-4

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