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Synthesis and structure of the coordination polymer [Li5/3H1/3(H4chhc)]

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Abstract

The coordination polymer of the composition [Li5/3H1/3(H4chhc)] was synthesized by the reaction of lithium hydroxide monohydrate with 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H6chhc) at 100 °C in a 1,4-dioxane-methanol mixture. The structure of this compound was determined by X-ray crystallography and confirmed by IR spectroscopy, as well as by thermo-gravimetric and elemental analysis. The coordination polymer has a structure of a 3D metal-organic framework built from lithium cations and H4chhc2− anions.

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References

  1. O. M. Yaghi, M. O’Keeffe, N. W. Ockwing, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.

    Article  CAS  Google Scholar 

  2. B. Kesanli, W. B. Lin, Coord. Chem. Rev., 2003, 246, 305.

    Article  CAS  Google Scholar 

  3. K. Sumida, D. L. Rogow, J. A. Mason, T. M. McDonald, E. D. Bloch, Z. R. Herm, T. Bae, J. R. Long, Chem. Rev., 2012, 112, 724.

    Article  CAS  Google Scholar 

  4. M. P. Suh, H. J. Park, T. K. Prasad, D. Lim, Chem. Rev., 2012, 112, 782.

    Article  CAS  Google Scholar 

  5. R. B. Getman, Y. Bae, C. E. Wilmer, R. Q. Snurr, Chem. Rev., 2012, 112, 703.

    Article  CAS  Google Scholar 

  6. O. M. Yaghi, G. Li, H. Li, Nature, 1995, 378, 703.

    Article  CAS  Google Scholar 

  7. Q. M. Wang, D. Shen, M. Bülow, M. L. Lau, S. Deng, F. R Fitch, N. O Lemcoff, J. Semanscin, Microporous Mesoporous Mater., 2002, 55, 217.

    Article  CAS  Google Scholar 

  8. J. Li, R. J. Kuppler, H. Zhou, Chem. Soc. Rev., 2009, 38, 1248.

    Article  Google Scholar 

  9. M. Yoon, K. Suh, S. Natarajan, K. Kim, Angew. Chem., Int. Ed., 2013, 52, 2688.

    Article  CAS  Google Scholar 

  10. M. O’Keeffe, Chem. Soc. Rev., 2009, 38, 1215.

    Article  Google Scholar 

  11. D. Banerjee, J. B. Parise, Cryst. Growth Des., 2011, 11, 4704.

    Article  CAS  Google Scholar 

  12. L. J. Murray, M. Dincay, J. R. Long, Chem. Soc. Rev., 2009, 38, 1294.

    Article  CAS  Google Scholar 

  13. X. Zhao, T. Wu, S. Zheng,L. Wang, X. Bu, P. Feng, Chem. Commun., 2011, 47, 5536.

    Article  CAS  Google Scholar 

  14. B. F. Abrahams, M. J. Grannas, T. A. Hudson, R. Robson, Angew. Chem., Int. Ed., 2010, 49, 1087.

    Article  CAS  Google Scholar 

  15. D. Banerjee, S. J. Kim, W. Li, H. Wu, J. Li, L. A. Borkowski, B. L. Philips, J. B. Parise, Cryst. Growth Des., 2010, 10, 2801.

    Article  CAS  Google Scholar 

  16. M. Frigoli, R. EI Osta, J. Marrot, M. E. Medina, R. I. Walton, F. Millange, Eur. J. Inorg. Chem., 2013, 7, 1138.

    Article  Google Scholar 

  17. Bruker Advanced X-ray Solutions, Bruker AXS Inc., Madison (WI), USA, 2004.

  18. G. M. Sheldrick, Acta Crystallogr., 2008, A64, 112.

    Article  Google Scholar 

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    S. B. Aliev, D. G. Samsonenko & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    D. G. Samsonenko & V. P. Fedin

Authors
  1. S. B. Aliev
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  2. D. G. Samsonenko
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  3. V. P. Fedin
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Correspondence to V. P. Fedin.

Additional information

According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhny Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0997–1000, April, 2014.

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Aliev, S.B., Samsonenko, D.G. & Fedin, V.P. Synthesis and structure of the coordination polymer [Li5/3H1/3(H4chhc)]. Russ Chem Bull 63, 997–1000 (2014). https://doi.org/10.1007/s11172-014-0539-1

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  • DOI: https://doi.org/10.1007/s11172-014-0539-1

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