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A Novel Coordination Polymer Constructed by Hetero−Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)2(μ-H2O)(H2O)2] n

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Abstract

A novel coordination polymer containing hetero-metal ions, [NiNa2(PDC)2(μ-H2O)(H2O)2] n , where PDC is 2,3-pyridine dicarboxylate ion, has been synthesized. In the structure, the PDC ligand chelates and bridges two Ni(II) and two Na(I) centers. Two kinds of metal centers are connected by μ4-PDC and μ2-H2O to form 2D coordination layers. Hydrogen bonds between coordination water molecules and carboxylate oxygen atoms further link these 2D coordination layers to form 3D supramolecular network.

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059 P. R., China

    Ming-Yu Dou & Jing Lu

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  1. Ming-Yu Dou
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  2. Jing Lu
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Correspondence to Jing Lu.

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Dou, MY., Lu, J. A Novel Coordination Polymer Constructed by Hetero−Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)2(μ-H2O)(H2O)2] n . Crystallogr. Rep. 62, 1055–1059 (2017). https://doi.org/10.1134/S1063774517070197

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  • DOI: https://doi.org/10.1134/S1063774517070197

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