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The synthesis of 5-amino-1H-pyrazole-4-carbonitriles by anomeric based oxidative aromatization over [CSPy]ZnCl3 as a new catalyst

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Abstract

4-Carboxy-1-sulfopyridin-1-ium monozinc(II) trichloride {[4CSPy]ZnCl3} as a new acidic catalyst was designed and tested on the synthesis of 5-amino-1H-pyrazole-4-carbonitriles by anomeric based oxidative aromatization. The structure of [4CSPy]ZnCl3 was studied by various analyses such as Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR), energy-dispersive X-ray spectroscopy, thermal gravimetric analysis, differential thermal gravimetric analysis and mass spectroscopy (MS).

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The synthesis of 5-amino-1H-pyrazole-4-carbonitriles by anomeric based oxidative aromatization over [CSPy]ZnCl3 as a new catalyst

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Acknowledgements

The authors gratefully acknowledge the Sayyed Jamaleddin Asadabadi University for providing support to this work.

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Authors and Affiliations

  1. Department of Chemical Engineering, Hamedan University of Technology, 65155, Hamedan, Iran

    Ahmad Reza Moosavi-Zare & Hamid Goudarziafshar

  2. Sayyed Jamaleddin Asadabadi University, 6541861841, Asadabad, I. R. of Iran

    Mohammad Rezaei-Gohar & Mahsa Tavasoli

Authors
  1. Ahmad Reza Moosavi-Zare
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  2. Mohammad Rezaei-Gohar
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  4. Hamid Goudarziafshar
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Correspondence to Ahmad Reza Moosavi-Zare.

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Moosavi-Zare, A.R., Rezaei-Gohar, M., Tavasoli, M. et al. The synthesis of 5-amino-1H-pyrazole-4-carbonitriles by anomeric based oxidative aromatization over [CSPy]ZnCl3 as a new catalyst. Res Chem Intermed 47, 2689–2700 (2021). https://doi.org/10.1007/s11164-021-04437-3

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