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Synthesis of some thionocarbamates from O-isopropyl xanthate and amines using Pd/Ti-HMS-10 as catalyst in water

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Abstract

Ti-HMS materials with different Si/Ti ratio (5, 10, 20 and 30) were prepared and used as the support for a palladium-containing (1 wt%) catalyst. The materials, analyzed by XRD and SEM techniques, were tested in the synthesis of some thionocarbamates from reaction of sodium O-isopropyl carbonodithioate with the corresponding amines. The best yield was obtained with 3 mmol% of the catalyst (Pd/Ti-HMS-10) in water as solvent after 10–15-h heating at 75 °C. The structures of the products were identified by spectroscopy techniques such as 1H-NMR, 13C-NMR, IR and elemental analysis.

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Acknowledgments

The authors wish to thank Vali-e-Asr University of Rafsanjan for partially funding this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Vali-e-Asr University, Rafsanjan, 77176, Islamic Republic of Iran

    Reza Ranjbar-Karimi, Masumeh Asadi, Alireza Talebizadeh & Samira Saeednia

  2. Department of Chemistry, Shahid Beheshti University, G. C., PO Box 19396 4716, Tehran, Iran

    Samira Saeednia & Sayed Mohammad Sayedbagheri

Authors
  1. Reza Ranjbar-Karimi
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  2. Masumeh Asadi
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  3. Alireza Talebizadeh
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  4. Samira Saeednia
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  5. Sayed Mohammad Sayedbagheri
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Correspondence to Reza Ranjbar-Karimi.

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Ranjbar-Karimi, R., Asadi, M., Talebizadeh, A. et al. Synthesis of some thionocarbamates from O-isopropyl xanthate and amines using Pd/Ti-HMS-10 as catalyst in water. J IRAN CHEM SOC 13, 1867–1874 (2016). https://doi.org/10.1007/s13738-016-0903-1

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  • DOI: https://doi.org/10.1007/s13738-016-0903-1

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