Abstract
Focusing on three different applications of sol–gel functional materials holding the potential to replace widely employed commercial products with significant economic and technical benefits, this study offers an original perspective on open challenges in sol–gel material science and technology. The applications discussed were selected on the basis of their societal and economic relevance and do not intend to represent the field of sol–gel material in general. The conclusions, however, are of general value and will hopefully aid young researchers and new companies to succeed in their efforts to commercialize chemical innovations based on sol–gel-derived functional materials.
Highlights
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Focusing on three different applications of sol–gel functional materials, this study offers an original perspective on open challenges in sol–gel science and technology.
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Technical and economic obstacles have limited the industrial uptake of sol–gel functional products to replace conventional products generally based on polymers.
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For silica-based sol–gel functional products to become ubiquitous in fields today dominated by polymers, the direct route to obtain silicon alkoxides from waste organic (or inorganic) silica must be commercialized on large scale.
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References
Levy D, Zayat M (eds) (2015) The sol–gel handbook. Wiley-VCH, Weinheim
Klein L, Aparicio M, Jitianu A (eds) (2018) Handbook of sol–gel science and technology. Springer International Publishing, Cham (Switzerland)
Sukka S (2018), History of the sol-gel chemistry and technology. In Klein L, Aparicio M, Jitianu A (eds), Handbook of sol-gel science and technology. Springer International Publishing, Cham (Switzerland), pp.3–29
Zelinski BJJ, Brinker CJ, Clark DE, Ulrich DR (eds) (1990). See for example the proceedings of the symposium held April 16–20 1990 in San Francisco. Better ceramics through chemistry IV, Materials Research Society, Pittsburgh, PA
Pillai SC, Hehir S (eds) (2017), Sol-gel materials for energy, environment and electronic applications. In: Aegerter M, Prassas M (series eds) Advances in sol-gel derived materials and technologies. Springer Nature Switzerland, Cham
Arenillas A, Menéndez JA, Reichenauer G, Celzard A, Fierro V, Maldonado Hodar FJ, Bailόn-Garcia E, Job N (2019) Organic and carbon gels. In: Aegerter M, Prassas M (Series eds) Advances in sol-gel derived materials and technologies. Springer Nature Switzerland, Cham
Almeida R, Martucci A, Santos L, Rojas Hernández RE (eds) (2020) Sol-gel derived optical and photonic materials, Woodhead Publishing, Sawston (UK)
Pierre AC (2020) Introduction to sol-gel processing. Springer Nature, Switzerland, Cham
Mordor Intelligence (2021) Sol-gel coatings market—segmented by product type, end-user industry, and geography—growth, trends, COVID-19 Impact, and Forecasts (2021–2026), Hyderabad
Search carried out on March 3, 2021, using the search term “sol-gel” on the website accessible at the https://patents.google.com/
Bartlett J (2020) Sol-gel science and technology—the microstructure of our community, ISGS Newsletter. https://www.isgs.org/wp-content/uploads/2020/06/ISGS-Newsletter-2020-06-Final.pdf
Mordor Intelligence (2021) Sol-gel products market—segmented by product type, end-user industry, and geography—growth, trends, COVID-19 impact, and forecasts (2021–2026), Hyderabad. https://www.mordorintelligence.com/industry-reports/sol-gel-products-market Accessed 4 Mar 2021
Choi D, Kumta PN (2007) Surfactant based sol–gel approach to nanostructured LiFePO4 for high rate Li-ion batteries. J Power Sour 163:1064–1069
Ciriminna R, Albo Y, Pagliaro M (2020) Sol-gel nanocoatings to functionalize fibers and textiles: a critical perspective. ChemistrySelect 5:9776–9780
Haufe H, Muschter K, Siegert J, Böttcher H (2008) Bioactive textiles by sol–gel immobilised natural active agents. J Sol–Gel Sci Technol 45:97–101
Nano4Life Europe, Nano4 Textile, Agios Dimitrios (Greece). https://www.nano4life.co/product-page/325050070-nano4-textile-500ml Accessed 4 Mar 2021
NewPro, NewPro Nano Textile 4NC, Monheim a. Rhein (Germany). https://www.newpro.de/en/newpro-nano-textile.html Accessed 4 Mar 2021
Markets and Markets (2020) Silicone market by type (elastomers, fluids, resins, gels), end-use industry (industrial process, building & construction, personal care & consumer products, transportation, electronics, medical & healthcare, energy). Region—Global Forecasts to 2025, Northbrook, IL
Ciriminna R, Fidalgo A, Béland F, Pandarus V, Ilharco LM, Pagliaro M (2013) The sol–gel route to advanced silica-based materials and recent applications. Chem Rev 113:6592–6620
For 99.5% TEOS sold by Shanghai Ruizheng Chemical Technology. See at the URL: https://www.alibaba.com/product-detail/Hot-selling-high-quality-low-price_1600187884554.html?spm=a2700.7724857.normal_offer.d_title.121965f9Fm3qdV Accessed 4 Mar 2021
Laine RM, Furgal JC, Doan P, Pan D, Popova V, Zhang X (2016) Avoiding carbothermal reduction: distillation of alkoxysilanes from biogenic, green, and sustainable sources. Angew Chem Int Ed 55:1065
Fukaya N, Jib Choi S, Horikoshi T, Kataoka S, Endo A, Kumai H, Hasegawa M, Sato K, Cho J-C (2017) Direct synthesis of tetraalkoxysilanes from silica and alcohols. N J Chem 41:2224–2226
Putro WS, Fukaya K, Choi J-C, Choi SJ, Horikoshi T, Sato K, Fukaya N (2020) Direct transformation of silica from natural resources to form tetramethoxysilane. Bull Chem Soc Jpn 93:958–962
Castricum HL, Kreiter R, van Veen HM, Blank DHA, Vente JF, ten Elshof JE (2008) High-performance hybrid pervaporation membranes with superior hydrothermal and acid stability. J Membr Sci 324:111–118
ECN grants Pervatech a licence to commercialise HybSi membrane technology (2010) Membrane technologies 2010(8):1
Energy research Centre of the Netherlands, ECN presents the revolutionary HybSi membrane that allows you to save up to 50% of energy and costs, increase product quality and reduce side products of separation processes significantly, https://www.hybsi.com Accessed 9 Mar 2021
ten Elshof JE (2016) Hybrid materials for molecular sieves. In: Klein L, Aparicio M, Jitianu A (eds) Handbook of sol–gel science and technology. Springer International Publishing Switzerland, Cham. pp.1–27
Wang J, Tanuwidjaja D, Bhattacharjee S, Edalat A, Jassby AD, Hoek DEMV (2020) Produced water desalination via pervaporative distillation. Water 12:3560
Raza W, Yang J, Wang J, Saulat H, He G, Lu J, Zhang Y (2020) HCl modification and pervaporation performance of BTESE membrane for the dehydration of acetic acid/water mixture. Sep Purif Technol 235:116102
Brüschke HEA (2001) State-of-art of pervaporation processes in the chemical industry. In Nunes SP, Peinemann K-V (eds) Membrane technology in the chemical industry, Wiley-VCH, Weinheim. pp. 127–172
Ren T (2009) Barriers and drivers for process innovation in the petrochemical industry: a case study. J Eng Technol Manag 26:285–304
Raza W, Wang J, Yang J, Tsuru T (2021) Progress in pervaporation membranes for dehydration of acetic acid. Sep Purif Technol 262:118338
Sigma-Aldrich. 1,2-bis(trimethoxysilyl)ethane https://www.sigmaaldrich.com/catalog/product/aldrich/447242?lang=it®ion=IT Accessed 10 Mar 2021
Puputti J, Jin H, Rosenholm J, Jiang H, Lindén M (2009) The use of an impure inorganic precursor for the synthesis of highly siliceous mesoporous materials under acidic conditions. Microporous Mesoporous Mater 126:272–275
Kaya GG, Deveci H (2020) Synergistic effects of silica aerogels/xerogels on properties of polymer composites: a review. J Ind Eng Chem 89:13–27
Pandarus V, Ciriminna R, Béland F, Pagliaro M, Kaliaguine S (2017) Solvent-free chemoselective hydrogenation of squalene to squalane. ACS Omega 2:3989–3996
Ciriminna R, Pandarus V, Béland F, Pagliaro M (2014) Catalytic hydrogenation of squalene to squalane. Org Process Res Dev 18:1110–1115
Pandarus V, Ciriminna R, Gingras G, Béland F, Pagliaro M, Kaliaguine S (2018) Hydrogenolysis of C–O chemical bonds of broad scope mediated by a new spherical sol–gel catalyst. ChemistryOpen 7:80–91
Ciriminna R, Palmisano G, Pagliaro M (2010) Shape and structural effects in silica-based functional materials. Chem Rec 10:17–28
Jhung SH, Romanenko AV, Lee KH, Park YS, Moroz EM, Likholobov VA (2002) Carbon-supported palladium-ruthenium catalyst for hydropurification of terephthalic acid. Appl Catal A 225:131–139
Pandarus V, Ciriminna R, Gingras G, Béland F, Pagliaro M, Kaliaguine S (2019) Waste-free and efficient hydrosilylation of olefins. Green Chem 21:129–140
Garcia S, Poulston S, Stavarek P (2021) Ni-free hydrogenation of natural products for the personal care industry: case study, squalene hydrogenation. In: Kaliaguine S, Dubois J-L (eds), Industrial green chemistry. de Gruyter, Berlin, pp. 115–138
Pandarus V, Gingras G, Béland F, Ciriminna R, Pagliaro M (2012) Selective hydrogenation of vegetable oils over SiliaCat Pd(0). Org Process Res Dev 16:1307–1311
Vásquez-Céspedes S, Betori RC, Cismesia MA, Kirsch JK, Yang Q (2021) Heterogeneous catalysis for cross-coupling reactions: an underutilized powerful and sustainable tool in the fine chemical industry? Org Process Res Dev https://doi.org/10.1021/acs.oprd.1c00041
Scurria A, Pagliaro M, Ciriminna R (2021) Quick, convenient, and clean: advancing education in green chemistry and nanocatalysis using sol-gel catalysts under flow. Preprints https://doi.org/10.20944/preprints202104.0027.v1
Ciriminna R, Pagliaro M, Luque R (2021) Heterogeneous catalysis under flow for the 21st century fine chemical industry, Green Energy Environ https://doi.org/10.1016/j.gee.2020.09.013
Pagliaro M (2021) Catalysis: a unified approach»: a new course in catalysis science and technology. J Flow Chem 11:53–58
Lapidot N, Gans O, Biagini F et al. (2003) Advanced sunscreens: UV absorbers encapsulated in sol-gel glass microcapsules. J Sol–Gel Sci Technol 26:67–72
Pandarus V, Ciriminna R, Béland F, Pagliaro M (2020) Making fine chemicals, nanomaterials and pharmaceutical ingredients over over SiliaCat catalysts. Appl Mater Today 20:100661
Oyola-Rivera O, He J, Huber GW, Dumesic JA, Cardona-Martínez N (2019) Catalytic dehydration of levoglucosan to levoglucosenone using Brønsted solid acid catalysts in tetrahydrofuran. Green Chem 21:4988–4999
Park B (2020) Twyneo under review for acne vulgaris, MPR. https://www.empr.com/home/news/drugs-in-the-pipeline/twyneo-fixed-dose-combination-tretinoin-retinoid-benzolyl-peroxide/ Accessed 10 Mar 2021
Laine RM (2021) Personal correspondence with M.P
Pagliaro M (2019) An industry in transition: the chemical industry and the megatrends driving its forthcoming transformation. Angew Chem Int Ed 58:11154–11159
Global Industry Analysts (2020) Global sol–gel coatings industry, San Jose, CA
Acknowledgements
Thanks to Professor Richard M. Laine, University of Michigan, for helpful correspondence. This article is dedicated to Professor Horst Böttcher, formerly at Dresden’s GMBU, on the occasion of his 80th birthday.
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RC and MP conceived the study. MP wrote the first draft of this study. RC reviewed the manuscript.
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Ciriminna, R., Pagliaro, M. Open challenges in sol–gel science and technology. J Sol-Gel Sci Technol 101, 29–36 (2022). https://doi.org/10.1007/s10971-021-05535-9
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DOI: https://doi.org/10.1007/s10971-021-05535-9