Skip to main content

Advertisement

SpringerLink
Log in

Research on the relationship between structure and properties of the soluble polyaryl ether ketone terminated with phthalonitrile

  • ORIGINAL PAPER
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

A novel soluble poly(aryl ether ketone) (PAEK) terminated with 4-nitrophthalonitrile was designed and synthesized, which was used to solve the problem of difficult solution processing. Then, a series of cross-linked PAEK films with different thermal treatment temperatures were fabricated by using 4,4-bis(3,4-dicyanophenoxy)biphenyl (BPH) as a novel cross-linking agent, improving the glass transition temperature (Tg) of the traditional PAEK. Then, the fourier transform infrared (FT-IR) spectrum, X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), dynamic mechanical analysis (DMA), mechanical testing machine and LCR meter were used to investigate the microstructure, thermal, mechanical and dielectric properties of PAEK films, respectively. The results indicated that the increase in heat-treatment time and temperature are beneficial for the improvement of the value of Tg and T5%, and the excellent thermal stability and mechanical properties of PAEK films are demonstrated. Compared to PAEK-1 film, the Tg and T5% both increased by 63 °C for PAEK-4 film. Significantly, the tensile strength of PAEK-3 film (42 MPa) reaches the highest value in comparison with other samples. In addition, the dielectric constants (ε) and loss tangent (tan δ) of PAEK-4 film is as low as 3.67 and 0.001 at 1 kHz, respectively. More importantly, the dielectric properties are found to be relatively stable to near the Tg value, which can be widely used for applications in dielectric energy storage at high temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Scheme 3
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Xu YX, Yang JS, Ye NY, Teng M, He RH (2015) Modification of poly(aryl ether ketone) using imidazolium groups as both pendants and bridging joints for anion exchange membranes. Eur Polym J 73:116–126

    Article  CAS  Google Scholar 

  2. Harsha AP, Wäsche R (2018) Influence of temperature on friction and wear characteristics of polyaryletherketones and their composites under reciprocating sliding condition. J Mater Eng Perform 27(10):5438–5449

    Article  CAS  Google Scholar 

  3. Panda JN, Bijwe J, Pandey RK (2017) Comparative potential assessment of solid lubricants on the performance of poly aryl ether ketone (PAEK) composites. Wear 384-385:192–202

    Article  CAS  Google Scholar 

  4. Ni CJ, Wang HB, Zhao Q, Liu BJ, Sun ZY, Zhang MY, Hu W, Liang L (2018) Crosslinking effect in nanocrystalline cellulose reinforce sulfonated poly(aryl ether ketone) proton exchange membranes. Solid State Ionics 323:5–15

    Article  CAS  Google Scholar 

  5. Garcia-Gonzalez D, Rusinek A, Jankowiak T, Arias A (2015) Mechanical impact behavior of polyether–ether–ketone (PEEK). Compos Struct 124:88–99

    Article  Google Scholar 

  6. Lu T, Wen J, Qian S, Cao HL, Ning CQ, Pan XX, Jiang XQ, Liu XY, Chu PK (2015) Enhanced osteointegration on tantalum-implanted polyetheretherketone surface with bone-like elastic modulus. Biomater 51:173–183

    Article  CAS  Google Scholar 

  7. Silva Burgal JD, Peeva LG, Kumbharkar S, Livingston A (2015) Organic solvent resistant poly(ether-ether-ketone) nanofiltration membranes. J Membr Sci 479:105–116

    Article  Google Scholar 

  8. Goyal R, Tiwari A, Mulik U, Negi Y (2007) Novel high performance Al2O3/poly(ether ether ketone) nanocomposites for electronics applications. Compos Sci Technol 67(9):1802–1812

    Article  CAS  Google Scholar 

  9. Kalin M, Zalaznik M, Novak S (2015) Wear and friction behaviour of poly-ether-ether-ketone (PEEK) filled with graphene, WS2 and CNT nanoparticles. Wear 332-333:855–862

    Article  CAS  Google Scholar 

  10. Díez-Pascual AM, Naffakh M, Marco C, Ellis G, Gómez-Fatou MA (2012) High-performance nanocomposites based on polyetherketones. Prog Mater Sci 57(7):1106–1190

    Article  Google Scholar 

  11. Najeeb S, Zafar MS, Khurshid Z, Siddiqui F (2016) Applications of polyetheretherketone (PEEK) in oral implantology and prosthodontics. J Prosthodont Res 60(1):12–19

    Article  Google Scholar 

  12. Liu TX, Mo ZS, Zhang HF (1998) Isothermal and nonisothermal melt crystallization kinetic behavior of poly(aryl ether biphenyl ether ketone ketone): PEDEKK. J Polym Eng 18(4):283–299

    CAS  Google Scholar 

  13. Ligot S, Bousser E, Cossement D, Klemberg-Sapieha J, Viville P, Dubois P, Snyders R (2015) Correlation between mechanical properties and cross-linking degree of ethyl lactate plasma polymer films. Plasma Process Polym 12(6):508–518

    Article  CAS  Google Scholar 

  14. Pu ZJ, Huang X, Chen L, Yang J, Tang HL, Liu XB (2013) Effect of nitrile-functionalization and thermal cross-linking on the dielectric and mechanical properties of PEN/CNTs–CN composites. J Mater Sci - Mater Electron 24(8):2913–2922

    Article  CAS  Google Scholar 

  15. Tang HL, Huang X, Yang XL, Yang J, Zhao R, Liu XB (2012) An effective approach to enhance temperature independence of dielectric properties for polyarylene ether nitrile films. Mater Lett 75:218–220

    Article  CAS  Google Scholar 

  16. Tong LF, Pu ZJ, Huang X, Chen ZR, Yang XL, Liu XB (2013) Cross-linking behavior of polyarylene ether nitrile terminated with phthalonitrile (PEN-t-Ph)/1,3,5-tri-(3,4-dicyanophenoxy) benzene (TPh) system and its enhanced thermal stability. J Appl Polym Sci 130(2):1363–1368

    Article  CAS  Google Scholar 

  17. Yang RQ, Wei RB, Li K, Tong LF, Jia K, Liu XB (2016) Cross-linked polyarylene ether nitrile film as flexible dielectric materials with ultrahigh thermal stability. Sci Rep 6:36434

    Article  Google Scholar 

  18. Liu T, Wang YP, Su Y, Yu HY, Zhao N, Yang YH, Jiang ZH (2015) Preparation and properties of film materials of poly(aryl ether ketone)-based phthalonitrile resins. Polym Eng Sci 55(10):2313–2321

    Article  CAS  Google Scholar 

  19. Wei RB, Tu L, You Y, Zhan CH, Wang YJ, Liu XB (2019) Fabrication of cross-linked single-component polyarylene ether nitrile composite with enhanced dielectric properties. Polym 161:162–169

    Article  CAS  Google Scholar 

  20. Rezania J, Shockravi A, Vatanpour V, Ehsani M (2019) Preparation and performance evaluation of carboxylic acid containing polyamide incorporated microporous ultrafiltration PES membranes. Polym Adv Technol 30(2):407–416

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors wish to thank for the Sichuan University of Science and Engineering Talent Introduction Project (No.2016RCL35), Opening Project of Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities (2018JXY04) and Major Project of Education Department in Sichuan (18ZA0346).

Author information

Author notes

  1. Yuhan Tian and Zejun Pu contributed equally to this work.

Authors and Affiliations

  1. College of Materials Science and Engineering, Material Corrosion and Protection Key Laboratory of Sichuan province, Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities, Sichuan University of Science & Engineering, Zigong, 643000, China

    Yuhan Tian, Zejun Pu, Jialing Xia, Linqing Hu, Jie Cheng & Jiachun Zhong

Authors
  1. Yuhan Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zejun Pu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jialing Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Linqing Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jie Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jiachun Zhong
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Besides, all the authors approved the final version of the manuscript.

Corresponding authors

Correspondence to Zejun Pu or Jiachun Zhong.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Yuhan Tian and Zejun Pu are the co-first author.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tian, Y., Pu, Z., Xia, J. et al. Research on the relationship between structure and properties of the soluble polyaryl ether ketone terminated with phthalonitrile. J Polym Res 26, 252 (2019). https://doi.org/10.1007/s10965-019-1933-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-019-1933-z

Keywords

Search

Navigation