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Thermodynamic and Physicochemical Studies of Binary Mixtures of 1-Propoxy-2-Propanol with Amines at Different Temperatures

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Abstract

In the present study, intermolecular interactions for binary liquid mixtures of 1-propoxy-2-propanol with amines namely diisopropylamine, dibutylamine and tributylamine have been examined through experimentally measured values of density (\(\rho\)), speed of sound (u) and viscosity (\(\eta\)). Measurements were carried out over entire the composition range and temperature range from 298.15 to 308.15 K. Various excess and deviation parameters have been calculated using measured data. These excess and deviation properties have been discussed in terms of intermolecular interactions in the mixtures. The presence of strong intermolecular interactions among unlike molecules in binary mixtures of 1-propoxy-2-propanol with diisopropylamine and dibutylamine while weak interactions in case of tributylamine have been revealed by these properties. Excess and deviation properties have been correlated with composition using Redlich–Kister polynomial. The Jouyban–Acree model was used to correlate the measured data with composition. Further, studies on Fourier-transform infrared spectroscopy were also carried out at room temperature.

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Acknowledgements

One of the authors (Likhish Dhingra) wish to acknowledge University Grant Commission (U.G.C.), New Delhi, India for their financial support in the form of Senior Research Fellowship via Letter no. 20/12/2015(ii)EU-V dated 17-05-2016.

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, 136119, India

    Likhish Dhingra & Gyan Prakash Dubey

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  1. Likhish Dhingra
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Material preparation, data collection and analysis were performed by [LD]. The first draft of the manuscript was written by [LD]. Supervision and review of manuscript was performed by [GPD].

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Correspondence to Gyan Prakash Dubey.

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Dhingra, L., Dubey, G.P. Thermodynamic and Physicochemical Studies of Binary Mixtures of 1-Propoxy-2-Propanol with Amines at Different Temperatures. J Solution Chem 52, 1013–1032 (2023). https://doi.org/10.1007/s10953-023-01293-0

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