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Thermodynamic and Spectral Investigation of Binary Liquid Mixtures Of 2-Isopropoxy Ethanol with Amines at (298.15, 303.15 and 308.15) K

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Abstract

Experimental values of density (\(\rho\)), speed of sound (u) and viscosity (\(\eta\)) of binary mixtures of 2-isopropoxy ethanol with dipropylamine, diethylamine and triethylamine at temperatures (298.15, 303.15 and 308.15) K are reported. Various excess and deviation properties were calculated using these experimentally measured values. A stronger solute–solvent interaction compared to solute–solute or solvent–solvent interactions, due to formation of hydrogen bonding is confirmed by the trends of these parameters. The excess and deviation properties were correlated with composition using Redlich–Kister polynomial. Density, speed of sound and viscosity data were correlated to composition using Jouyban–Acree model. Further, change in enthalpy (\(\Delta {H}^{*}\)) and change in entropy (\(\Delta {S}^{*}\)) of viscous flow were calculated using the viscosity data. Various semi-empirical models of viscosity were tested. The correlation ability of tested models increases with increase in the number of adjustable parameters. FT-IR spectra of these mixtures also support the results obtained from calculated parameters.

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References

  1. Dubey, G.P., Sharma, M.: Thermodynamic and transport properties of binary liquid mixtures of 1-hexanol with hexadecane and squalane at 298.15, 303.15 and 308.15 K. Z. Phys. Chem. 223, 279–298 (2009)

    Article  CAS  Google Scholar 

  2. Dubey, G.P., Kumar, K.: Thermodynamic properties of binary liquid mixtures of diethylenetriamine with alcohols at different temperatures. Thermochim. Acta. 524, 7–17 (2011)

    Article  CAS  Google Scholar 

  3. Dubey, G.P., Kaur, P.: Thermodynamic and spectral studies of molecular interactions in binary liquid mixtures of 1-butoxy-2-propanol with 1-alcohols. J. Chem. Eng. Data. 60, 2232–2239 (2015)

    Article  CAS  Google Scholar 

  4. Li, X.X., Liu, Y.X., Wei, X.H.: Density, viscosity, and surface tension at 293.15 K and liquid–liquid equilibria from 301.15 K to 363.15 K under atmospheric pressure for binary mixtures of diethylene glycol diethyl ether+ water. J. Chem. Eng. Data 49, 1043–1045 (2004)

    Article  CAS  Google Scholar 

  5. Dubey, G.P., Kumar, K.: Volumetric and viscometric properties of binary liquid mixtures of ethylene glycol monomethyl ether + 1-hexanol, 1-octanol, and 1-decanol at temperatures T = (293.15, 298.15, 303.15, and 308.15) K. J. Chem. Eng. Data 55, 1700–1703 (2010)

    Article  CAS  Google Scholar 

  6. Redlich, O., Kister, A.T.: Algebric representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  7. Dubey, G.P., Dhingra, L.: Acoustic, volumetric, transport and spectral studies of binary liquid mixtures of 2-(2-butoxyethoxy) ethanol with amines at different temperatures. J. Chem. Thermodyn. 149, 1016161 (2020)

    Google Scholar 

  8. Dubey, G.P., Dhingra, L.: Molecular interactions in binary liquid mixtures of 1-propoxy-2-propanol with amines at (298.15, 303.15 and 308.15)K: A thermophysical and spectroscopic approach. J. Mol. Liq. 318, 114072 (2020)

    Article  CAS  Google Scholar 

  9. Dubey, G.P., Dhingra, L.: Excess thermodynamic properties and FT-IR studies of binary mixtures of 2-butoxy ethanol + amines at different temperatures. J. Chem. Thermodyn. 157, 106388 (2021)

    Article  CAS  Google Scholar 

  10. Dubey, G.P., Dhingra, L.: Theoretical interpretation of thermophysical properties and their correlation with intermolecular interactions in binary liquid mixtures of 2-(2-butoxyethoxy) ethanol with amines. Int. J. Thermophys. 42, 156 (2021)

    Article  CAS  Google Scholar 

  11. Kiyohara, O., Benson, G.C.: Ultrasonic speeds and isentropic compressibilties of n- alkanol + n- heptane mixtures at 298.15 K. J. Chem. Thermodyn. 11, 861–873 (1979)

    Article  CAS  Google Scholar 

  12. Douheret, G., Davis, M.I., Loya, J.: Ultrasonic speeds and isentropic functions of 2-(2-alkoxyethoxy)ethanol + water at 298.15 K. Thermochim. Acta 207, 313–328 (1992)

    Article  CAS  Google Scholar 

  13. Douheret, G., Viallard, A.J.: Chem. Phys. 80, 809–818 (1983)

    CAS  Google Scholar 

  14. Douheret, G., Holczer, M.B., Peryrelier, R., Davis, M.I.: Speeds of sound and excess volumetric properties of mixtures of water with 2- propanol and with ethylene glycol monoisopropyl ether at 298.15 K. J. Chem. Eng. Data 39, 868–872 (1994)

    Article  CAS  Google Scholar 

  15. Douheret, G., Pal, A., Davis, M.I.: Ultrasonic speeds and isentropic functions of (2-alkoxyethanol + water) at 298.15 K. J. Chem. Thermodyn. 22, 99–108 (1990)

    Article  CAS  Google Scholar 

  16. Checoni, R.F., Francesconi, A.Z.: Measurements of the molar heat capacities and excess molar heat capacities for acetonitrile + diethylamine or sec-butylamine mixtures at various temperatures and atmospheric pressure. J. Solution Chem. 36, 913–922 (2007)

    Article  CAS  Google Scholar 

  17. Goralski, P., Wasiak, M., Bald, A.: Heat capacities, speeds of sound, and isothermal compressibilities of some n-amines and tri-n-amines at 298.15 K. J. Chem. Eng. Data 47, 83–86 (2002)

    Article  CAS  Google Scholar 

  18. Oswal, S.L., Oswal, P., Gardas, R.L., Patel, S.G., Shinde, R.G.: Acoustic, volumetric, compressibility and refractivity properties and reduction parameters for the ERAS and Flory models of some homologous series. Fluid Phase Equilib. 216, 33–45 (2004)

    Article  CAS  Google Scholar 

  19. Gonzalez, J.A., Mozo, I., de la Fuente, I.G., Cobos, J.C., Riesco, N.: Thermodynamics of mixtures containing alkoxyethanols. Part XXIII. Speed of sound prediction and ultrasonic studies of hydroxyether + organic solvent mixtures. Phys. Chem. Liq. 46, 390–407 (2008)

    Article  CAS  Google Scholar 

  20. Grunberg, L., Nissan, A.: Mixture law for Viscosity. Nature 164, 799–800 (1949)

    Article  CAS  PubMed  Google Scholar 

  21. Tamura, M., Kurata, M.: On the viscosity of binary mixture of liquids. Bull. Chem. Soc. Jpn. 25, 32–38 (1952)

    Article  Google Scholar 

  22. Katti, P.K., Chaudhri, M.M.: Viscosities of binary mixtures of benzyl acetate with dioxane, aniline, and m-cresol. J. Chem. Eng. Data 9, 442–443 (1964)

    Article  CAS  Google Scholar 

  23. Hind, R.K., McLaughlin, E., Ubbelohde, A.R.: Structure and viscosity of liquids. Camphor + pyrene. Trans. Faraday Soc. 56, 328–330 (1960)

    Article  CAS  Google Scholar 

  24. McAllister, R.A.: The viscosity of liquid mixtures. AIChE J. 6, 427–431 (1960)

    Article  CAS  Google Scholar 

  25. Heric, E.L.: On the viscosity of ternary mixtures. J. Chem. Eng. Data 11, 66–68 (1966)

    Article  CAS  Google Scholar 

  26. Pal, A., Bhardwaj, R.K.: Excess molar volumes and viscosities for binary mixtures of 2-propoxyethanol and of 2-isopropoxyethanol with propylamine and dipropylamine at (298.15, 308.15, and 318.15) K. J. Chem. Eng. Data 46, 933–938 (2000)

    Article  Google Scholar 

  27. Eyring, H., John, M.S.: Significant Liquid Structures. John Wiley & Sons, New York (1969)

    Google Scholar 

  28. Eyring, H.: Viscosity, plasticity and diffusion as examples of absolute reaction rates. J. Chem. Phys. 4, 283–289 (1936)

    Article  CAS  Google Scholar 

  29. Nain, A.K.: Molecular interactions in binary mixtures of formamide with 1-butanol, 2-butanol, 1,3-butanediol and 1,4-butanediol at different temperatures: An ultrasonic and viscometic study. Fluid Phase Equilib. 265, 46–56 (2008)

    Article  CAS  Google Scholar 

  30. Fort, R.J., Moore, W.R.: Viscosities of binary liquid mixtures. Trans. Faraday Soc. 62, 1112–1119 (1966)

    Article  CAS  Google Scholar 

  31. Postigo, M., Mariano, A., Mussari, L., Canzonieri, S.: Viscosities for binary mixtures of 1-decanol, hexane, and diethylamine at 10, 25, and 40 °C. J. Solution Chem. 30, 1081–1090 (2002)

    Article  Google Scholar 

  32. Letcher, T.M.: Thermodynamics of aliphatic amine mixtures I. The excess volumes of mixing for primary, secondary, and tertiary aliphatic amines with benzene and substituted benzene compounds. J. Chem. Thermodyn. 4, 159–173 (1972)

    Article  CAS  Google Scholar 

  33. Kinart, C.M., Kinart, W.J., Cwiklinska, A., Klimczak, M., Kinart, A.: Speed of sound of some aliphatic amines with 2-methoxyethanol mixtures at 298.15 K. Phy. Chem. Liq. 44, 167–172 (2006)

    Article  CAS  Google Scholar 

  34. Alonso, I., Alonso, V., Mozo, I., de la Fuente, I.G., Gonzalez, J.A., Cobos, J.C.: Thermodynamics of ketone + amine mixtures: Part II. Volumetric and speed of sound data at (293.15, 298.15 and 303.15) K for 2-propanone + dipropylamine, + dibutylamine or + triethylamine systems. J. Mol. Liq. 155, 109–114 (2010)

    Article  CAS  Google Scholar 

  35. Shakila, A., Ravikumar, S., Pandiyan, V., Gaba, R.: Influence of temperature on thermo physical properties of binary mixtures of ethyl acrylate and alkyl amines: An experimental and theoretical approach. J. Mol. Liq. 265, 544–555 (2018)

    Article  CAS  Google Scholar 

  36. Oswal, S.L., Shinde, R.G., Patel, A.T., Dave, J.P., Patel, S.G., Patel, B.M.: Study of viscosity of mono-, di-, and trialkylamines. Int. J. Thermophys. 13, 617–628 (1992)

    Article  CAS  Google Scholar 

  37. Li, D., Fang, W.: Thermodynamic study of binary mixtures of tricycle [5.2.1.02.6] decane with N-methylpiperazine or triethylamine at T = 298.15–323.15 K. Thermochim. Acta 544, 38–42 (2012)

    Article  CAS  Google Scholar 

  38. Kumar, A., Prakash, O., Prakash, S.: Ultrasonic velocities, densities, and viscosities of triethylamine in methanol, ethanol, and 1-propanol. J. Chem. Eng. Data 26, 64–67 (1981)

    Article  CAS  Google Scholar 

  39. Shah, J.K., Dewitt, K.J., Stoops, C.E.: Viscosity–temperature correlation for liquid aliphatic amines. J. Chem. Eng. Data 14, 333–335 (1969)

    Article  CAS  Google Scholar 

  40. Alonso, I., Mozo, I., de la Fuente, I.G., Gonzalez, J.A., Cobos, J.C.: Thermodynamics of (ketone + amine) mixtures. Part VI. Volumetric and speed of sound data at (293.15, 298.15, and 303.15) K for (2-heptanone + dipropylamine, +dibutylamine, or +triethylamine) systems. Thermochim. Acta 43, 1506–1514 (2011)

    Google Scholar 

  41. Partibha, Kumar, K., Gahlyan, S., Rani, M., Bhankar, V.: Measurement and correlation of thermodynamic properties of amine and esters. J. Mol. Liq. 259, 167–178 (2018)

  42. Reghem, P., Baylaucq, A., Comunas, M.J.P., Fernandez, J., Boned, C.: Influence of the molecular structure on the viscosity of some alkoxyethanols. Fluid Phase Equilib. 236, 229–236 (2005)

    Article  CAS  Google Scholar 

  43. Dhondge, S.S., Pandhurnekar, C.P., Parwate, D.V.: Density, speed of sound, and refractive index of aqueous binary mixtures of some glycol ethers at T = 298.15 K. J. Chem. Eng. Data 55, 3962–3968 (2010)

    Article  CAS  Google Scholar 

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Acknowledgements

One of the authors (Likhish Dhingra) wish to acknowledge University Grant Commission (U.G.C.), New Delhi, India for their financial support in the form of Junior Research Fellowship via Letter no. 20/12/2015(ii)EU-V dated 17-05-2016.

Funding

This work was supported by the University Grants Commission [20/12/2015(ii)EU-V dated 17–05-2016].

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, 136119, Haryana, India

    Gyan Prakash Dubey & Likhish Dhingra

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  1. Gyan Prakash Dubey
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  2. Likhish Dhingra
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GPD: Conceptualization, Validation, investigation, Resources, Writing- Review & Editing, Supervision. LD: Conceptualization, Resources, Writing- original draft preparation, Visualization, Funding acquisition.

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Correspondence to Gyan Prakash Dubey.

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Dubey, G.P., Dhingra, L. Thermodynamic and Spectral Investigation of Binary Liquid Mixtures Of 2-Isopropoxy Ethanol with Amines at (298.15, 303.15 and 308.15) K. J Solution Chem 51, 135–166 (2022). https://doi.org/10.1007/s10953-021-01136-w

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