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In situ construction of porous Ni/Co-MOF@Carbon cloth electrode with honeycomb-like structure for high-performance energy storage

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Abstract

Porous Ni/Co-organic framework with honeycomb-like structure was directly grown on the carbon cloth (Ni/Co-MOF@CC) through a hydrothermal process. The Ni/Co-MOF@CC displayed a high specific surface area with an average pore size of 3.05 nm and excellent conductivity. The electrochemical performances of the porous Ni/Co-MOF@CC as the electrode of supercapacitors were evaluated using cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy measurements in 2 M KOH electrolyte. The Ni/Co-MOF@CC electrode exhibited a maximal specific capacity of 1180.5 mC cm−2 at 3 mA cm−2, good high-rate discharge ability (624.1 mC cm−2 at 60 mA cm−2), and long-term cycling life (97.6% capacity retention after 5000 cycles). Our experiments demonstrated the practical application of mixed-MOFs as supercapacitors for next-generation energy storage devices.

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Authors and Affiliations

  1. School of Materials and Energy, University of Electronic Science & Technology of China, Chengdu, 610054, People’s Republic of China

    Yunjian Chen, Ni Wang & Wencheng Hu

  2. Materials Research Institute, Department of Ecosystem Science and Management, 204 Energy and the Environment Laboratory, The Pennsylvania State University, University Park, State College, PA, 16802, USA

    Ni Wang & Sridhar Komarneni

Authors
  1. Yunjian Chen
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  2. Ni Wang
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  3. Wencheng Hu
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  4. Sridhar Komarneni
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Correspondence to Ni Wang or Sridhar Komarneni.

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Chen, Y., Wang, N., Hu, W. et al. In situ construction of porous Ni/Co-MOF@Carbon cloth electrode with honeycomb-like structure for high-performance energy storage. J Porous Mater 26, 921–929 (2019). https://doi.org/10.1007/s10934-019-00735-9

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