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Unique Properties of Novel Binary P(Py-co-OT)/MFe2O4 (M = Ni, Cu, and Co) Nanocomposites for Renewable Energy Storage Applications

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Abstract

In this work, novel nanocomposites (NCs) were fabricated via in situ-chemical oxidative polymerization process. For the purpose of examining their physical and chemical properties, the synthesized samples were examined utilizing a variety of analytical techniques. XRD, TEM, SEM, electrical and dielectric studies confirm the presence of copolymer P(Py-co-OT) and reveal that MFe2O4@P(Py-co-OT)NCs exhibited a core–shell structure. The Poly (Pyrrole-co-o-toluidine) possessed the highest activation energy and the lowest conductivity. Moreover, the incorporation of MFe2O4 into copolymer enhances the conductivity. Impedance analysis emphasizes the contribution of grain boundaries on transport properties. A relationship between the polarization effect and the dielectric behavior was found. An enhancement on the dielectric constant εʹ and the dielectric loss ε″ was noticed with the embedding of spinel ferrites into copolymer. Results obtained suggest that this binary material has a promise for use in energy conversion applications.

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References

  1. T.M. Akel, S. Pienimaa, T. Taka, S. Jussila, H. Isotalo, Synth. Metals 85, 1335 (1997)

    Article  Google Scholar 

  2. X. Lu, H.Y. Ng, J. Xu, H. Chaobin, Synth. Metals 128, 167 (2002)

    Article  CAS  Google Scholar 

  3. J.Q. Kan, X.H. Pan, C. Chen, Biosens. Bioelectron. 19, 1635 (2004)

    Article  CAS  PubMed  Google Scholar 

  4. N. Ahmad, A.G. MacDiarmid, Synth. Metals 78, 103 (1996)

    Article  CAS  Google Scholar 

  5. T.L. Rose, S.D. Antonio, M.H. Jillson, A.B. Kron, R. Suresh, F. Wang, Synth. Metals 85, 1439 (1997)

    Article  CAS  Google Scholar 

  6. S.Y. Inkaya, T. Tuken, B. Yazici, M. Erbil, Progress Organic Coat. 63, 424 (2008)

    Article  Google Scholar 

  7. A.A. Farghali, M. Moussa, M.H. Khedr, J. Alloy, Comp. 499, 98 (2010)

    Article  CAS  Google Scholar 

  8. G.D. Prasanna, H.S. Jayanna, A.R. Lamani, S. Dash, Synth Met. 161, 2306 (2011)

    Article  CAS  Google Scholar 

  9. N.S. Gajbhiye, G. Balaji, S. Bhattacharyya, M. Ghafari, Hyperfine Interact. 156, 57 (2004)

    Article  Google Scholar 

  10. A.K. Giri, E.M. Kirkpartrick, P. Mongkhamllang, S.A. Majetich, Appl. Phys. Lett. 80, 2341 (2002)

    Article  CAS  Google Scholar 

  11. M.F. Hansen, S. Morup, J. Magn. Magn. Mater. 184, 262 (1998)

    Article  CAS  Google Scholar 

  12. C.V.G. Reddy, S.V. Manorama, V.J. Rao, Sens. Actuators B 55, 90 (1999)

    Article  Google Scholar 

  13. L. Satyanarayana, K.M. Reddy, S.V. Manoram, Mater. Chem. Phys. 82, 21 (2003)

    Article  CAS  Google Scholar 

  14. Z. Zi, Y. Sun, X. Zhu, Z. Yang, J. Dai, W. Song, J. Magn. Mater. 321(9), 1251–1255 (2009)

    Article  CAS  Google Scholar 

  15. A. Afkhami, H. Khoshsafar, H. Bagheri, T. Madrakian, Sens. Actuator B 203, 909–918 (2014)

    Article  CAS  Google Scholar 

  16. M. Sertkol, Y. Köseoglu, A. Baykal, H. Kavas, A.M.S. Bozkurt, M.S. Toprak, J. Alloys Compd. 486, 325 (2009)

    Article  CAS  Google Scholar 

  17. A. Timoumi, M.A. Wederni, N. Bouguila, B. Jamoussi, M.K. Al-Turkestani, R. Chakroun, B. Al-Mur, Synth. Metals 272, 116659 (2021)

    Article  CAS  Google Scholar 

  18. J. Koaib, N. Bouguila, H. Abassi, N. Moutia, M. Kraini, A. Timoumi, C. Vázquez-Vázquez, K. Khirouni, S. Alaya, RSC Adv. 10(16), 9549–9562 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. A. Timoumi, N. Bouguila, J. Koaib, M.K. Al-Turkestani, B. Jamoussi, Mater. Res. Express 6(5), 055103 (2019)

    Article  CAS  Google Scholar 

  20. A. Timoumi, Graphene 7(4), 31–38 (2018)

    Article  CAS  Google Scholar 

  21. B. Jamoussi, R. Chakroun, A. Timoumi, K. Essalah, Catalysts 10(8), 906 (2020)

    Article  CAS  Google Scholar 

  22. R. Nongjai, S. Khan, K. Asokan, H. Ahmed, I. Khan, J. Appl. Phys. 112, 084321 (2012)

    Article  Google Scholar 

  23. A.K. Jonscher, Nature 267, 673 (1977)

    Article  CAS  Google Scholar 

  24. M. Khairy, M.E. Gouda, J. Adv. Res 6, 555–562 (2015)

    Article  CAS  PubMed  Google Scholar 

  25. B. Viswanathan, V. Murthy, Ferrite Materials: Science and Technology (Springer, Berlin, 1990)

    Google Scholar 

  26. E.V. Gopalan, K.A. Malini, S. Sagar, D.S. Kumar, Y. Yoshida, I.A. Al-Omari, M.R. Anantharaman, J. Phys. D 42, 165005 (2009)

    Article  Google Scholar 

  27. S.R. Elliott, Philos. Mag. B 36, 1291 (1977)

    Article  CAS  Google Scholar 

  28. R. Lahouli, J. Massoudi, M. Smari, H. Rahmouni, K. Khirouni, E. Dhahri, L. Bessais, RSC Adv. 9, 19949 (2019)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  29. R.K. Panda, R. Muduli, S.K. Kar, D. Behera, J. Alloys Compd. 615, 899 (2014)

    Article  CAS  Google Scholar 

  30. M. Mubasher, M. Mumtaz, M. Hassan, L. Ali, Z. Ahmad, M.A. Imtiaz, M.F. Aamir, A. Reman, K. Nadeem, Appl. Phys. A 126, 334 (2020)

    Article  CAS  Google Scholar 

  31. C. Murugesan, L. Okrasa, G. Chandrasekaran, J. Mater. Sci. 28, 13168–13175 (2017)

    CAS  Google Scholar 

  32. I. Ahmad, M. Akhtar, R.T.A. Khan, M.M. Hasan, J. Appl. Phys. 114, 034103 (2013)

    Article  Google Scholar 

  33. V. Senthil, T. Badapanda, A. Chithambararaj, A.C. Bose, A.K. Mohapatra, S. Panigrahi, J. Polym. Res. 19, 9898–9906 (2012)

    Article  Google Scholar 

  34. M.M. El-Desoky, M.A. Ali, G. Afifi, H. Imam, M.S. Al-Assiri, SILICON 10, 301–307 (2018)

    Article  CAS  Google Scholar 

  35. P.V.B. Reddy, B. Ramesh, C.G. Reddy, Physica B 405, 1852–1856 (2010)

    Article  CAS  Google Scholar 

  36. M.C. Dimri, A. Verma, S.C. Kashyap, D.C. Dubea, O.P. Thakur, C. Prakash, Mater. Sci. Eng. 133, 42–48 (2006)

    Article  CAS  Google Scholar 

  37. H. Rahmouni, M. Smari, C. Boutheina, E. Dhahri, K. Khirouni, Dalton Trans. 44, 10457–10466 (2015)

    Article  CAS  PubMed  Google Scholar 

  38. X. Lu, W. Bian, C. Min, Z. Fu, Q. Zhang, H. Zhu, Ceram. Int. 44, 10028–10034 (2018)

    Article  CAS  Google Scholar 

  39. X. Lu, W. Bian, Y. Li, H. Zhu, Z. Fu, Q. Zhang, J. Am. Ceram. Soc. 101, 1646–1654 (2018)

    Article  CAS  Google Scholar 

  40. X.H. Wang, Z.L. Gui, L.T. Li, Mater. Chem. Phys. 55, 193–196 (1998)

    Article  CAS  Google Scholar 

  41. T.S. Sasikala, C. Pavithran, M.T. Sebastian, J. Mater. Sci. 21, 141–144 (2010)

    CAS  Google Scholar 

Download references

Acknowledgements

The authors extend their appreciation to the Deanship for Research & Innovation, Ministry of Education in Saudi Arabia for funding this research work through the Project Number: IFP22UQU4331172DSR150

Funding

The funding of this work from the Deanship for Research & Innovation, Ministry of Education in Saudi Arabia through the Project Number: IFP22UQU4331172DSR150.

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Authors and Affiliations

  1. Laboratoire de Physique des Matériaux et des Nanomatériaux Appliquée à l’Environnement, Université de Gabès, Cité Erriadh, Zrig, 6072, Gabès, Tunisia

    J. Koaib & N. Bouguila

  2. Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, P.O. Box 16722, Makkah, 21955, Saudi Arabia

    D. F. Katowah & Saleh A. Ahmed

  3. Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia

    D. F. Katowah

  4. Department of Physics, Faculty of Applied Science, Umm Al-Qura University, Makkah, 21955, Saudi Arabia

    A. Timoumi

  5. Chemistry Department, Faculty of Science, Assiut University, Assiut, 71516, Egypt

    Saleh A. Ahmed

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  1. J. Koaib
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  2. D. F. Katowah
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  3. A. Timoumi
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  4. N. Bouguila
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  5. Saleh A. Ahmed
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All authors share equally in writing the main manuscript, preparing the figures and reviewed the manuscript.

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Correspondence to A. Timoumi or Saleh A. Ahmed.

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Koaib, J., Katowah, D.F., Timoumi, A. et al. Unique Properties of Novel Binary P(Py-co-OT)/MFe2O4 (M = Ni, Cu, and Co) Nanocomposites for Renewable Energy Storage Applications. J Inorg Organomet Polym 33, 2270–2278 (2023). https://doi.org/10.1007/s10904-023-02659-z

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