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Effect of Bulk Doping on the Electrical Conductivity of Selected Metallocene Polyamines

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Abstract

The conductivity of the polyamine derived from titanocene dichloride and 2-nitro-1,4-phenylenediamine increases to 101 to 103 fold when doped with iodine. Larger increases are found for the analogous polyamines except derived from zirconocene dichloride (increased 103–104 fold) and hafnocene dichloride (105–106 fold) and for certain other diamines. The conductivity of the product of titanocene dichloride and N-methyl-1,4-phenylenediamine increased 105 fold when doped. By comparison, conductivity increased only tenfold for the product from titanocene dichloride and chloro-1,4-phenylenediamine and less for the titanocene product with 1,4-phenylenediamine and methoxy-1,4-phenylenediamine and none for the product from dibutyltin dichloride and 2-nitro-1,4-phenylenediamine. Conductivity did not appreciably change when samples were exposed to the atmosphere for 21 h. MALDI MS and IR results are consistent with the formation of C–I compounds for doped materials.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431, USA

    Charles E. Carraher Jr. & Amitabh J. Battin

  2. Department of Biology, University of Texas at Arlington, Arlington, TX, 76019, USA

    Michael R. Roner

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  1. Charles E. Carraher Jr.
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  2. Amitabh J. Battin
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  3. Michael R. Roner
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Correspondence to Charles E. Carraher Jr..

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Carraher, C.E., Battin, A.J. & Roner, M.R. Effect of Bulk Doping on the Electrical Conductivity of Selected Metallocene Polyamines. J Inorg Organomet Polym 23, 61–73 (2013). https://doi.org/10.1007/s10904-012-9696-6

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  • DOI: https://doi.org/10.1007/s10904-012-9696-6

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