Skip to main content

Advertisement

Log in

Bio-polymer poly(lactic acid) thin film-based K-ion-associated photo-rechargeable power cell

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

A very simple, low-cost and bio-compatible photo-induced K-ion-based power cell has been developed using an aqueous electrolyte solution of PVA-WO3-ZnO-K2HPO4 and poly(lactic acid) film. After investigation of the charging and discharging phenomenon the maximum open circuit voltage is obtained \(\sim\) 1 V under light intensity ~ 110 mW/cm2. Then the device is discharged with a constant discharge current density ~ 0.5 mA/cm2. The sturdiness of K-ion photo-power cell is also verified by observing the charging-discharging data repeatedly for 200 cycles. It shows \(\sim 16\) F/m2 storage capacity with energy density and power density \(\sim 2.22\) mWh/m2 and \(\sim\) 5 W/m2, respectively. A commercially available LED also driven by our fabricated power cell for showing its practical application possibilities.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

Data availability

The data in support of our findings of this study are available within the paper.

References

  1. C. Liu, F. Li, L.-P. Ma, H.-M. Cheng, Advanced materials for energy storage. Adv. Mater. 22, 28–62 (2010)

    Article  CAS  Google Scholar 

  2. N. Kannan, D. Vakeesan, Solar energy for future world: a review. Renew. Sustain. Energy Rev. 62, 1092–1105 (2016)

    Article  Google Scholar 

  3. B. Parida, S. Iniyan, R. Goic, A review of solar photovoltaic technologies. Renew. Sustain. Energy Rev. 15, 1625–1636 (2011)

    Article  CAS  Google Scholar 

  4. L. Gao, S. Chen, L. Zhang, X. Yang, High performance sodium ion hybrid supercapacitors based on Na2Ti3O7 nanosheet arrays. J. Alloys Compd. 766, 284–290 (2018)

    Article  CAS  Google Scholar 

  5. M.D. Slater, D. Kim, E. Lee, C.S. Jhonson, Sodium-ion batteries. Adv. Funct. Mater. 23, 947 (2013)

    Article  CAS  Google Scholar 

  6. S. Roy, P. Thakur, N.A. Hoque, B. Bagchi, N. Sepay, F. Khatun, A. Kool, S. Das, Electroactive and high dielectric folic acid/PVDF composite film rooted simplistic organic photovoltaic self-charging energy storage cell with superior energy density and storage capability. ACS Appl. Mater. Interfaces 9, 24198–24209 (2017)

    Article  CAS  Google Scholar 

  7. X. Zhang, X. Huang, C. Li, H. Jiang, Dye-sensitized solar cell with energy storage function through PVDF/ZnO nanocomposite counter electrode. Adv. Mater. 25(30), 4093–4096 (2013)

    Article  CAS  Google Scholar 

  8. Y. Yin, K. Feng, C. Liu, S. Fan, A polymer supercapacitor capable of self-charging under light illumination. J. Phys. Chem. C 119(16), 8488–8491 (2015)

    Article  CAS  Google Scholar 

  9. M. Zhou, P. Bai, X. Ji, J. Yang, C. Wang, Y. Xu, Electrolytes and interphases in potassium ion batteries. Adv. Mater. 33, 2003741 (2021)

    Article  CAS  Google Scholar 

  10. X.-Q. Zhang, T. Li, B.-Q. Li, R. Zhang, P. Shi, C. Yan, J.-Q. Huang, Q. Zhang, Sustainable solid electrolyte interphase enables high-energy density lithium metal batteries under practical conditions. Angew. Chem. Int. Ed. (2020). https://doi.org/10.1002/anie.20191172

    Article  Google Scholar 

  11. E. Lim, C. Jo, M.S. Kim, M.-H. Kim, J. Chun, H. Kim, J. Park, K.C. Roh, K. Kang, S. Yoon, J. Lee, High-performance sodium-ion hybrid supercapacitor based on Nb2O5@carbon core-shell nanoparticles and reduced graphene oxide nanocomposites. Adv. Funct. Mater. 26, 3711 (2016)

    Article  CAS  Google Scholar 

  12. B. Ji, W. Yao, Y. Zheng, P. Kidkhunthod, X. Zhou, S. Tunmee, S. Sattayaporn, H.-M. Cheng, H. He, Y. Tang, A fluoroxalate cathode material for potassium-ion batteries with ultra-long cyclability. Nat. Commun. (2020). https://doi.org/10.1038/s41467-020-15044-y

    Article  Google Scholar 

  13. A. Sultana, S.K. Ghosh, V. Sencadas, T. Zheng, M.J. Higgins, T.R. Middyaa, D. Mandal, Human skin interactive self-powered wearable piezoelectric bio-e-skin by electrospun poly-l-lactic acid nanofibers for non-invasive physiological signal monitoring. J. Mater. Chem. B 5, 7352 (2017)

    Article  CAS  Google Scholar 

  14. E. Fukada, Piezoelectricity of biopolymers. Biorheology 32, 593–609 (1995)

    CAS  Google Scholar 

  15. J. Kobayashi, T. Asahi, M. Ichiki, A. Oikawa, T. Suzuki, H.T. Watanabe, N. Shinjuku-ku, E. Fukada, Y. Shikinami, Structural and optical properties of poly lactic acids. J. Appl. Phys. 77, 2957–2973 (1995)

    Article  CAS  Google Scholar 

  16. Y. Ikada, Y. Shikinami, Y. Hara, M. Tagawa, E. Fukada (1996) Enhancement of bone formation by drawn poly(l-lactide). J. Biomed. Mater. Res. 30, 553–558 (1996)

    Article  CAS  Google Scholar 

  17. S. Kang, S.L. Hsu, D. Howard, S.P.B. Smith, M.A. Leugers, X. Yang, A spectroscopic analysis of poly(lactic acid) structure. Macromolecules 34, 4542–4548 (2001)

    Article  CAS  Google Scholar 

  18. D. Brizzolara, H.-J. Cantow, K. Diederichs, E. Keller, A.J. Domb, Mechanism of the stereocomplex formation between enantiomeric poly(lactide)s. Macromolecules 29, 191 (1996)

    Article  CAS  Google Scholar 

  19. D.A. Brant, A.E. Tonelli, P.J. Flory, The configurational statistics of random poly (lactic acid) chains II. Theory. Macromolecules 2, 228 (1969)

    Article  CAS  Google Scholar 

  20. F.A. Obrezkov, V. Ramezankhani, I. Zhidkov, V.F. Traven, E.Z. Kurmaev, K.J. Stevenson, A. Pavel, J. Troshin, High-energy and high-power-density potassium ion batteries using dihydrophenazine-based polymer as active cathode material. J. Phys. Chem. Lett. 10, 5440–5445 (2019)

    Article  CAS  Google Scholar 

  21. J.-Y. Hwang, S.-T. Myung, Y.-K. Sun, Recent progress in rechargeable potassium batteries. Adv. Funct. Mater. 28, 1802938 (2018)

    Article  CAS  Google Scholar 

  22. Y.-S. Xu, S.-Y. Duan, Y.-G. Sun, D.-S. Bin, X.-S. Tao, D. Zhang, Y. Liu, A.-M. Cao, L.-J. Wan, Recent developments in electrode materials for potassium-ion batteries. J. Mater. Chem. A 7, 4334–4352 (2019)

    Article  CAS  Google Scholar 

  23. A. Eftekhari, Potassium secondary cell based on Prussian Blue cathode. J. Power Sources 126, 221–228 (2004)

    Article  CAS  Google Scholar 

  24. Q. Sun, B.K. Rao, P. Jena, D. Stolcic, Y.D. Kim, G. Gantefor, A.W. Castleman, Appearance of bulk properties in small tungsten oxide clusters. J. Chem. Phys. 121, 9417–9422 (2004)

  25. F. Khatun, P. Thakur, N.A. Hoque, A. Kool, S. Roy, P. Biswas, B. Bagchi, S. Das, In situ synthesized SrF2/polyvinylidene fluoride nanocomposite film based photo-power cell with imperious performance and stability. Electrochim. Acta 282, 194–204 (2018)

    Article  CAS  Google Scholar 

  26. F. Khatun, P. Thakur, B. Bagchi, S. Das, Photo-charging polymeric sodium-ion cell based on YSZ/PVDF film. Appl. Phys. Lett. (2019). https://doi.org/10.1063/1.5123784

    Article  Google Scholar 

  27. P. Thakur, A. Kool, N.A. Hoque, B. Bagchi, F. Khatun, P. Biswas, D. Brahma, S. Roy, S. Banerjee, S. Das, Superior performances of in situ synthesized ZnO/PVDF thin film based selfpoled piezoelectric nanogenerator and self-charged photo-power bank with high durability. Nano Energy 44, 456–467 (2018)

    Article  CAS  Google Scholar 

  28. S.K. Mohapatra, N. Kondamudi, S. Banerjee, M. Misra, Functionalization of self-organized TiO2 nanotubes with Pd nanoparticles for photocatalytic decomposition of dyes under solar light illumination. Langmuir 24, 11276 (2008)

    Article  CAS  Google Scholar 

  29. J.A. Anta, E. Guillen, R. Tena-Zaera, ZnO-based dye-sensitized solar cells. J. Phys. Chem. C 116, 11413 (2012)

    Article  CAS  Google Scholar 

  30. K. Hou, B. Tian, F. Li, Z. Bian, D. Zhao, C. Huang, Highly crystallized mesoporous TiO2 films and their applications in dye sensitized solar cells. J. Mater. Chem. 15, 2414–2420 (2005)

    Article  CAS  Google Scholar 

  31. Y. Fu, H. Wu, S. Ye, X. Cai, X. Yu, S. Hou, H. Kafafya, D. Zou, Integrated power fiber for energy conversion and storage. Energy Environ. Sci. 6, 805–812 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Authors are thankful to the Science and Engineering Research Board (SERB), Government of India (Sanction Id: EEQ/2019/000340), for providing financial assistances.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Pradip Thakur.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (AVI 2004 kb)

Supplementary file2 (DOCX 22 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Molla, S., Khatun, F. & Thakur, P. Bio-polymer poly(lactic acid) thin film-based K-ion-associated photo-rechargeable power cell. J Mater Sci: Mater Electron 33, 1864–1870 (2022). https://doi.org/10.1007/s10854-021-07385-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-021-07385-1

Navigation