Abstract
In this work, Ni0.7−xZn0.3CoxFe2O4 (x = 0, 0.05, 0.10, 0.15 and 0.20, NZCF) ferrites were successfully fabricated by solid-state reaction method. We have been more focused on the effects of cobalt-substituted NiZn ferrite on crystal structure, microstructure and magneto-electric properties. With gradual addition of cobalt content, since the smaller ionic radius and larger atomic weight of the cobalt, which leads to decrease lattice parameter (a) and enhance X-ray density (dx), respectively. The grain size (D) increases (4.86 ± 1.10 to 6.26 ± 1.67 μm). When x = 0.05, the initial permeability (μi) of NiZnCo ferrites reaches the maximum value. The saturation magnetization (Ms) is firstly decreased slightly from 78.96 to 77.96 emu/g when x ≤ 0.10, then increased to 83.14 emu/g (x = 0.15), ultimately decreased to 81.54 emu/g. Meanwhile, the coercivity (Hc) is dropped from 19.95 to 13.25 Oe when x ≤ 0.05, and stabilized at about 13.40 Oe when x > 0.05. From the dielectric spectrum, the real dielectric constant (ε′) exhibits typical relaxation-dispersion behavior with increasing frequency. The resistivity temperature spectrum also shows good performance: both dc resistivity (ρ) and activation energy (Eρ) increase with the Co substitution. Here, we have developed a NiZnCo ferrite when Co-substituted x = 0.05 with the highest permeability (μi, 123@10 kHz), higher saturation magnetization (Ms, 78.25 emu/g) and lowest coercivity (Hc, 13.25Oe), which is expected to be used in high-frequency capacitors and inductors.
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Acknowledgements
This work was supported under the Project of Science and Technology Supporting Plan in Sichuan Province of China (2019YJ0354, 2019YJ0364), the National Natural Science Foundation of China Grant (51701025) and Research Found for Young Academic Leaders of CUIT Grant (J201710).
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Wu, XH., Tao, ZX., Li, LZ. et al. Crystal structure and enhanced magneto-electric properties of cobalt-substituted nickel–zinc ferrite. J Mater Sci: Mater Electron 31, 20277–20284 (2020). https://doi.org/10.1007/s10854-020-04547-5
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DOI: https://doi.org/10.1007/s10854-020-04547-5