Skip to main content

Advertisement

Log in

Pool Fire Burning Characteristics of Biodiesel

  • Published:
Fire Technology Aims and scope Submit manuscript

Abstract

The characteristics of pool fire burning of methyl esters/biodiesels of palm, soybean, coconut and their blends with diesel were compared against baseline diesel. Pool fires were established and investigated using four different crucible sizes, ranging between 40 mm and 70 mm in diameter to obtain the mass burning rate, flame height and emissions of NO, CO, and SO2 under diffusional flame mode at unconfined atmospheric conditions. The mass burning rate increased with increasing crucible size for all tested fuels, with biodiesel showing higher mass burning rates when compared with diesel. Modified empirical correlations for estimating fuel mass burning rate and flame height showed good agreement with experimental data. Emission-wise, biodiesels generally exhibited higher specific NO emission level than baseline diesel. Blending biodiesel with diesel resulted in an increase of NO level. CO emissions showed a reverse trend, where diesel showed higher emission values than all biodiesels. Burning of neat palm and coconut biodiesels showed non-existent SO2 emission. The experiment showed that the oxygen content in biodiesel assists in pool fire combustion, as evident by the higher mass burning rate as compared to diesel. Soybean biodiesel with higher density exhibited higher mass burning rate as compared to palm and coconut biodiesels. Biodiesel with high level of unsaturation produced lower NO but higher CO emissions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13
Figure 14

Similar content being viewed by others

References

  1. Demirbas A (2007) Progress and recent trends in biofuels. Prog Energy Combust Sci 33:1–18

    Article  Google Scholar 

  2. Shahir VK, Jawahar CP, Suresh PR (2015) Comparative study of diesel and biodiesel on CI engine with emphasis to emissions—a review. Renew Sustain Energy Rev 45:686–697

    Article  Google Scholar 

  3. International Energy Agency (2017) Technology roadmap: delivering sustainable bioenergy

  4. Koseki H, Mulholland GW (1991) The effect of diameter on the burning of crude oil pool fires. Fire Technol 27:54–65

    Article  Google Scholar 

  5. Chatris JM, Quintela J, Folch J et al (2001) Experimental study of burning rate in jet-fuel pool fires. Combust Flame 126:1373–1383

    Article  Google Scholar 

  6. Iwata Y, Koseki H, Janssens ML, Takahashi T (2001) Comparison of combustion characteristics of various crude oils. Int Assoc Fire Saf Sci 7:1–7

    Google Scholar 

  7. Roh JS, Ryou HS, Kim DH et al (2007) Critical velocity and burning rate in pool fire during longitudinal ventilation. Tunn Undergr Sp Technol 22:262–271

    Article  Google Scholar 

  8. Roh JS, Yang SS, Ryou HS et al (2008) An experimental study on the effect of ventilation velocity on burning rate in tunnel fires-heptane pool fire case. Build Environ 43:1225–1231

    Article  Google Scholar 

  9. Woods JAR, Fleck BA, Kostiuk LW (2006) Effects of transverse air flow on burning rates of rectangular methanol pool fires. Combust Flame 146:379–390

    Article  Google Scholar 

  10. Hu L, Liu S, Xu Y, Li D (2011) A wind tunnel experimental study on burning rate enhancement behavior of gasoline pool fires by cross air flow. Combust Flame 158:586–591

    Article  Google Scholar 

  11. Hu L (2017) A review of physics and correlations of pool fire behaviour in wind and future challenges. Fire Saf J 91:41–55

    Article  Google Scholar 

  12. Hu L, Liu S, Wu L (2013) Flame radiation feedback to fuel surface in medium ethanol and heptane pool fires with cross air flow. Combust Flame 160:295–306

    Article  Google Scholar 

  13. Hu L, Hu J, Liu S et al (2015) Evolution of heat feedback in medium pool fires with cross air flow and scaling of mass burning flux by a stagnant layer theory solution. Proc Combust Inst 35:2511–2518

    Article  Google Scholar 

  14. Thomas PH, Webster CT, Raftery MM (1961) Some experiments on buoyant diffusion flames. Combust Flame 5:359–367

    Article  Google Scholar 

  15. Heskestad G (1983) Luminous heights of turbulent diffusion flames. Fire Saf J 5:103–108

    Article  Google Scholar 

  16. Yoshihara N, Ito A, Torikai H (2013) Flame characteristics of small-scale pool fires under low gravity environments. Proc Combust Inst 34:2599–2606

    Article  Google Scholar 

  17. Abe H, Ito A, Torikai H (2015) Effect of gravity on puffing phenomenon of liquid pool fires. Proc Combust Inst 35:2581–2587

    Article  Google Scholar 

  18. Tu R, Fang J, Zhang Y-M et al (2013) Effects of low air pressure on radiation-controlled rectangular ethanol and n-heptane pool fires. Proc Combust Inst 34:2591–2598

    Article  Google Scholar 

  19. Tang F, Hu L, Zhang X et al (2015) Burning rate and flame tilt characteristics of radiation-controlled rectangular hydrocarbon pool fires with cross air flows in a reduced pressure. Fuel 139:18–25

    Article  Google Scholar 

  20. Drysdale D (2011) An introduction to flame dynamics. Wiley, Hoboken

    Book  Google Scholar 

  21. Smith DA, Cox G (1992) Major chemical species in buoyant turbulent diffusion flames. Combust Flame 91:226–238

    Article  Google Scholar 

  22. Chen X, Lu S, Li C et al (2014) Experimental study on ignition and combustion characteristics of typical oils. Fire Mater 38:409–417

    Article  Google Scholar 

  23. Tran V, Morton C, Parthasarathy RN, Gollahalli SR (2014) Pool fires of biofuels and their blends with petroleum diesel. Int J Green Energy 11:595–610

    Article  Google Scholar 

  24. Bazooyar B, Ebrahimzadeh E, Jomekian A, Shariati A (2014) NOx formation of biodiesel in utility power plant boilers. Part A: influence of fuel characteristics. Energy Fuels 28:3778–3792

    Article  Google Scholar 

  25. Tian B, Chong CT, Fan L et al (2019) Soot volume fraction measurements over laminar pool flames of biofuels, diesel and blends. Proc Combust Inst 37:877–884

    Article  Google Scholar 

  26. Sun H, Wang C, Liu H et al (2018) Burning behavior and parameter analysis of biodiesel pool fires. Combust Sci Technol 190:269–285

    Article  Google Scholar 

  27. Chiong MC, Chong CT, Ng J-H et al (2018) Liquid biofuels production and emissions performance in gas turbines : a review. Energy Convers Manag 173:640–658

    Article  Google Scholar 

  28. Hoekman SK, Broch A, Robbins C et al (2012) Review of biodiesel composition, properties, and specifications. Renew Sustain Energy Rev 16:143–169

    Article  Google Scholar 

  29. Heskestad G (2002) Fire plumes, flame height, and air entrainment. In: DiNenno PJ, Drysdale D, Beyler CL et al (eds) SFPE handbook of fire protection engineering, 3rd edn. National Fire Protection Association

  30. Zukoski EE, Cetegen BM, Kubota T (1985) Visible structure of buoyant diffusion flames. Symp Combust 20:361–366

    Article  Google Scholar 

  31. Hamins A, Takashi K, Buch R (1995) Characteristics of pool fire burning. In: Fire resistance of industrial fluids. American Society for Testing and Materials, Indianapolis, IN

  32. Chiong MC, Chong CT, Ng J-H et al (2019) Combustion and emission performances of coconut, palm and soybean methyl esters under reacting spray flame conditions. J Energy Inst 92:1034–1044

    Article  Google Scholar 

  33. Jha SK, Fernando S, To SDF (2008) Flame temperature analysis of biodiesel blends and components. Fuel 87:1982–1988

    Article  Google Scholar 

  34. Burgess D, Strasser A, Grumer J (1961) Diffusive burning of liquid fuels in open trays. Symp Am Chem Soc 91–106

  35. Babrauskas V (1983) Estimating large pool fire burning rates. Fire Technol 19:251–261

    Article  Google Scholar 

  36. Blinov VI, Khudyakov GN (1961) Diffusion burning of liquids. Army Engineer Research and Development Labs Fort Belvoir VA

  37. Gann R, Friedman R (2015) Principles of fire behavior and combustion. Jones and Bartlett Learning, Burlington

    Google Scholar 

  38. Thomas PH (1963) The size of flames from natural fires. Symp Combust 9:844–859

    Article  Google Scholar 

  39. Sun H, Wang C, Liu H et al (2017) Experimental study of combustion characteristics of circular ring thin-layer pool fire. Energy Fuels 31:10082–10092

    Article  Google Scholar 

  40. Leite RM, Centeno FR (2018) Effect of tank diameter on thermal behavior of gasoline and diesel storage tanks fires. J Hazard Mater 342:544–552

    Article  Google Scholar 

  41. Turns SR (2012) An introduction to combustion: concepts and applications, 3rd edn. Mc-GrawHill, New York

    Google Scholar 

  42. Kholghy MR, Weingarten J, Sediako AD et al (2017) Structural effects of biodiesel on soot formation in a laminar coflow diffusion flame. Proc Combust Inst 36:1321–1328

    Article  Google Scholar 

  43. Lefebvre AH, Ballal DR (2010) Gas turbine combustion: alternative fuels and emissions, 3rd edn. CRC Press, Boca Raton

    Book  Google Scholar 

  44. Varatharajan K, Cheralathan M (2012) Influence of fuel properties and composition on NOx emissions from biodiesel powered diesel engines: a review. Renew Sustain Energy Rev 16:3702–3710

    Article  Google Scholar 

Download references

Acknowledgements

Financial support from the Ministry of Education, Malaysia for M.C. Chiong, the Academy Sciences Malaysia and Malaysian Industry-Government Group for High Technology for C.T. Chong under the Newton Advanced Fellowship (NA160115) are gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Meng-Choung Chiong.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chong, C.T., Chiong, MC., Teyo, Z.Y. et al. Pool Fire Burning Characteristics of Biodiesel. Fire Technol 56, 1703–1724 (2020). https://doi.org/10.1007/s10694-020-00949-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10694-020-00949-3

Keywords

Navigation