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Selective Oxidation of 5-Hydroxymethylfurfural to 2, 5-Diformylfuran Over a Vanadium Manganese Oxide Catalyst

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Abstract

5-Hydroxymethylfurfural (HMF) is a major feedstock derived from biomass which could be converted to various high-value-added chemicals. However, it is a challenge to obtain a target product with high selectivity under mild conditions using a heterogeneous non-noble catalyst. In this study, a vanadium manganese oxide catalyst was prepared by a simple chemical synthesis method. Detailed characterization was performed to reveal that the catalyst phase composition is V2O5 and Mn(VO3)2. The catalyst showed good catalytic activity in the selective oxidation of HMF to produce 2,5-diformylfuran (DFF) at atmospheric oxygen pressure. Under optimal conditions, DFF selectivity of 97.8% was obtained at 80 °C with acetonitrile as the solvent. Furthermore, the catalyst could be recovered conveniently and reused for several runs without significant loss of the catalytic activity.

Graphic Abstract

The vanadium manganese oxide catalyst was developed for the selective oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran under atmospheric pressure of molecular oxygen.

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Acknowledgements

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant No. 21606082), Scientific Research Fund of Hunan Provincial Education Department (Grant No. 20B364), and Hunan Province College Students Research Learning and Innovative Experiment Project (Grant Nos. S202010542062 and S202110542077).

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Authors and Affiliations

  1. National & Local Joint Engineering Laboratory for New Petro-Chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha, 410081, China

    Jie Zhu, Feng Cheng, Fei Wang, Sha Wen & Xianxiang Liu

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  1. Jie Zhu
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  2. Feng Cheng
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  3. Fei Wang
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  4. Sha Wen
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  5. Xianxiang Liu
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Correspondence to Xianxiang Liu.

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Zhu, J., Cheng, F., Wang, F. et al. Selective Oxidation of 5-Hydroxymethylfurfural to 2, 5-Diformylfuran Over a Vanadium Manganese Oxide Catalyst. Catal Lett 152, 2280–2287 (2022). https://doi.org/10.1007/s10562-021-03817-z

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  • DOI: https://doi.org/10.1007/s10562-021-03817-z

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