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Surface modification of dielectric materials by Ar/toluene DBD plasma for flotation and drag reduction

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Abstract

In this study, a new approach based on dielectric barrier discharge (DBD) plasma was used to fabricate super-buoyant dielectric materials for drag-reduction. We used a glass slide as a high-density substrate for buoyancy tests and a model boat made from Polymethyl methacrylate (PMMA) for drag-reduction experiments. In the first step, an atmospheric pressure DBD plasma was used for the deposition of the hydrogenated amorphous carbon (a-C:H) film using argon working gas and toluene precursors. The layer characterizations were performed versus the plasma deposition time by FE-SEM, AFM, FTIR, and Raman analysis. The morphological characterizations showed the formation of some micro and nanostructures on the surface followed by an increase in surface roughness. Moreover, the chemical characterizations suggested the successful formation of a-C:H film. In the next step, the effect of the deposited layer was assessed on the buoyance and drag reduction. Based on the results, the plasma coating produced a super-buoyant glass slide with remarkable load-bearing capacity, high durability, and robustness. In addition, the drag force was reduced noticeably after the plasma treatment. The results of this study promise the use of atmospheric pressure plasma for the fabrication of super-buoyant surfaces for buoyancy applications.

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References

  1. T. Zhu et al., A transparent superhydrophobic coating with mechanochemical robustness for anti-icing, photocatalysis and self-cleaning. Chem. Eng. J. 399, 125746 (2020)

    Google Scholar 

  2. S. Xu, Q. Wang, N. Wang, Chemical fabrication strategies for achieving bioinspired superhydrophobic surfaces with micro and nanostructures: a review. Adv. Eng. Mater. 23(3), 2001083 (2021)

    Google Scholar 

  3. Y.-Y. Quan et al., Recent advances in fabricating durable superhydrophobic surfaces: a review in the aspects of structures and materials. Mater. Chem. Front. 5(4), 1655–1682 (2021)

    Google Scholar 

  4. K. Manoharan, S. Bhattacharya, Superhydrophobic surfaces review: functional application, fabrication techniques and limitations. J. Micromanufactur. 2(1), 59–78 (2019)

    Google Scholar 

  5. P.K. Sow et al., Fabricating low-cost, robust superhydrophobic coatings with re-entrant topology for self-cleaning, corrosion inhibition, and oil-water separation. J. Colloid Interface Sci. 600, 358–372 (2021)

    ADS  Google Scholar 

  6. V.A. Ganesh et al., A review on self-cleaning coatings. J. Mater. Chem. 21(41), 16304–16322 (2011)

    Google Scholar 

  7. J. Peng et al., Durable self-cleaning surfaces with superhydrophobic and highly oleophobic properties. Langmuir 35(25), 8404–8412 (2019)

    Google Scholar 

  8. Z. Yang et al., Superhydrophobic epoxy coating modified by fluorographene used for anti-corrosion and self-cleaning. Appl. Surf. Sci. 401, 146–155 (2017)

    ADS  Google Scholar 

  9. S.K. Lahiri et al., Robust fluorine-free and self-healing superhydrophobic coatings by H3BO3 incorporation with SiO2–alkyl-silane@ PDMS on cotton fabric. ACS Appl. Mater. Interfaces 11(10), 10262–10275 (2019)

    Google Scholar 

  10. K. Chen et al., Smart UV-curable fabric coatings with self-healing ability for durable self-cleaning and intelligent oil/water separation. Colloids Surf. A 565, 86–96 (2019)

    Google Scholar 

  11. J. Yong et al., A review of femtosecond laser-structured superhydrophobic or underwater superoleophobic porous surfaces/materials for efficient oil/water separation. RSC Adv. 9(22), 12470–12495 (2019)

    ADS  Google Scholar 

  12. Y. He et al., Fabrication and characterization of degradable and durable fluoride-free super-hydrophobic cotton fabrics for oil/water separation. Surf. Coat. Technol. 378, 125079 (2019)

    Google Scholar 

  13. J. Zhang et al., Facile one-step method to fabricate a slippery lubricant-infused surface (LIS) with self-replenishment properties for anti-icing applications. Coatings 10(2), 119 (2020)

    Google Scholar 

  14. L. Tang et al., Robust superhydrophobic surface with wrinkle-like structures on AZ31 alloy that repels viscous oil and investigations of the anti-icing property. Colloids Surf. A 594, 124655 (2020)

    Google Scholar 

  15. W. Long et al., Superhydrophobic diamond-coated Si nanowires for application of anti-biofouling’. J. Mater. Sci. Technol. 48, 1–8 (2020)

    ADS  Google Scholar 

  16. K. Sun et al., Anti-biofouling superhydrophobic surface fabricated by picosecond laser texturing of stainless steel. Appl. Surf. Sci. 436, 263–267 (2018)

    ADS  Google Scholar 

  17. T. Mouterde et al., Antifogging abilities of model nanotextures. Nat. Mater. 16(6), 658–663 (2017)

    ADS  Google Scholar 

  18. Z. Sun et al., Fly-eye inspired superhydrophobic anti-fogging inorganic nanostructures. Small 10(15), 3001–3006 (2014)

    Google Scholar 

  19. Z. Zhan et al., Highly floatable superhydrophobic metallic assembly for aquatic applications. ACS Appl. Mater. Interfaces 11(51), 48512–48517 (2019)

    Google Scholar 

  20. M. Cheng et al., Improving the durability of a drag-reducing nanocoating by enhancing its mechanical stability. ACS Appl. Mater. Interfaces 7(7), 4275–4282 (2015)

    ADS  Google Scholar 

  21. Y. Zhang et al., A review of recent advances in superhydrophobic surfaces and their applications in drag reduction and heat transfer. Nanomaterials 12(1), 44 (2021)

    Google Scholar 

  22. M. Liravi et al., A comprehensive review on recent advances in superhydrophobic surfaces and their applications for drag reduction. Prog. Org. Coat. 140, 105537 (2020)

    Google Scholar 

  23. P. Dimitrakellis, E. Gogolides, Hydrophobic and superhydrophobic surfaces fabricated using atmospheric pressure cold plasma technology: a review. Adv. Coll. Interface. Sci. 254, 1–21 (2018)

    Google Scholar 

  24. R. Jafari, S. Asadollahi, M. Farzaneh, Applications of plasma technology in development of superhydrophobic surfaces. Plasma Chem. Plasma Process. 33, 177–200 (2013)

    Google Scholar 

  25. F. Sohbatzadeh, E. Shakerinasab, S. Mirzanejhad, Surface modification of aramid yarn by atmospheric pressure plasma: Reinforcement and floating properties. Polym. Testing 117, 107836 (2023)

    Google Scholar 

  26. G.F. Diniz et al., Investigation of the drag-reduction phenomenon on plasma-modified surface. Symmetry 14(3), 524 (2022)

    ADS  Google Scholar 

  27. R. Di Mundo et al., Plasma-textured teflon: repulsion in air of water droplets and drag reduction underwater. Biomimetics 2(1), 1 (2017)

    Google Scholar 

  28. T. Ren et al., Modulating interactions between molten polystyrene and porous solids using atomic layer deposition. Langmuir 37(49), 14520–14526 (2021)

    Google Scholar 

  29. F. Sohbatzadeh et al., Roll-to-roll treatment of silk thread by a compact, single-step cold atmospheric plasma: hydrophobicity and mechanical properties. Appl. Phys. A 126, 1–13 (2020)

    Google Scholar 

  30. F. Sohbatzadeh et al., Characterization and performance of coupled atmospheric pressure argon plasma jet with n-hexane electrospray for hydrophobic layer coatings on cotton textile. Diam. Relat. Mater. 91, 34–45 (2019)

    ADS  Google Scholar 

  31. Y. Liang et al., Reaction mechanism of toluene decomposition in non-thermal plasma: How does it compare with benzene? Fundam Res (2022). https://doi.org/10.1016/j.fmre.2022.03.02

    Article  Google Scholar 

  32. S. Liu et al., Plasma reforming of toluene as a model tar compound from biomass gasification: effect of CO 2 and steam. Waste Dispos. Sustain. Energy 1, 133–141 (2019)

    Google Scholar 

  33. M. Derudi, D. Polino, C. Cavallotti, Toluene and benzyl decomposition mechanisms: elementary reactions and kinetic simulations. Phys. Chem. Chem. Phys. 13(48), 21308–21318 (2011)

    Google Scholar 

  34. W. Liang et al., Abatement of toluene from gas streams via ferro-electric packed bed dielectric barrier discharge plasma. J. Hazard. Mater. 170(2–3), 633–638 (2009)

    Google Scholar 

  35. J. Datta et al., Structure of hydrogenated diamond like carbon by Micro-Raman spectroscopy. Mater. Lett. 71, 131–133 (2012)

    Google Scholar 

  36. J.G. Buijnsters et al., Hydrogen quantification in hydrogenated amorphous carbon films by infrared, Raman, and x-ray absorption near edge spectroscopies. J. Appl. Phys. 105(9), 093510 (2009)

    ADS  Google Scholar 

  37. S. López-Romero, J. Chávez-Ramírez, Synthesis of TiC thin films by CVD from toluene and titanium tetrachloride with nickel as catalyst. Matéria (Rio de Janeiro) 12, 487–493 (2007)

    Google Scholar 

  38. J. Zhao et al., Application of ZnO/epoxy resin superhydrophobic coating for buoyancy enhancement and drag reduction. Colloids Surf. A 651, 129714 (2022)

    Google Scholar 

  39. Z. Wang et al., Water entry dynamics of rough microstructured spheres. Phys. Fluids (2022). https://doi.org/10.1063/5.0102109

    Article  Google Scholar 

  40. Z. Wang et al., Robust air cavity generation on sacrificial microstructures for sustainable underwater drag reduction. Appl. Phys. Lett. (2022). https://doi.org/10.1063/5.0128049

    Article  Google Scholar 

  41. Z. Wang et al., Dramatically reducing the critical velocity of air cavity generation via biomimetic microstructure effects. Nanoscale 14(31), 11218–11226 (2022)

    Google Scholar 

  42. T. Tao et al., Influence of superhydrophobic area occupancy and impact angle on the water entry dynamics of spheres. Phys. Fluids (2022). https://doi.org/10.1063/5.0111025

    Article  Google Scholar 

  43. Z. Wang et al., Underwater drag reduction and buoyancy enhancement on biomimetic antiabrasive superhydrophobic coatings. ACS Appl. Mater. Interfaces 13(40), 48270–48280 (2021)

    Google Scholar 

  44. J. Zhang, L. Zhang, X. Gong, Large-scale spraying fabrication of robust fluorine-free superhydrophobic coatings based on dual-sized silica particles for effective antipollution and strong buoyancy. Langmuir 37(19), 6042–6051 (2021)

    Google Scholar 

  45. H. Chen et al., Construction of MOF-based superhydrophobic composite coating with excellent abrasion resistance and durability for self-cleaning, corrosion resistance, anti-icing, and loading-increasing research. Chem. Eng. J. 408, 127343 (2021)

    ADS  Google Scholar 

  46. G.R.T. Suyambulingam et al., Excellent floating and load bearing properties of superhydrophobic ZnO/copper stearate nanocoating. Chem. Eng. J. 320, 468–477 (2017)

    Google Scholar 

  47. G.B. Hwang et al., Buoyancy increase and drag-reduction through a simple superhydrophobic coating. Nanoscale 9(22), 7588–7594 (2017)

    Google Scholar 

  48. Z.X. Jiang, L. Geng, Y.D. Huang, Design and fabrication of hydrophobic copper mesh with striking loading capacity and pressure resistance. J. Phys. Chem. C 114(20), 9370–9378 (2010)

    Google Scholar 

  49. Q. Pan, M. Wang, Miniature boats with striking loading capacity fabricated from superhydrophobic copper meshes. ACS Appl. Mater. Interfaces 1(2), 420–423 (2009)

    Google Scholar 

  50. W. Guo et al., Construction of durable flame-retardant and robust superhydrophobic coatings on cotton fabrics for water-oil separation application. Chem. Eng. J. 398, 125661 (2020)

    Google Scholar 

  51. N. Celik et al., Fabrication of robust superhydrophobic surfaces by one-step spray coating: Evaporation driven self-assembly of wax and nanoparticles into hierarchical structures. Chem. Eng. J. 396, 125230 (2020)

    Google Scholar 

  52. P. Nguyen-Tri et al., Robust superhydrophobic cotton fibers prepared by simple dip-coating approach using chemical and plasma-etching pretreatments. ACS Omega 4(4), 7829–7837 (2019)

    MathSciNet  Google Scholar 

  53. N. Wang et al., Fabrication of robust and scalable superhydrophobic surfaces and investigation of their anti-icing properties. Mater. Des. 156, 320–328 (2018)

    Google Scholar 

  54. Z.-H. Zhang et al., One-step fabrication of robust superhydrophobic and superoleophilic surfaces with self-cleaning and oil/water separation function. Sci. Rep. 8(1), 3869 (2018)

    ADS  Google Scholar 

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FS., supervision, validation, writing—review and editing, project administration, visualization, ES., conceptualization, methodology, software, investigation, data curation, writing—original draft, visualization, project administration.

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Correspondence to Farshad Sohbatzadeh.

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Shakerinasab, E., Sohbatzadeh, F. Surface modification of dielectric materials by Ar/toluene DBD plasma for flotation and drag reduction. Appl. Phys. A 129, 857 (2023). https://doi.org/10.1007/s00339-023-07121-y

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