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Properties of polyurethane-poly(2,2,3,3-tetrafluoropropyl acrylate) triblock copolymer aqueous dispersion and its film cast from the dispersion

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Abstract

Polyurethane-poly(2,2,3,3-tetrafluoropropyl acrylate) (PU-PTFPA) triblock copolymer aqueous dispersions were synthesized by three-step polymerization. Infra-red (IR) data verify the copolymerization between PU and TFPA. The properties of copolymer aqueous dispersion and its film cast from the dispersion have been investigated by transmission electron microscopy (TEM), dynamic light scattering (DLS), and some other physical testing methods. TEM observations indicate that the morphologies of copolymer particles formed in water are almost irregular spherical shape with core-shell structure. DLS results verify that the introduction of TFPA monomer changes the average particle size of copolymer particles. The experimental data demonstrate that the factors influencing the properties of PU-PTFPA triblock copolymer aqueous dispersion and its film cast from the dispersion mainly involve PU content, DMPA content and PTFPA content.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shandong University of Technology, 255049, Zibo, P.R. China

    Guoquan Zhu

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  1. Guoquan Zhu
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Correspondence to Guoquan Zhu.

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Zhu, G. Properties of polyurethane-poly(2,2,3,3-tetrafluoropropyl acrylate) triblock copolymer aqueous dispersion and its film cast from the dispersion. Fibers Polym 8, 243–248 (2007). https://doi.org/10.1007/BF02877265

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  • DOI: https://doi.org/10.1007/BF02877265

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