Skip to main content
SpringerLink
Log in

Surface improvements in coatings using polyfluorooxetane-modified polyesters

Améliorations de la surface des revêtements grâce aux polyesters modifiés de polyfluorooxétane

Oberflächenverbesserung mit Hilfe von Polyfluorooxetan-modifizierten Polyester

  • Papers
  • Published:
Surface Coatings International Part B: Coatings Transactions

Summaries

A significant enhancement of fluorine content at the air interface in polyester melamine coatings was achieved by the utilisation of surface-migrating polyfluorooxetane copolymer moieties. The manipulation of the microstructure of the fluorinated polyesters was conducted by utilising a design of experiments (DOE) to quantify and optimise the performance of polyester melamine coatings through the manipulation of the non-cyclic monomer level, the polyfluorooxetane level, the choice of aromatic monomer, and the functionality of the polyester. Changes in stain, solvent and scratch resistances corresponding with the composition of the polyfluorooxetane-modified polyesters were demonstrated.

Résumé

Une amélioration signifiante de la teneur en fluor à l’interface avec l’air des revêtements mélamine polyester a été obtenu grâce à l’emploi des combinaisons copolymère polyfluorooxétane qui migrent à la surface. La manipulation de la microstructure des polyesters fluorés a été accomplie en utilisant un design d’expériences (DOE) pour quantifier et optimaliser la performance des revêtements mélamine polyester par le moyen de la manipulation du niveau monomérique non-cyclique, du niveau polyfluorooxétane, du choix de monomère aromatique et de la fonctionnalité du polyester. On a démontré des changements dans le domaine de la résistance aux taches, aux solvants et aux éraflures, changements qui correspondaient à la composition des polyesters modifiés de polyfluorooxétane.

Zusammenfassung

Wir erzielten eine deutliche Steigerung des Fluoritgehaltes an der Oberfläche von Polyestermelaminlacken unter Verwendung von Oberflächen-migrierenden Polyfluorooxetan-Kopolymerhälften. Wir veränderten die Mikrostruktur des fluorinierten Polyesters mit Hilfe eines experimentellen Designs (DOE) das uns erlaubte, die Leistung von Polyestermelaminlacken durch die Manipulation des nicht-zyklischen Monomergehaltes, des Polyfluorooxetangehaltes, der Wahl des aromatischen Monomers und der Funktionalität des Polyesters zu kontrollieren. Wir zeigten, daß die Veränderung des Polyfluorooxetan-modifizierten Polyesters mit Veränderung in der Widerstandsfähigkeit des Lackes zu Flecken, Lösungsmitteln und Kratzern einhergeht.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Anton D,Adv Mater,10, 1197, 1998

    Article  CAS  Google Scholar 

  2. Castelvetro V, M Aglietto, F Ciardelli, O Chiantore, M Lazzari and Massimo, ‘Structure control, coating properties, and durability of fluoronated acrylic-based polymers’,The Journal of Coating Technology,74, (928), 57, 2002

    Article  CAS  Google Scholar 

  3. Bessiere J M, A El Bachiri and B J Boutevin,Fluorine Chem,56, 295, 1992

    Article  CAS  Google Scholar 

  4. Narita T, T Hagiwara, H Hamana and T Nara,Makromol Chem Rapid Comm,6, 301, 1985

    Article  CAS  Google Scholar 

  5. Sharpe M R, I R Peterson and J P Tatum, ‘Wetting kinetics of fluorinated surfaces’,Langmuir,18, (9), 3549–54, 2002

    Article  CAS  Google Scholar 

  6. Clark G D, US Patent 6,168,866, ‘Abrasion and stain resistant curable fluorinated coating’, 2nd Janury 2001

  7. Qiu Z M, WO 02072537, ‘Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties’

  8. Canteri R, G Speranza, M Anderle, S Turri, S Radice and T Trombetta, ‘Characterization of perfluoropolyether-urethane coatings by TOF-SIMS and XPS’, Second Ion Mass Spectrom, Proceedings of international conference, 741–4, SIMS XII, 2000

  9. Delucchi M, S Turri, A Barbucci, S Novelli and G Cerisola, ‘Investigation on physico-chemical and electrochemical properties of fluoropolyether coatings’,Progress in Organic Coatings,44, (3), 227–32, 2002

    Article  CAS  Google Scholar 

  10. Clark G D, ‘Abrasion and stain resistant curable fluorinated coating’, US Patent 6,168,886, 2nd January 2001

  11. Tsibouklis J, P Graham, P J Eaton, J R Smith, T G Nevell, J D Smart and R J Ewen ‘Poly(perfluoroalkym methacrylate) film structures: Surface organization phenomena, surface energy determinations, and force of adhesion measurements’,Macromolecules,33, 8460–65, 2000

    Article  CAS  Google Scholar 

  12. Garcia G, R Weinert, P Cadile and R Cuevas, US Patent 6,465,566, ‘Anionic water-borne polyurethane dispersions containing polyiluorooxetanes’, 15th October 2002

  13. Garcia G, R Weinert, P Cadile and R Cuevas, US Patent 6,465,565, ‘Anionic water-borne polyurethane dispersions containing polyíluorooxetanes, 15th October 2002

  14. Callicott M S, D L Hyde, C M Kausch, A Verrocchi, R J Weinert, R E Medsker, D D Medsker and D C Gottschalk, US Patent 6,423,418, ‘Easily cleanable polymer laminates’ 23rd July 2002

  15. Weinert R, E N Kresge, R E Medsker and D D Woodland, US Patent 6,383,651, ‘Polyester with partially fluorinated side chains’, 7th May 2002

  16. Ji Q, S Wang, H Kang, T E Glass and J E McGrath, Proceedings from 218th ACS National Meeting, New Orleans, USA, 22nd to 26th August 1999

  17. Ji Q, H Kang, J Wang, S Wang, T E Glass and J E McGrath, Proceedings from 219th ACS National Meeting, 26–30, San Francisco, USA, March 2000

  18. McGrath J E, Q Ji, J Wang, S Wang and T E Glass,Polymer Preprints,41, (1), 346–7, 2000

    Google Scholar 

  19. Kim Y S, J S Lee, Q Ji, and J E McGrath, ‘Surface properties of fluorinated oxetane polyol modified polyurethane block copolymers’,Polymer,43, (25), 7161–70, 2002

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. OMNOVA Solutions Inc, 2990 Gilchrist Road, 44305, Akron, Ohio, USA

    R J Weinert & J E Robbins

  2. Cabot Microelectronics Corporation, USA

    D Woodland & R Medsker

Authors
  1. R J Weinert
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J E Robbins
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D Woodland
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R Medsker
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R J Weinert.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Weinert, R.J., Robbins, J.E., Woodland, D. et al. Surface improvements in coatings using polyfluorooxetane-modified polyesters. Surface Coatings International Part B: Coatings Transactions 87, 159–165 (2004). https://doi.org/10.1007/BF02699630

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02699630

Keywords

Search

Navigation